journal article·2019-11Open access

Graphene type dependence of carbon nanotubes/graphene nanoplatelets polyurethane hybrid nanocomposites: Micromechanical modeling and mechanical properties

Amir Navidfar, Levent Trabzon

Abstract

Micromechanical modeling and mechanical properties of polyurethane (PU) hybrid nanocomposite foams with multi-walled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) were investigated by mean of tensile strength, hardness, impact strength and modified Halpin-Tsai equation. Three types of graphene, with varied flake sizes and specific surface areas (SSA), were utilized to study the effect of graphene types on the synergistic effect of MWCNT/GNP hybrid nanofillers. The results indicate a remarkable synergetic effect between MWCNTs and GNP-1.5 (1:1) with a flake size of 1.5 μm and a higher SSA (750 m^2/g), which tensile strength of PU was improved by 43% as compared to 19% for PU/MWCNTs and 17% for PU/GNP-1.5 at 0.25 wt% nanofiller loadings. The synergy was successfully predicted using unit cell modeling, in which the calculated data agrees with the experimental results.
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Polymer Nanocomposites and Properties · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Enhanced mechanical and thermal properties of rigid polyurethane foam composites containing graphene nanosheets and carbon nanotubes10.1002/pi.4188 ↗
2. A study on polyurethane hybrid nanocomposite foams reinforced with multiwalled carbon nanotubes and silica nanoparticles10.1080/03602559.2017.1410834 ↗
3. Acoustic properties of polyurethane compositions enhanced with multi-walled carbon nanotubes and silica nanoparticles10.1002/mawe.201700074 ↗
4. Improving electrical conductivity of poly methyl methacrylate by utilization of carbon nanotube and CO2 laser10.1002/app.42671 ↗
5. Effect of carbon nanotubes on laser cutting of multi-walled carbon nanotubes/poly methyl methacrylate nanocomposites10.1016/j.optlastec.2014.10.003 ↗
6. Role of CO2 laser cutting conditions on anisotropic properties of nanocomposite contain carbon nanotubes10.2351/1.4947491 ↗
7. Influence of processing condition and carbon nanotube on mechanical properties of injection molded multi‐walled carbon nanotube/poly (methyl methacrylate) nanocomposites10.1002/app.43738 ↗
8. Size and synergy effects of nanofiller hybrids including graphene nanoplatelets and carbon nanotubes in mechanical properties of epoxy composites10.1016/j.carbon.2012.07.021 ↗
9. Characterization of polyacrylonitrile, poly (acrylonitrile‐co‐vinyl acetate), and poly (acrylonitrile‐co‐itaconic acid) based activated carbon nanofibers10.1002/app.44381 ↗
10. Tensile and hardness properties of polycarbonate nanocomposites in the presence of styrene maleic anhydride as compatibilizer10.1002/adv.21832 ↗
11. Improving the mechanical properties of poly methyl methacrylate nanocomposites for dentistry applications reinforced with different nanoparticles10.1080/03602559.2017.1289402 ↗
12. A review of recent research on materials used in polymer–matrix composites for body armor application10.1177/0021998318764002 ↗
13. Effect of functionalized carbon nanotubes on the thermal conductivity of epoxy composites10.1016/j.carbon.2009.08.047 ↗
14. Investigating the effects of number and distribution of GNP layers on graphene reinforced polymer properties: physical, numerical and micromechanical methods10.1016/j.compscitech.2016.12.024 ↗
15. Synergetic effects of graphene platelets and carbon nanotubes on the mechanical and thermal properties of epoxy composites10.1016/j.carbon.2010.10.014 ↗
16. Carbon nanotube–graphene nanoplatelet hybrids as high-performance multifunctional reinforcements in epoxy composites10.1016/j.compscitech.2012.11.015 ↗
17. Elastic behaviour of hybrid cross-linked epoxy-based nanocomposite reinforced with GNP and CNT: experimental and multiscale modelling
