journal article·2017-12

Synthesis and characterization of composite materials “aerogel-MWCNT”

N. Menshutina, S. Ivanov, P. Tsygankov, I. Khudeev

Publisher page

Abstract

Composite materials “aerogel—multi-walled carbon nanotubes” were prepared and characteristics of these materials were investigated. Multi-walled carbon nanotubes were embedded into silica and alginate aerogels at stage of sol. Effects of the multi-walled carbon nanotubes embedding on porosity, specific surface area and pore size distribution were analyzed. Multi-walled carbon nanotubes concentration ranged from 0 to 4.5 wt% for silica aerogel and from 0 to 30 wt% for alginate aerogel. It was observed that multi-walled carbon nanotubes occupy pores with diameter of 30–40 nm that correspond to the carbon nanotube diameter. BET analysis using nitrogen adsorption revealed the specific surface areas within 737–780 m2/g range for the composite “silica aerogel—multi-walled carbon nanotubes” and 317–459 m2/g range for the composite “alginate aerogel—multi-walled carbon nanotubes”.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Aerogels and thermal insulation · Supercapacitor Materials and Fabrication · Mesoporous Materials and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. González A, Goikolea E, Barrena JA, Mysyk R (2016) Review on supercapacitors: technologies and materials. Renew Sustainable Energy Rev 58:1189–120610.1016/j.rser.2015.12.249 ↗
2. Yang X et al. (2015) Carbon aerogel with 3-D continuous skeleton and mesopore structure for lithium-ion batteries application. Mater Chem Phys 149:657–66210.1016/j.matchemphys.2014.11.023 ↗
3. Lee EJ, Lee YJ, Kim JK, Lee M, Yi J, Yoon JR et al. (2015) Oxygen group-containing activated carbon aerogel as an electrode material for supercapacitor. Mater Res Bull 70:209–21410.1016/j.materresbull.2015.04.044 ↗
4. Li C, Yang X, Zhang G (2015) Mesopore-dominant activated carbon aerogels with high surface area for electric double-layer capacitor application. Mater Lett 161:538–54110.1016/j.matlet.2015.09.003 ↗
5. Yang X, Wei C, Zhang G (2016) Activated carbon aerogels with developed mesoporosity as high-rate anodes in lithium-ion batteries. J Mater Sci 51(11):5565–557110.1007/s10853-016-9861-3 ↗
6. Lee YJ, Park HW, Kim GP, Yi J, Song IK (2013) Supercapacitive electrochemical performance of graphene-containing carbon aerogel prepared using polyethyleneimine-modified graphene oxide. Curr Appl Phys 13(5):945–94910.1016/j.cap.2013.02.005 ↗
7. Yang X et al. (2014) Ammonia-assisted semicarbonization: a simple method to introduce micropores without damaging a 3D mesoporous carbon nanonetwork structure. Langmuir 30(30):9183–918910.1021/la5008846 ↗
8. Kalpana D, Omkumar KS, Kumar SS, Renganathan NG (2006) A novel high power symmetric ZnO/carbon aerogel composite electrode for electrochemical supercapacitor. Electrochim Acta 52(3):1309–131510.1016/j.electacta.2006.07.032 ↗
9. Wei TY, Chen CH, Chang KH, Lu SY, Hu CC (2009) Cobalt oxide aerogels of ideal supercapacitive properties prepared with an epoxide synthetic route. Chem Mater 21(14):3228–323310.1021/cm9007365 ↗
10. Hrubesh LW, Pekala RW (1994) Thermal properties of organic and inorganic aerogels. J Mater Res 9(03):731–73810.1557/JMR.1994.0731 ↗
11. Hegde ND, Hirashima H, Rao AV (2007) Two step sol-gel processing of TEOS based hydrophobic silica aerogels using trimethylethoxysilane as a co-precursor. J Porous Mater 14(2):165–17110.1007/s10934-006-9021-2 ↗
