Synthesis of pore-expanded mesoporous ZIF-8/silica composites in the presence of swelling agent
Source abstract
Abstract
The synthesis of mesoporous zeolitic imidazolate framework-8/silica composites with foam-like structure templated by Pluronic P123 (EO 20 PO 70 EO 20 ) block copolymer surfactant in the presence of swelling agent was demonstrated in this study. It was found that 1,3,5-trimethylbenzene was a suitable swelling agent, which worked effectively in the pluronic-P123-templated synthesis of zeolitic imidazolate framework-8/silica composites when a moderate amount was added. The pore diameter of the foams in resulting composites increased to 50–60 nm when the 1,3,5-trimethylbenzene /P123 weight ratio of 3/4 was used during the synthesis. In addition, the composite with enlarged diameter of foams showed superior adsorption capacity to phthalic acid (H2-PA) at 20 °C in comparison with aggregated bulk zeolitic imidazolate framework-8.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Mesoporous Materials and Catalysis · Covalent Organic Framework Applications
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