Rapid fluorination using polyvinylidene-difluoride (PVDF) for the synthesis of oxyfluoride Bi2VO5F1−x
Source abstract
Abstract
The topotactic fluorination of Bi4V2O11 to Bi2VO5F1−x using polyvinylidene difluoride (PVDF) was investigated. The reaction proceeded rapidly at a moderate temperature of 400 °C. In situ XRD-DSC measurement revealed that fluorination initiated above 270 °C and reached near completion by 352 °C within minutes, beyond which prolonged heating led to sample decomposition. These results underscore the feasibility of achieving topotactic fluorination at moderate temperatures with rapid ionic kinetics in ionic conductors, presenting a promising strategy for synthesizing novel mixed-anion compounds via soft chemistry.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Catalysis and Oxidation Reactions · Inorganic Fluorides and Related Compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University
Joint Research Center, Kindai University
References (23)
Show source-provided references
1. 1) M. Leblanc, V. Maisonneuve and A. Tressaud, Chem. Rev. 115, 1191 (2015).10.1021/cr500173c ↗
2. 2) H. Kageyama, K. Hayashi, K. Maeda, J. P. Attfield, Z. Hiroi, J. M. Rondinelli and K. R. Poeppelmeier, Nat. Commun. 9, 772 (2018).10.1038/s41467-018-02838-4 ↗
3. 3) J. Ravez and A. Simon, Ferroelectrics 81, 309 (1988).10.1080/00150198808008870 ↗
4. 4) K. Oka, H. Hojo, M. Azuma and K. Oh-ishi, Chem. Mater. 28, 5554 (2016).10.1021/acs.chemmater.6b02509 ↗
5. 5) Y. Wang, T. Takami, Z. Li, K. Yamamoto, T. Matsunaga, T. Uchiyama, T. Watanabe, H. Miki, T. Inoue, H. Iba, U. Mizutani, H. Sato, K. Maeda, H. Kageyama and Y. Uchimoto, Chem. Mater. 34, 10631 (2022).10.1021/acs.chemmater.2c02736 ↗
6. 6) H. Miki, K. Yamamoto, H. Nakaki, T. Yoshinari, K. Nakanishi, S. Nakanishi, H. Iba, J. Miyawaki, Y. Harada and A. Kuwabara, J. Am. Chem. Soc. 146, 3844 (2024).10.1021/jacs.3c10871 ↗
7. 7) R. Kuriki, T. Ichibha, K. Hongo, D. Lu, R. Maezono, H. Kageyama, O. Ishitani, K. Oka and K. Maeda, J. Am. Chem. Soc. 140, 6648 (2018).10.1021/jacs.8b02822 ↗
8. 8) R. Mizuochi, K. Oka, Y. Inaguma and K. Maeda, Sustain. Energy Fuels 6, 2423 (2022).10.1039/D2SE00282E ↗
9. 9) R. Mizuochi, Y. Sugawara, K. Oka, Y. Inaguma, S. Nozawa, T. Yokoi, T. Yamaguchi and K. Maeda, J. Am. Chem. Soc. 146, 32343 (2024).10.1021/jacs.4c05740 ↗
10. 10) K. Oka and K. Oh-ishi, Inorg. Chem. 54, 10239 (2015).10.1002/anie.201503954 ↗
11. 11) M. R. Marvel, J. Lesage, J. Baek, P. S. Halasyamani, C. L. Stern and K. R. Poeppelmeier, J. Am. Chem. Soc. 129, 13963 (2007).10.1021/ja074659h ↗
12. 12) C. R. Morelock, B. K. Greve, M. Cetinkol, K. W. Chapman, P. J. Chupas and A. P. Wilkinson, Chem. Mater. 25, 1900 (2013).10.1021/cm400536n ↗
13. 13) R. Gautier, R. Gautier, K. B. Chang and K. R. Poeppelmeier, Inorg. Chem. 54, 1712 (2015).10.1021/ic5026735 ↗
14. 14) F. J. Berry, F. C. Coomer, C. Hancock, Ö. Helgason, E. A. Moore, P. R. Slater, A. J. Wright and M. F. Thomas, J. Solid State Chem. 184, 1361 (2011).10.1016/j.jssc.2011.04.011 ↗
15. 15) Y. Tsujimoto, K. Yamaura and E. Takayama-Muromachi, Appl. Sci.-Basel 2, 206 (2012).10.3390/app2010206 ↗
16. 16) O. Clemens, J. Solid State Chem. 225, 261 (2015).10.1016/j.jssc.2014.12.027 ↗
17. 17) J. Jacobs, M. A. L. Marques, H.-C. Wang, E. Dieterich and S. G. Ebbinghaus, Inorg. Chem. 60, 13646 (2021).10.1021/acs.inorgchem.1c01957 ↗
18. 18) Y. Ji, C. T. Jafvert, N. N. Zyaykina and F. Zhao, J. Clean. Prod. 367, 133112 (2022).10.1016/j.jclepro.2022.133112 ↗
19. 19) A. V. Akopjan, T. V. Serov, V. A. Dolgikh, E. I. Ardaschnikova and P. Lightfoot, J. Mater. Chem. 12, 1490 (2002).10.1039/b201049f ↗
20. 20) F. Izumi and K. Momma, Solid State Phenom. 130, 15 (2007).10.4028/www.scientific.net/SSP.130.15 ↗
21. 21) K. Momma and F. Izumi, J. Appl. Crystallogr. 44, 1272 (2011).10.1107/S0021889811038970 ↗
22. 22) E. E. McCabe, I. P. Jones, D. Zhang, N. C. Hyatt and C. Greaves, J. Mater. Chem. 17, 1193 (2007).10.1039/b613970a ↗
23. 23) T. Pickford, X. Gu, E. L. Heeley and C. Wan, CrystEngComm 21, 5418 (2019).10.1039/C9CE01051C ↗