DataVXJournal of Sol-Gel Science and TechnologyPaper
journal article·2024-01

Effect of Ni2+and Co2+ substitution on the characteristics of the strontium aluminum hexaferrite (SrAl2Fe10O19)

Himani Joshi, A. Ruban Kumar

Journal of Sol-Gel Science and Technology· Volume 109· Issue 1
Publisher page
Source abstract

Abstract

Abstract The nickel and cobalt substituted strontium aluminium hexaferrite Sr1 − xNixAl2Fe10O19/Sr1 − xCoxAl2Fe10O19 (x = 0.1, 0.2) were synthesized via the sol-gel auto-combustion technique using glycine fuel. The particles formed in hexagonal crystal structure with space group P63/mmc. The field-emission scanning microscopy was adopted for morphological analysis, and the images revealed the plate-like formation of the particles. X-ray photoelectron spectroscopy confirmed the presence and oxidation states of all the elements. The vibrating sample magnetometer studies were taken to determine saturation magnetization (Ms), coercivity (Hc), squareness ratio (Mr/Ms), and energy product (BHmax) values. The electric studies disclosed the presence of relaxations in the system, which was interpreted through Koop and Maxwell-Wagner's model.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Multiferroics and related materials · Magneto-Optical Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. Liaquat A, Anis-ur-Rehman M, ul Haq A (2020) Impact of Gd doping on the dielectric and magnetic properties of (Sr–Ba) Fe12O19 nanoparticles. J Alloy Compd 822:153561. https://doi.org/10.1016/j.jallcom.2019.15356110.1016/j.jallcom.2019.153561 ↗
2. Kumar A, Verma MK, Singh S et al. (2020) Electrical, magnetic and dielectric properties of cobalt-doped barium hexaferrite BaFe12−xCoxO19 (x = 0.0, 0.05, 0.1 and 0.2) ceramic prepared via a chemical route. J Electron Mater 49:6436–6447. https://doi.org/10.1007/s11664-020-08364-810.1007/s11664-020-08364-8 ↗
3. Rehman MR, Akram MA, Gul IH (2022) Improved electrical properties of strontium hexaferrite nanoparticles by Co2+ substitutions. ACS Omega 7:43432–43439. https://doi.org/10.1021/acsomega.2c0325610.1021/acsomega.2c03256 ↗
4. Chen N, Yang K, Gu M (2010) Microwave absorption properties of La-substituted M-type strontium ferrites. J Alloy Compd 490:609–612. https://doi.org/10.1016/j.jallcom.2009.10.11610.1016/j.jallcom.2009.10.116 ↗
5. Pullar RC (2012) Hexagonal ferrites: a review of the synthesis, properties and applications of hexaferrite ceramics. Prog Mater Sci 57:1191–1334. https://doi.org/10.1016/j.pmatsci.2012.04.00110.1016/j.pmatsci.2012.04.001 ↗
6. Vinnik DA, Trukhanov AV, Podgornov FV et al. (2020) Correlation between entropy state, crystal structure, magnetic and electrical properties in M-type Ba-hexaferrites. J Eur Ceram Soc 40:4022–4028. https://doi.org/10.1016/j.jeurceramsoc.2020.04.03610.1016/j.jeurceramsoc.2020.04.036 ↗
7. VE Zhivulin, OV Zaitseva, EA Trofimovo, et al (2021) Anisotropy of the electrical properties of a single crystal of BaFe11.25Ti0.75O19 M-type barium hexaferrite. J Solid State Chem 298. https://doi.org/10.1016/j.jssc.2021.12210410.1016/j.jssc.2021.122104 ↗
8. Buzinaro MAP, Macêdo MA, Costa BFO, Ferreira NS (2019) Disorder of Fe(2)O5 bipyramids and spin-phonon coupling in SrFe 12 O 19 nanoparticles. Ceram Int 45:13571–13574. https://doi.org/10.1016/j.ceramint.2019.03.21410.1016/j.ceramint.2019.03.214 ↗
9. Saafan SA, Assar ST, Mansour SF (2012) Magnetic and electrical properties of Co1-xCaxFe2O4 nanoparticles synthesized by the auto combustion method. J Alloy Compd 542:192–198. https://doi.org/10.1016/j.jallcom.2012.07.05010.1016/j.jallcom.2012.07.050 ↗
