journal article·2013-04

Hybrid polymer sol–gel material for UV-nanoimprint: microstructure and thermal densification

Franziska Back, Matthias Bockmeyer, Eveline Rudigier-Voigt, Peer Löbmann

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Abstract

Hybrid polymer solutions suitable for UV-nanoimprint were synthesized by combination of an alkoxysilane binder mixture with silica nanoparticles. Hydrolysis and condensation reactions were monitored by NMR and viscosity measurements. Thereby long-term stable systems were produced as a prerequisite for industrial application. Dip-coating of glass substrates and subsequent UV-curing yielded thin films. Their thermal densification and microstructural evolution resulted in pure glassy porous coatings, which were in detail characterized by N2-sorption measurements and ellipsometric porosimetry. Results emphasize the importance of the binder-particle interaction within these materials that are destined for the fabrication of microstructured surfaces by cost efficient and industrially feasible UV-based soft lithography. Structured glassy layers with high inorganic content show thermal stability up to >500 °C and have a high structure accuracy >85 %.
Source: openaire · Quality: candidate unverified · Source record ↗

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OpenAlex topics: Nanofabrication and Lithography Techniques · Advancements in Photolithography Techniques · Photonic Crystals and Applications

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