Carboxymethyl-dithiocarbamate-functionalized silica nanoparticles for naked-eye detection of Ag+ in aqueous medium
Source abstract
Abstract
We prepared the carboxymethyl-dithiocarbamate-functionalized silica nanoparticle for detecting silver ions in aqueous media. The functionalized silica nanoparticles were characterized by X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, transmission electron microscopy and thermogravimetric analysis. The functionalized silica nanoparticles realize highly sensitive and selective detection for Ag+ in aqueous solution with an apparent color change over a pH range of 4–6 and under interfering ions. The functionalized silica nanoparticles allow fast detection for Ag+ at 90 °C with a low minimum detectable concentration (0.09 mM). And a remarkable color change also occurs in the presence of Ag+ solutions containing EDTA. This developed technique can easy and fast detect silver ions by the naked eye without using any sophisticated instrumentation.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Molecular Sensors and Ion Detection · Advanced biosensing and bioanalysis techniques · Advanced Nanomaterials in Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (28)
Show source-provided references
1. Liu X, Wi L, Shen Q, Nie Z, Guo M, Han Y, Liu W, Yao S (2011) The Ag+-G interaction inhibits the electrocatalytic oxidation of guanine-A novel mechanism for Ag+ detection. Talanta 85(3):1603–160810.1016/j.talanta.2011.06.061 ↗
2. Wen G, Lin C, Tang M, Liu G, Liang A, Jiang ZA (2013) Highly sensitive aptamer method for Ag+ sensing using resonance rayleigh scattering as the detection technique and a modified nanogold probe. RSC Adv 3:1941–194610.1039/C2RA22542E ↗
3. Ghaedi M, Shokrollahi A, Niknam K, Niknam E, Najibi A, Soylak M (2009) Cloud point extraction and flame atomic absorption spectrometric determination of cadmium (II), lead (II), palladium (II) and silver (I) in environmental samples. J Hazard Mater 168:1022–102710.1016/j.jhazmat.2009.02.130 ↗
4. Zanganeh AR, Amini MK (2007) A potentiometric and voltammetric sensor based on polypyrrole film with electrochemically induced recognition sites for detection of silver ion. Electrochim Acta 52:3822–383010.1016/j.electacta.2006.10.055 ↗
5. Brenner IB, Liezers M, Godfrey J, Nelms S, Cantle J (1999) Analytical characteristics of a high efficiency ion transmission interface (S mode) inductively coupled plasma mass spectrometer for trace element determinations in geological and environmental materials. Spectrochim Acta Part B 54:991–101310.1016/S0584-8547(99)00062-2 ↗
6. Hosoba M, Oshita K, Katarina RK, Takayanagi T, Oshima M, Motomizu S (2009) Synthesis of novel chitosan resin possessing histidine moiety and its application to the determination of trace silver by ICP-AES coupled with triplet automated-pretreatment system. Anal Chim Acta 639:51–5610.1016/j.aca.2009.02.050 ↗
7. Li G, Zhang L, Li Z, Zhang W (2010) PAR immobilized colorimetric fiber for heavy metal ion detection and adsorption. J Hazard Mater 177:983–98910.1016/j.jhazmat.2010.01.015 ↗
8. Kumar A, Kumar V, Diwan U, Upadhyay KK (2013) Highly sensitive and selective naked-eye detection of Cu2+ in aqueous medium by a ninhydrin–quinoxaline derivative. Sens Actuators B 176:420–42710.1016/j.snb.2012.09.089 ↗
9. Zhang JF, Zhou Y, Yoon J, Kim JS (2011) Recent progress in fluorescent and colorimetric chemosensors for detection of precious metal ions (silver, gold and platinum ions). Chem Soc Rev 40:3416–342910.1039/c1cs15028f ↗
10. Sung YM, Wu SP (2014) Highly selective and sensitive colorimetric detection of Ag (I) using N-1-(2-mercaptoethyl) adenine functionalized gold nanoparticles. Sens Actuators B 197:172–17610.1016/j.snb.2014.02.044 ↗