10. Kishor G, Bhowmik RN, Sinha AK (2022) Structural phase stabilization via Ba site doping with bivalent Sr, Ca and Zn ions and Fe site doping with trivalent Cr and Ga ions in the BaFe12O19 hexaferrite and its magnetic modification. CrystEngComm 24:5269–5288. https://doi.org/10.1039/d2ce00583b10.1039/d2ce00583b ↗
11. G Han, R Sui, Y Yu, et al (2021) Structure and magnetic properties of the porous Al-substituted barium hexaferrites. J Magn Magn Mater 528:1–7.10.1016/j.jmmm.2021.167824 ↗
12. Trusov LA, Gorbachev EA, Lebedev VA et al. (2018) Ca-Al double-substituted strontium hexaferrites with giant coercivity. Chem Commun 54:479–482. https://doi.org/10.1039/c7cc08675j10.1039/c7cc08675j ↗
13. XM Ma, J Liu, SZ Zhu, HG Shi (2016) Tuning of magnetic properties of aluminium-doped strontium hexaferrite powders. Chin Phys B 25: https://doi.org/10.1088/1674-1056/25/12/12610210.1088/1674-1056/25/12/126102 ↗
14. Irshad Z, Bibi I, Ghafoor A et al. (2022) Results in physics Ni doped SrFe12O19 nanoparticles synthesized via micro-emulsion route and photocatalytic activity evaluation for the degradation of crystal violet under visible light irradiation. Results Phys 42:106006. https://doi.org/10.1016/j.rinp.2022.10600610.1016/j.rinp.2022.106006 ↗
15. V Dixit, SG Kim, J Park, YK Hong (2017) Effect of ionic substitutions on the magnetic properties of strontium hexaferrite: a first principles study. AIP Adv 7. https://doi.org/10.1063/1.499530910.1063/1.4995309 ↗
16. Alna’washi GA, Alsmadi AM, Bsoul I et al. (2021) Investigation on X-ray photoelectron spectroscopy, structural and low temperature magnetic properties of Ni-Ti co-substituted M-type strontium hexaferrites prepared by ball milling technique. Results Phys 28:104574. https://doi.org/10.1016/j.rinp.2021.10457410.1016/j.rinp.2021.104574 ↗
17. Godara SK, Singh M, Kaur V et al. (2021) Effect of calcium solubility on structural, microstructural and magnetic properties of M-type barium hexaferrite. Ceram Int 47:20399–20406. https://doi.org/10.1016/j.ceramint.2021.04.04810.1016/j.ceramint.2021.04.048 ↗
18. Godara SK, Kaur V, Narang SB et al. (2021) Tailoring the magnetic properties of M-type strontium ferrite with synergistic effect of co- substitution and calcinations temperature. J Asian Ceram Soc 9:686–698. https://doi.org/10.1080/21870764.2021.191105910.1080/21870764.2021.1911059 ↗
19. Sharma A, Jasrotia R, Kumari N et al. (2022) Tailoring the structural and magnetic traits of copper modified BaFe12O19 nanostructured hexaferrites for recording media application. J Magn Magn Mater 564:170124. https://doi.org/10.1016/j.jmmm.2022.17012410.1016/j.jmmm.2022.170124 ↗
20. R Jasrotia, N Kumari, R Verma, et al. (2023) Effect of rare earth (Nd3+) metal doping on structural, morphological, optical and magnetic traits of Zn–Mg nano-ferrites. J Rare Earths https://doi.org/10.1016/j.jre.2022.08.01510.1016/j.jre.2022.08.015 ↗
21. Godara SK, Kaur V, Chuchra K et al. (2021) Impact of Zn2+-Zr4+ substitution on M-type Barium Strontium Hexaferrite’s structural, surface morphology, dielectric and magnetic properties. Results Phys 22:103892. https://doi.org/10.1016/j.rinp.2021.10389210.1016/j.rinp.2021.103892 ↗
22. Godara SK, Kaur V, Narang SB et al. (2019) Tunable M-type nano barium hexaferrite material by Zn2+/Zr4+ co-doping. Mater Res Express 6:11611110.1088/2053-1591/ab4894 ↗
23. Kumar S, Kaur T, Kumar S, Srivastava AK (2015) Effect of heat treatment on properties of Sr0.7Nd0.3Co0.3Fe11.7O19. J Supercond Nov Magn 28:2935–2940. https://doi.org/10.1007/s10948-015-3105-710.1007/s10948-015-3105-7 ↗
24. Godara SK, Dhaka RK, Kaur N et al. (2021) Synthesis and characterization of Jamun pulp-based M-type barium hexaferrite via sol–gel auto-combustion. Results Phys 22:103903. https://doi.org/10.1016/j.rinp.2021.10390310.1016/j.rinp.2021.103903 ↗
