journal article·2019-02

Novel and inexpensive Nb2O5/tannin-formaldehyde xerogel composites as substitutes for titanium dioxide in photocatalytic processes

Nicolas Perciani de Moraes, Leticia Araujo Bacetto, Livia Kent Paiva, Gabriela Spirandelli dos Santos, Maria Lucia Caetano Pinto da Silva, Liana Alvares Rodrigues

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Abstract

This project studied the preparation of new Nb2O5/tannin-formaldehyde xerogel composites (XTF-wNb) for photocatalytical applications. The choice of tannin biomass and niobium recycled scraps as precursors is aimed at reducing costs and environmental impacts. The composites were characterized by diffuse reflectance spectroscopy (DR), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), infrared spectroscopy (IR), and X-ray diffraction (XRD). The photocatalytic properties of the composites were evaluated by methylene blue decomposition. The influence of the catalyst dosage and the initial concentration of dye in the adsorption and photocatalysis processes were studied. The X-ray profiles of the XTF-wNb show the presence of niobic acid in the structure of the materials, proving the presence of the inorganic oxide in the matrix of these composites. The tannin/Nb ratio had a significant influence on the morphology of the formed composites, causing changes in the shape and size of the particles composing each material. All materials have pHPZC < 5. The XTF-24Nb was the most effective photocatalyst, its photocatalytic efficiency superior to the one of titanium dioxide, evidencing the beneficial effect of the xerogel coupling on the photocatalytic properties of the material.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Aerogels and thermal insulation · Advanced Photocatalysis Techniques · Pigment Synthesis and Properties

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