journal article·2009-10

An attempt to correct the quasichemical model

Mats Hillert, Malin Selleby, Bo Sundman

Acta Materialia· Volume 57· Issue 17
Publisher page

Abstract

An attempt was made to correct the quasichemical model to avoid predictions of negative configurational entropy when long-range order is impossible as in liquids. The attempt was successful for negative interaction energies but for positive interaction energies the simplest possible variant of the model predicted two narrow miscibility gaps. It was not possible to improve this by adding regular solution parameters. However, using the next possible variant of the correction term these difficulties may be avoided.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Chemical Thermodynamics and Molecular Structure · High-pressure geophysics and materials · Phase Equilibria and Thermodynamics

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References (14)

Show source-provided references
1. Fowler · 1939
2. Takagi · Proc Phys Math Soc Jpn · 1941 · 23 · 44
3. Kikuchi · Phys Rev · 1951 · 81 · 98810.1103/PhysRev.81.988 ↗
4. Pelton · Metall Trans B · 1986 · 4 · 80510.1007/BF02657144 ↗
5. Pelton · Int J Mater Res · 2007 · 98 · 110.3139/146.101554 ↗
6. Ising · Z Phys · 1925 · 31 · 25310.1007/BF02980577 ↗
7. Pelton · Metall Trans A · 2001 · 32 · 135510.1007/s11661-001-0226-3 ↗
8. Chartrand · Metall Trans A · 2001 · 32 · 138510.1007/s11661-001-0228-1 ↗
9. Hillert · 2008
10. Andersson · Acta Metall · 1986 · 34 · 43710.1016/0001-6160(86)90079-9 ↗
11. Andersson · Calphad · 2002 · 26 · 23710.1016/S0364-5916(02)00037-8 ↗
12. Lukas · 2007
13. Sundman · Z Metallkd · 1990 · 81 · 251
14. Hillert · J Alloy Compd · 2001 · 320 · 16110.1016/S0925-8388(00)01481-X ↗