journal article·2013-05

Orientation dependence of the dielectric and piezoelectric properties for the Ba0.98Ca0.02Ti0.96Sn0.04O3 thin films

Wei Li, Jigong Hao, Wangfeng Bai, Jiwei Zhai

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Abstract

Lead free Ba0.98Ca0.02Ti0.96Sn0.04O3 (BCST) thin films with (110), (111) and (001) orientations were processed via chemical solution deposition, and effects of orientation on the dielectric and piezoelectric properties were investigated in some aspects. The (110) orientated BCST thin films exhibit highest Curie temperature (T c of 85 °C) and lowest dielectric loss (tan δ of 0.02). While, the (111) orientated BCST thin films exhibit highest dielectric tunability (74 %) and largest piezoelectric coefficient (d 33 of 78 pm/V), which indicate that it is a promising lead-free replacement for lead-based applications. The anisotropic dielectric and piezoelectric properties in the three kinds of oriented BCST films has been attributed to the difference of structure, in-plane stress and polarization rotation in orientation engineered BCST films. This work clearly reveals the dielectric and piezoelectric properties of BCST films exhibit a strong sensitivity to orientation.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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