journal article·2013-12

Features of sol–gel synthesis of new functional materials based on complex oxides with tunnel structure

O. Yu. Sinelshchikova, S. A. Petrov, N. V. Besprozvannykh, S. K. Kuchaeva, E. A. Vlasov

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Abstract

A new method of sol–gel synthesis has been proposed for fabrication of functional materials with ramsdellite and hollandite types of crystal structure in the following oxide systems: Me2O–Me′2O3–Me″O2 (Me = Li, K; Me′ = Ga, Cr, Fe, In; Me″ = Ti, Sn). The formation of titanates with ramsdellite-type structure is shown to achieve at the temperature range of 250–650 °C, when gel combustion occurs. This allows fabrication of materials with high specific surface area. The ramsdellite phases and stannate hollandites are shown to form in the temperature range of 1,100–1,150 °C. Thus our method gives the possibility to reduce the thermo-temporal parameters of synthesis for this class of materials.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Catalysis and Oxidation Reactions · Catalytic Processes in Materials Science · Pigment Synthesis and Properties

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References (10)

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1. Van Thournout M, Aldon L, Womesa M (2007) Metal-doped Li2Ti3O7 with ramsdellite structure as high voltage anode for new generation Li-ion batteries. J Power Sources 174:1270–127410.1016/j.jpowsour.2007.06.094 ↗
2. Aldon L, Van Thournout M, Strobel P (2006) Neutron diffraction and Mössbauer studies of iron substituted Li2Ti3O7 of ramsdellite-type as negative electrode for Li-ion accumulator. Solid State Ion 177:1185–119110.1016/j.ssi.2006.03.029 ↗
3. Hiroshi A, Mayumi Y, Naoto Y (2004) Electrochemical capacitor and hybrid power source constituted of it. Patent Japan. No 221523(A), 5 Aug 2004
4. Watanabe M, Mori T, Yamauchi S (1995) Catalytic property of the hollandite-type 1-D ion-conductors: selective reduction of NOx. Solid States Ion 79:376–38110.1016/0167-2738(95)00091-J ↗
5. Mori T, Yamauchi S, Yamamura H (1995) New hollandite catalyst for the selective reduction of nitrogen monoxide with propene. Appl Catal A Gen 129:1–710.1016/0926-860X(95)00115-8 ↗
6. Sinel’shchikova OY, Petrov SA, Kuchaeva SK (2011) Synthesis and study of novel catalysts based on hollandite K2Ga2Ti6O16. Glass Phys Chem 37:584–594
7. Khol’kin AK, Patrusheva TN (2006) Ekstraktsionno-piroliticheskii metod. Poluchenie funktsional’nykh oksidnykh materialov (Extraction pyroletic method: preparation of functional oxide materials). KomKniga, Moscow [in Russian]
8. Zhuravlev VD, Bamburov VG, Ostroushko AA (2007) Synthesis of oxide materials by pyrolysis. In: Abstracts of papers of the 7th international scientific conference “solid state chemistry and contemporary micro- and nanotechnologies”. Kislovodsk, pp 149–150
9. Petrov SA, Grigor’eva LF, Sinel’shchikova OYu (2008) Physicochemical prerequisites of the synthesis of new ionic conductors based on complex oxides with a ramsdellite-type structure. Glass Phys Chem 34:449–46010.1134/S1087659608040123 ↗
10. Petrov SA, Grigor’eva LF, Sazeev IYu (1994) Some crystal chemical features of phases with a hollandite structure crystallizing in the K2O-MO(M2O3)-TiO2 (M = Mg, Zn, Ga) and M′2 O-MgO-TiO2 (M` = Li, K, Rb, Cs) systems. Izv Ross Akad Nauk Neorg Mater 30:963–966