Microstructure and texture development in Ti50Ni25Cu25 melt-spun ribbon

Abstract The conventionally produced Ti50Ni50−xCux shape memory alloys with Cu-content exceeding 12 at.% have been reported to be brittle. The authors have recently reported that, after being properly annealed, the Ti50Ni25Cu25 melt-spun ribbon exhibits excellent superelasticity and shape memory effect. The present research aims to elucidate why these beneficial properties come about by investigating the evolution of microstructures and textures as a function of the annealing condition. It is found that annealing at 500 °C and above results in the formation of a strong ( 1 1 1 ) [ 7 ¯ 1 5 ] B 19 sheet texture that is favorable to martensite detwinning, while with annealing at 550 °C and above the formation of B11 precipitates becomes significant. These two factors are believed to play key roles in determining the properties of the ribbon.