25. Zahid M, Siddique S, Anum R et al. (2021) M-type barium hexaferrite-based nanocomposites for EMI shielding application: a review. J Supercond Nov Magn 34:1019–104510.1007/s10948-021-05859-1 ↗
26. Joshi H, Kumar AR (2022) Investigations and correlations of structural, magnetic, and dielectric properties of M-type barium hexaferrite (BaFe12O19) for hard magnet applications. J Supercond Nov Magn 35:2435–2451. https://doi.org/10.1007/s10948-022-06203-x10.1007/s10948-022-06203-x ↗
27. Yang Y, Wang F, Shao J et al. (2019) Structural, spectral, magnetic, and electrical properties of Gd–Co-co-substituted M-type Ca–Sr hexaferrites synthesized by the ceramic method. Appl Phys A Mater Sci Process 125:1–13. https://doi.org/10.1007/s00339-018-2339-110.1007/s00339-018-2339-1 ↗
28. Rashad MM, Rasly M, El-Sayed HM et al. (2013) Controlling the composition and the magnetic properties of hexagonal Co2Z ferrite powders synthesized using two different methods. Appl Phys A Mater Sci Process 112:963–973. https://doi.org/10.1007/s00339-012-7456-710.1007/s00339-012-7456-7 ↗
29. SK Godara, M Singh, V Kaur, et al (2022) Effect of calcium solubility on structural, microstructure and magnetic properties of SrFe12O19. Phys B Condens Matter 628. https://doi.org/10.1016/j.physb.2021.413560.10.1016/j.physb.2021.413560 ↗
30. Gupta A, Kar M, Roy PK (2022) Substitutional effect of Ni-Al in electromagnetic properties of Sr-hexaferrite based non-rare earth magnet with high energy density for motor applications. Mater Chem Phys 292:126842. https://doi.org/10.1016/j.matchemphys.2022.12684210.1016/j.matchemphys.2022.126842 ↗
31. Verma S, Singh A, Sharma S et al. (2023) Magnetic and structural analysis of BaZnxZrxFe12–2xO19 (x = 0.1–0.7) hexaferrite samples for magnetic applications. J Alloy Compd 930:167410. https://doi.org/10.1016/j.jallcom.2022.16741010.1016/j.jallcom.2022.167410 ↗
32. Mehmood S, Anis-ur-Rehman M (2020) Association of structural strains and dielectric relaxation in Co-doped Sr-Hexaferrites. Phys B Condens Matter 582:412003. https://doi.org/10.1016/j.physb.2020.41200310.1016/j.physb.2020.412003 ↗
33. Gupta A, Roy PK (2021) Synthesis and tuning the electro-magnetic properties of Co-Cr substituted Sr-hexaferrite towards diverse usages. Mater Sci Eng B Solid State Mater Adv Technol 263:114815. https://doi.org/10.1016/j.mseb.2020.11481510.1016/j.mseb.2020.114815 ↗
34. Sriramulu G, Maramu N, Reddy BR et al. (2022) Structural, magnetic and electromagnetic properties of microwave-hydrothermally synthesized Sr(Zr-Mn)2xFe12-2xO19 hexaferrites. Mater Res Bull 149:111732. https://doi.org/10.1016/j.materresbull.2022.11173210.1016/j.materresbull.2022.111732 ↗
35. S Thakur, B Raina, KK Bamzai (2022) Investigations on structural, spectroscopic and magnetic properties of yttrium barium orthoferrite and nickel doped strontium hexaferrite composites. Appl Phys A Mater Sci Process 128. https://doi.org/10.1007/s00339-022-05399-y10.1007/s00339-022-05399-y ↗
36. T Yener, İ Araz, A Kırsoy, et al (2022) Electromagnetic properties in the structure of cerium-copper substituted barium hexaferrite. J Mol Struct 1269. https://doi.org/10.1016/j.molstruc.2022.13375210.1016/j.molstruc.2022.133752 ↗
37. VE Zhivulin, EA Trofimov, OV Zaitseva, et al (2022) Effect of configurational entropy on phase formation, structure, and magnetic properties of deeply substituted strontium hexaferrites. Ceram Int https://doi.org/10.1016/j.ceramint.2022.09.08210.1016/j.ceramint.2022.09.082 ↗
38. Tang R, Jiang C, Qian W et al. (2015) Dielectric relaxation, resonance and scaling behaviors in Sr3Co2Fe24O41 hexaferrite. Sci Rep. 5:1–11. https://doi.org/10.1038/srep1364510.1038/srep13645 ↗
39. Rusevich LL, Kotomin EA, Zvejnieks G et al. (2022) Effects of Al Doping on Hydrogen Production Efficiency upon Photostimulated Water Splitting on SrTiO3Nanoparticles. J Phys Chem C 126:21223–21233. https://doi.org/10.1021/acs.jpcc.2c0599310.1021/acs.jpcc.2c05993 ↗