11. Zhang T, Chai Y, Yuan R, Guo J (2012) Potentiometric detection of silver (I) ion based on carbon paste electrode modified with diazo-thiophenol-functionalized nanoporous silica gel. Mater Sci Eng C 32:1179–118310.1016/j.msec.2012.03.005 ↗
12. Zhou Y, Wang S, Zhang K, Jiang X (2008) Visual detection of copper (II) by azide-and alkyne-functionalized gold nanoparticles using click chemistry. Angew Chem 120:397564–397566
13. Li F, Meng F, Wang Y, Zhu C, Cheng Y (2015) Polymer-based fluorescence sensor incorporating thiazole moiety for direct and visual detection of Hg2+ and Ag+. Tetrahedron 71:1700–170410.1016/j.tet.2015.01.052 ↗
14. Lou T, Chen Z, Wang Y, Chen L (2011) Blue-to-red colorimetric sensing strategy for Hg2+ and Ag+ via redox-regulated surface chemistry of gold nanoparticles. ACS Appl Mater Interfaces 3:1568–157310.1021/am200130e ↗
15. Swamy KMK, Kim HN, Soh JH, Kim Y, Kim SJ, Yoon J (2009) Manipulation of fluorescent and colorimetric changes of fluorescein derivatives and applications for sensing silver ions. Chem Commun 45:1234–123610.1039/b819538b ↗
16. Khabbaz LS, Hassanzadeh-Khayyat M, Zaree P, Ramezani M, Abnous K, Taghdisi SM (2015) Detection of kanamycin by using an aptamer-based biosensor using silica nanoparticles. Anal Methods 7:8611–861610.1039/C5AY01807B ↗
17. Schätz A, Hager M, Reiser O (2009) Cu (II)-azabis (oxazoline)-complexes immobilized on superparamagnetic magnetite@ silica-nanoparticles: a highly selective and recyclable catalyst for the kinetic resolution of 1, 2-diols. Adv Funct Mater 19:2109–211510.1002/adfm.200801861 ↗
18. Chen JF, Ding HM, Wang JX, Shao L (2004) Preparation and characterization of porous hollow silica nanoparticles for drug delivery application. Biomaterials 25:723–72710.1016/S0142-9612(03)00566-0 ↗
19. Mahmoodi NM, Khorramfar S, Najafi F (2011) Amine-functionalized silica nanoparticle: preparation, characterization and anionic dye removal ability. Desalination 279:61–6810.1016/j.desal.2011.05.059 ↗
20. Shen XC, Fang XZ, Zhou YH, Liang H (2004) Synthesis and characterization of 3-aminopropyltriethoxysilane-modified superparamagnetic magnetite nanoparticles. Chem Lett 33:1468–146910.1246/cl.2004.1468 ↗
21. Prado AGS, Airoldi C (2001) The pesticide 3-(3, 4-dichlorophenyl)-1, 1-dimethylurea (Diuron) immobilized on silica gel surface. J Colloid Interface Sci 236:1161–1165
22. Cui W, Wang S, Peng J, Zhang L, Zhang G (2016) Catechol-functionalized nanosilica for adsorption of germanium ions from aqueous media. J Sol-Gel Sci Technol 77:666–67410.1007/s10971-015-3898-7 ↗
23. Zhang L, Liu Y, Wang S, Liu B, Peng J (2015) Selective removal of cationic dyes from aqueous solutions by an activated carbon-based multicarboxyl adsorbent. RSC Adv 5(121):99618–9962610.1039/C5RA18093G ↗
24. Bai L, Hu H, Fu W, Wan J, Cheng X, Zhuge L, Xiong L, Chen Q (2011) Synthesis of a novel silica-supported dithiocarbamate adsorbent and its properties for the removal of heavy metal ions. J Hazard Mater 195:261–27510.1016/j.jhazmat.2011.08.038 ↗
25. Hong SG (1995) The thermal-oxidative degradation of an epoxy adhesive on metal substrates: XPS and RAIR analyses. Polym Degrad Stab 48(2):211–21810.1016/0141-3910(95)00042-K ↗
26. Zhang L, Liu Y, Wang S, Liu B, Peng J (2015) Selective removal of cationic dyes from aqueous solutions by an activated carbon-based multicarboxyl adsorbent. RSC Adv 5:99618–9962610.1039/C5RA18093G ↗
27. Castillo M, Criado A, Guzmán R, Criado JJ, Macias B (1987) Chemistry of dithiocarbamate derivatives of amino acids. Part III. X-ray photoelectron spectroscopy of Ba(S2CNHCH2CO2)·3H2O. Ir and esr studies of α-amino acid-dithiocarbamate complexes of copper (II). Transit Met Chem 12(3):225–22910.1007/BF01023535 ↗
28. Xing X, Yang H, Tao M, Zhang W (2015) An overwhelmingly selective colorimetric sensor for Ag+ using a simple modified polyacrylonitrile fiber. J Hazard Mater 297:207–21610.1016/j.jhazmat.2015.05.001 ↗