18. Graphene nanoplatelets/carbon nanotubes/polyurethane composites as efficient shield against electromagnetic polluting radiations10.1016/j.compositesb.2017.03.068 ↗
19. Synergistic effect of graphene/multiwalled carbon nanotube hybrid fillers on mechanical, electrical and EMI shielding properties of polycarbonate/ethylene methyl acrylate nanocomposites10.1016/j.compositesb.2018.10.009 ↗
20. Hybrids of carbon nanotubes and graphene/graphene oxide10.1016/j.cossms.2012.12.002 ↗
21. Extraordinary synergy in the mechanical properties of polymer matrix composites reinforced with 2 nanocarbons10.1073/pnas.0905844106 ↗
22. Influence of filler size on the properties of poly (lactic acid)(PLA)/graphene nanoplatelet (GNP) nanocomposites10.1016/j.eurpolymj.2016.10.045 ↗
23. Mechanical properties of multi-walled carbon nanotube/epoxy composites10.1016/j.matdes.2010.04.018 ↗
24. Mechanical behavior of phenolic-based composites reinforced with multi-walled carbon nanotubes10.1016/j.carbon.2005.07.005 ↗
25. A review on lattice defects in graphene: types, generation, effects and regulation10.3390/mi8050163 ↗
26. Porous graphene networks as high performance anode materials for lithium ion batteries10.1016/j.carbon.2013.04.053 ↗
27. Enhanced acoustic damping in flexible polyurethane foams filled with carbon nanotubes10.1016/j.compscitech.2008.07.003 ↗
28. Synthesis of nanoparticle-enhanced polyurethane foams and evaluation of mechanical characteristics10.1016/j.compositesb.2017.10.025 ↗
29. Sensing strain and damage in polyurethane-MWCNT nano-composite foams using electrical measurements10.3144/expresspolymlett.2013.4 ↗
30. Polyimide reinforced with hybrid graphene oxide@ carbon nanotube: toward high strength, toughness, electrical conductivity10.1016/j.carbon.2017.07.055 ↗
31. Micromechanics of reinforcement of a graphene-based thermoplastic elastomer nanocomposite10.1016/j.compositesa.2018.04.014 ↗
32. The effect of flake diameter on the reinforcement of few-layer graphene–PMMA composites10.1016/j.compscitech.2015.01.005 ↗
33. A study of rigid polyurethane foams: the effect of synthesized polyols and nanoporous graphene10.1002/app.45001 ↗
34. Comparative study of graphene nanoparticle and multiwall carbon nanotube filled epoxy nanocomposites based on mechanical, thermal and dielectric properties10.1016/j.compositesb.2017.03.023 ↗
35. Synergistic toughening of composite fibres by self-alignment of reduced graphene oxide and carbon nanotubes10.1038/ncomms1661 ↗
36. Synergistic effect of carbon nanotube and graphene nanoplates on the mechanical, electrical and electromagnetic interference shielding properties of polymer composites and polymer composite foams10.1016/j.cej.2018.07.144 ↗
37. Modeling and analysis of synergistic effect in thermal conductivity enhancement of polymer composites with hybrid filler10.1016/j.ijheatmasstransfer.2014.10.051 ↗
38. Enhanced thermal conductivity in a hybrid graphite nanoplatelet–carbon nanotube filler for epoxy composites10.1002/adma.200800401 ↗
39. Navidfar · 2014
40. Investigation of Rockwell hardness and Charpy impact test of injection molded multi-walled carbon nanotubes/poly methyl methacrylate nanocomposites
41. Reich · 2008
42. Modeling and mechanical performance of carbon nanotube/epoxy resin composites10.1016/j.matdes.2012.02.039 ↗
43. Enhanced mechanical properties of nanocomposites at low graphene content10.1021/nn9010472 ↗
44. Measurement of the elastic properties and intrinsic strength of monolayer graphene10.1126/science.1157996 ↗
45. Synergistic effect of multi-walled carbon nanotubes and silica nanoparticles on polyurethane nanocomposites
46. Synergistic mechanical properties improvement of carbon nanotubes/graphene reinforced polyurethane hybrid nanocomposites
47. Effect of graphene nanoplatelets and multi-walled carbon nanotubes on tensile properties of rigid polyurethane