Structure engineering of Fe-based MOF aerogel by Halloysite Nanotubes for efficient methylene blue adsorption
Source abstract
Abstract
Halloysite Nanotubes (HNTs) with large surface/volume ratio and rich reactive groups are incorporated into Fe-based MOF aerogel to develop MOF(Fe)/HNTs composite aerogels for efficient methylene blue (MB) adsorption. A sol–gel method along with supercritical drying technology is applied for the preparation of the MOF(Fe)/HNTs composite aerogels. Micro-morphology and pore structure of the aerogels are properly regulated by controlling the addition amount of HNTs. The obtained samples show three-dimensional mesoporous network structures. The addition of HNTs can slightly increase the specific surface area of the aerogel and then decrease gradually with the increase of HNTs content. The MOF(Fe)/HNTs composite aerogels show favorable adsorption property towards MB and the maximum adsorption capacity can be 384 mg/g with the adsorption efficiency of 96.1%. Besides, the adsorption kinetic analysis reveals that the adsorption process of the MOF(Fe)/HNTs composite aerogel follows the pseudo-second-order model, indicating that chemical sorption may be the rate-limiting step.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Metal-Organic Frameworks: Synthesis and Applications · Geochemistry and Elemental Analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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