40. Anantharamaiah PN, Shashanka HM, Srinivasan S et al. (2022) Structural, magnetic, and magnetostriction properties of flexible, nanocrystalline CoFe2O4 films made by chemical processing. ACS Omega 7:43813–43819. https://doi.org/10.1021/acsomega.2c0494310.1021/acsomega.2c04943 ↗
41. Joshi H, Kumar AR (2021) Scrutiny and correlations of structural, magnetic, and dielectric properties of M-type strontium hexaferrite (SrFe12O19) for permanent magnet applications. J Mater Sci Mater Electron 32:4331–4346. https://doi.org/10.1007/s10854-020-05176-810.1007/s10854-020-05176-8 ↗
42. Dagar S, Hooda A, Khasa S, Malik M (2020) Structural refinement, investigation of dielectric and magnetic properties of NBT doped BaFe12O19 novel composite system. J Alloy Compd 826:154214. https://doi.org/10.1016/j.jallcom.2020.15421410.1016/j.jallcom.2020.154214 ↗
43. Pandey R, Kumar Pradhan L, Kumari S et al. (2020) Surface magnetic interactions between Bi0.85La0.15FeO3 and BaFe12O19 nanomaterials in (1-x)Bi0.85La0.15FeO3-(x)BaFe12O19 nanocomposites. J Magn Magn Mater 508:166862. https://doi.org/10.1016/j.jmmm.2020.16686210.1016/j.jmmm.2020.166862 ↗
44. Basha DB, Kumar NS, Kumar GR, et al (2022) Structural, electrical, and magnetic properties of nano Sr1-XLaXFe12O19 (X = 0. 2 - 0. 8)10.21203/rs.3.rs-1420921/v1 ↗
45. Z Li, V Koval, A Mahajan, et al (2020) Room-temperature multiferroic behavior in layer-structured Aurivillius phase ceramics. Appl Phys Lett 117. https://doi.org/10.1063/5.001778110.1063/5.0017781 ↗
46. A Hilczer, K Pasińska (2022) Dielectric response of Sr0.95Nd0.05Fe12-xScxO19 hexaferrites nanoceramics as dependent on crystal and microstructure and ceramic heterogeneity. J Alloys Compd 893. https://doi.org/10.1016/j.jallcom.2021.16230310.1016/j.jallcom.2021.162303 ↗
47. MR Rehman, MA Akram, IH Gul (2022) Improved electrical properties of strontium hexaferrite nanoparticles by Co2+ substitutions. ACS Omega https://doi.org/10.1021/acsomega.2c0325610.1021/acsomega.2c03256 ↗
48. Khadhraoui S, Triki A, Hcini S et al. (2014) Variable-range-hopping conduction and dielectric relaxation in Pr 0.6Sr0.4Mn0.6Ti0.4O 3±δ perovskite. J Magn Magn Mater 371:69–76. https://doi.org/10.1016/j.jmmm.2014.07.04410.1016/j.jmmm.2014.07.044 ↗
49. Rahmouni H, Smari M, Cherif B et al. (2015) Conduction mechanism, impedance spectroscopic investigation and dielectric behavior of La0.5Ca0.5-xAgxMnO3 manganites with compositions below the concentration limit of silver solubility in perovskites (0 ≤ x ≤ 0.2). Dalton Trans 44:10457–10466. https://doi.org/10.1039/c5dt00444f10.1039/c5dt00444f ↗
50. Lobo LS, Kalainathan S, Kumar AR (2015) Investigation of electrical studies of spinel FeCo2O4 synthesized by sol-gel method. Superlattices Microstruct 88:116–126. https://doi.org/10.1016/j.spmi.2015.09.01010.1016/j.spmi.2015.09.010 ↗
51. Thansanga L, Shukla A, Kumar N, Choudhary RNP (2020) Study of effect of Dy substitution on structural, dielectric, impedance and magnetic properties of bismuth ferrite. J Mater Sci Mater Electron 31:10006–10017. https://doi.org/10.1007/s10854-020-03545-x10.1007/s10854-020-03545-x ↗
52. Tanwar K, Gyan DS, Gupta P et al. (2018) Investigation of crystal structure, microstructure and low temperature magnetic behavior of Ce4+ and Zn2+ co-doped barium hexaferrites (BaFe12O19). RSC Adv 8:19600–19609. https://doi.org/10.1039/C8RA02455C10.1039/C8RA02455C ↗
53. Almessiere MA, Unal B, Slimani Y et al. (2019) Results in physics electrical and dielectric properties of Nb 3 + ions substituted Ba-hexaferrites. Results Phys 14:102468. https://doi.org/10.1016/j.rinp.2019.10246810.1016/j.rinp.2019.102468 ↗