journal article·2025-03

β-relaxation anomaly with low modulus and enhanced recoverable strain in strain glasses crossover

Chuanxin Liang, Dong Wang, Yuanchao Ji, Jian Zhang, Xiaobing Ren, Yunzhi Wang

Acta Materialia· Volume 286
Publisher page

Abstract

The β-relaxation phenomenon in glasses has shown important effects on toughness, ductility, and creep. However, such a β-relaxation has not been reported yet in an important class of glassy materials, ferroic glasses. Here, we report the existence of a β-relaxation anomaly and its physical origin in strain glass systems by combining molecular statics calculation and phase field simulation. The resolved β-relaxation is observed below the strain glass transition temperature at a critical composition accompanied with spontaneous strain glass to normal martensitic phase transformation, and the internal friction for this β-relaxation anomaly fits well with the Arrhenius equation. The superelasticity with β-relaxation has shown low modulus with high recoverable strain over a wide temperature range. Calculated microstructural evolution and the local stress field caused by point defects suggest that the formed percolation-like metastable suppression field under cooling could be the physical origin of the β-relaxation in strain glass systems and is correlated with crystallization.
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Research context

OpenAlex topics: Material Dynamics and Properties · Metallic Glasses and Amorphous Alloys · High-pressure geophysics and materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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