Synthesis of nanosized carbonated apatite by a modified Pechini method: hydroxyapatite nucleation from a polymeric matrix
Source abstract
Abstract
Pechini method is a materials synthesis method based on the preparation of a polymeric matrix. The advantage of this method is the ability to obtain materials with different particle sizes depending on the synthesis condition with a homogeneous distribution. In this work, carbonated hydroxyapatite (c-OHAp) nanoparticles were obtained by a modified Pechini method. To obtain the polymeric precursor of the c-OHAp, the polymeric matrix was prepared through a polyesterification reaction between citric acid and ethylene-glycol. Adding calcium hydroxide and ortophosphoric acid in aqueous solutions, raising the temperature up to 140 C/2 h and keeping constant the pH at 8. The polymeric matrix was calcinated at different ranges of temperature from 200 to 600 C in order to obtain the c-OHAp powder. The results show the presence of c-OHAp a as unique phase. The thermal analysis indicates that the c-OHAp phase was obtained at 600 C. The particle size of the obtained material was\50 nm
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Research context
OpenAlex topics: Bone Tissue Engineering Materials · Thermal and Kinetic Analysis · Additive Manufacturing and 3D Printing Technologies
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