12. Lu X, Arduini-Schuster MC (1992) Thermal conductivity of monolithic organic aerogels. Science 255(5047):97110.1126/science.255.5047.971 ↗
13. Hardin BE, Snaith HJ, McGehee MD (2012) The renaissance of dye-sensitized solar cells. Nat Photon 6(3):162–16910.1038/nphoton.2012.22 ↗
14. Chiang YC, Cheng WY, Lu SY (2012) Titania aerogels as a superior mesoporous structure for photoanodes of dye-sensitized solar cells. Int J Electrochem Sci 7:6910–691910.1016/S1452-3981(23)15757-9 ↗
15. Biener J, Stadermann M, Suss M, Worsley MA, Biener MM, Rose KA, Baumann TF (2011) Advanced carbon aerogels for energy applications. Energy Environ Sci 4(3):656–66710.1039/c0ee00627k ↗
16. Baumann TF, Worsley MA, Han TYJ, Satcher JH (2008) High surface area carbon aerogel monoliths with hierarchical porosity. J Non-Crystalline Solids 354(29):3513–351510.1016/j.jnoncrysol.2008.03.006 ↗
17. Cui S, Cheng W, Shen X, Fan M, Russell AT, Wu Z, Yi X (2011) Mesoporous amine-modified SiO 2 aerogel: a potential CO 2 sorbent. Energy Environ Sci 4(6):2070–207410.1039/c0ee00442a ↗
18. Saquing CD, Cheng TT, Aindow M, Erkey C (2004) Preparation of platinum/carbon aerogel nanocomposites using a supercritical deposition method. J Phys Chem B 108(23):7716–772210.1021/jp049535v ↗
19. Ulker Z, Sanli D, & Erkey C (2014) Applications of aerogels and their composites in energy-related technologies. Supercritical Fluid Technol Energy Environ Appl 157–18010.1016/B978-0-444-62696-7.00008-3 ↗
20. Goldberg G, Dodiuk H, Kenig S, Cohen R, Tenne R (2014) The effect of tungsten disulfide nanotubes on the properties of silicone adhesives. Int J Adhesion Adhesives 55:77–8110.1016/j.ijadhadh.2014.07.001 ↗
21. Sedova A, Bar G, Goldbart O, Ron R, Achrai B, Kaplan-Ashiri I et al. (2015) Reinforcing silica aerogels with tungsten disulfide nanotubes. J Supercritical Fluids 106:9–1510.1016/j.supflu.2015.07.018 ↗
22. Hamilton, CE et al. (2010) “Carbon nanomaterials in silica aerogel matrices.” MRS Proceedings Vol. 1258. Los Alamos National Laboratory, Los Alamos NM, USA: Cambridge University Press
23. Song X-Y et al. (1995) Carbon nanostructures in silica aerogel composites. J Mater Res 10(02):251–25410.1557/JMR.1995.0251 ↗
24. Zhang Y et al. (2006) Reinforcement of silica with single-walled carbon nanotubes through covalent functionalization. J Mater Chem 16(47):4592–459710.1039/b612317a ↗
25. Jung I-k et al. (2012) Silica xerogel films hybridized with carbon nanotubes by single step sol–gel processing. J Non-Cryst Solids 358(3):550–55610.1016/j.jnoncrysol.2011.11.009 ↗
26. Chernov AI et al. (2016) Optical properties of silica aerogels with embedded multiwalled carbon nanotubes. Phys Status Solidi B 253(12):2440–244510.1002/pssb.201600326 ↗
27. Huang J et al. (2016) Hierarchical porous MWCNTs-silica aerogel synthesis for high-efficiency oily water treatment. J Environ Chem Eng 4(3):3274–328210.1016/j.jece.2016.06.039 ↗
28. Purohit R, Purohit K, Rana S, Rana RS, Patel V (2014) Carbon nanotubes and their growth methods. Procedia Mater Sci 6:716–72810.1016/j.mspro.2014.07.088 ↗
29. Hoffmann H, Meyer M, Zeitler I (2006) Control of morphology inside the mesoporous gelstructure in silica-gels. Colloids Surf A 291(1):117–12710.1016/j.colsurfa.2006.07.032 ↗
30. Chan Z et al. (2007) Effect of doping levels on the pore structure of carbon nanotube/silica xerogel composites. Mater Lett 61(3):644–64710.1016/j.matlet.2006.05.074 ↗
31. Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC technical report). Pure Appl Chem 87(9–10):1051–106910.1515/pac-2014-1117 ↗