journal article·2013-10

Synthesis of two-dimensional gallium nitride via spin coating method: influences of nitridation temperatures

C. Y. Fong, S. S. Ng, F. K. Yam, H. Abu Hassan, Z. Hassan

Publisher page

Abstract

This paper reports the synthesis and characterization of gallium nitride (GaN) thin films deposited on p-type silicon (100) substrates by using low cost spin coating method under various nitridation temperatures. This work demonstrated that spin coating with the new prepared precursor solution can be used as a versatile method for the successfully growth of GaN thin films. Furthermore, the influence of varying nitridation temperatures on the structural, morphological, and optical properties of synthesized GaN thin films were studied in this work. The GaN thin films were characterized by X-ray diffraction, field-emission scanning electron microscopy, atomic force microscopy, photoluminescence and Raman spectroscopy. All the characteristics of the GaN thin films were effectively improved with the increasing of the nitridation temperatures from 750 to 950 °C and degraded at temperature of 1,050 °C. The measured results show that nitridation temperature plays an important role in improving the crystalline quality of the GaN thin films and the most efficient nitridation temperature was at 950 °C.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: GaN-based semiconductor devices and materials · Ga2O3 and related materials · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (26)

Show source-provided references
1. Yang TH, Ku JT, Chang JR, Shen SG, Chen YC, Wong YY, Chou WC, Chen CY, Chang CY (2009) Growth of free-standing GaN layer on Si (111) substrate. J Cryst Growth 311:1997–200110.1016/j.jcrysgro.2008.10.099 ↗
2. Ma JH, Zhang H, Chen YJ, Fu L (2010) Synthesis, thermal stability, and photocatalytic activity of nanocrystalline gallium nitride via the reaction of Ga2O3 and NH4Cl at low temperature. J Alloy Compd 499:269–27210.1016/j.jallcom.2010.03.185 ↗
3. Wood AW, Collino RR, Wang PT, Wang YQ, Goldman RS (2012) Formation and transformation of embedded GaN nanocrystals. Appl Phys Lett 100:203113(203111)–203113(203114)
4. Wagner T, Puchinger M, Fini P, Kisailus D, Beck U, Bill J, Aldinger F, Arzt E, Lange FF (2001) Chemical solution deposition derived buffer layers for MOCVD-grown GaN films. J Cryst Growth 23:57–67
5. Liu HF, Chen H, Li ZQ, Wan L, Huang Q, Zhou JM, Yang N, Tao K, Han YJ, Luo Y (2000) MBE growth and Raman studies of cubic and hexagonal GaN films on (001)-oriented GaAs substrates. J Cryst Growth 218:191–19610.1016/S0022-0248(00)00574-1 ↗
6. Kim ST, Lee YJ, Chung SH, Moon DC (1998) Properties of Free-Standing GaN Prepared by HVPE Using AlN/Si Substrate. J Korean Phys Soc 33:313–315
7. Zhang CG, Chen WD, Bian LF, Song SF, Hsu CC (2006) Preparation and characterization of GaN films by radio frequency magnetron sputtering and carbonized-reaction technique. Appl Surf Sci 252:2153–215810.1016/j.apsusc.2005.03.209 ↗
8. Ogi T, Itoh Y, Abdullah M, Iskandar F, Azuma Y, Okuyama K (2005) Fabrication and photoluminescence of highly crystalline GaN and GaN:Mg nanoparticles. J Cryst Growth 281:234–24110.1016/j.jcrysgro.2005.04.021 ↗
9. Hashim MR, Al-Heuseen K (2011) One-step synthesis of GaN thin films on Si substrate by a convenient electrochemical technique at low temperature for different durations. J Cryst Growth 324:274–27710.1016/j.jcrysgro.2011.03.051 ↗
10. Iskandar F, Ogi T, Okuyama K (2006) Simple synthesis of GaN nanoparticles from gallium nitrate and ammonia aqueous solution under a flow of ammonia gas. Mater Lett 60:73–7610.1016/j.matlet.2005.07.075 ↗
11. Yoon DH, Yang JH, Kang SM, Dinh DV (2009) Influence of AlN buffer layer thickness and deposition methods on GaN epitaxial growth. Thin Solid Films 517:5057–506010.1016/j.tsf.2009.03.089 ↗
12. Abdullah QN, Yam FK, Hassan Z, Bououdina M (2013) Growth and conversion of b-Ga2O3 nanobelts into GaN nanowires via catalyst-free chemical vapor deposition technique. Superlattice Microst 54:215–22410.1016/j.spmi.2012.11.017 ↗
13. Manoharan PT, Thangadurai P, Balaji S (2009) Growth and mechanism of CdS nanorods by microstructure analysis. Mater Chem Phys 114:420–42410.1016/j.matchemphys.2008.09.048 ↗
14. Phuruangrat A, Thongtem T, Thongtem S (2010) Characterization of multipod cadmium sulfide nanostructures synthesized by aminethermal method. Chalcogenide Lett 7(8):605–608
15. Man BY, Xi HZ, Chen CS, Liu M, Wei J, Yang SY (2009) Effects of annealing temperature on amorphous GaN films formed on Si(1 1 1) by pulsed laser deposition. Semicond Sci Technol 24(085024):1–7
16. Xue SB, Zhang X, Huang R, Zhuang HZ (2009) A study on a two-step technique of growing Ga2O3/ZnO films ammoniated at different temperatures. Phys E 41:460–46410.1016/j.physe.2008.09.005 ↗
17. Wagner T, Puchinger M, Kisailus DJ, Lange FF (2002) Microstructural evolution of precursor-derived gallium nitride thin films. J Cryst Growth 245:219–22710.1016/S0022-0248(02)01712-8 ↗
18. Kisailus D, Choi JH, Lange FF (2002) Chemical solution deposited GaN films from oxygen- and nitrogen-based precursors. J Mater Res 17(10):2540–254810.1557/JMR.2002.0369 ↗
19. Lee YC, Hu SY, Water W, Tiong KK, Feng ZC, Chen YT, Huang JC, Lee JW, Huang CC, Shen JL, Cheng MH (2009) Rapid thermal annealing effects on the structural and optical properties of ZnO films deposited on Si substrates. J Luminesc 129:148–15210.1016/j.jlumin.2008.09.003 ↗
20. Xiao HD, Liu R, Liu JQ, Lin ZJ, Mei LM (2009) Growth process from amorphous GaN to polycrystalline GaN on Si (111) substrates. Vacuum 83:1393–139610.1016/j.vacuum.2009.04.052 ↗
21. Low LL, Yam FK, Beh KP, Hassan Z (2011) The influence of Ga source and substrate position on the growth of low dimensional GaN wires by chemical vapour deposition. Appl Surf Sci 257:10052–1005510.1016/j.apsusc.2011.06.138 ↗
22. Xiang X, Zhu H (2007) One-dimensional gallium nitride micro/nanostructures synthesized by a space-confined growth technique. Appl Phys A 87:651–65910.1007/s00339-007-3887-y ↗
23. Kuo SY, Lai FL, Chen WC, Hsiao CN (2008) Catalyst-free growth and characterization of gallium nitride nanorods. J Cryst Growth 310:5129–513310.1016/j.jcrysgro.2008.08.047 ↗
24. Chuah LS, Hassan Z, Ng SS, Hassan HA (2007) High carrier concentrations of n- and p-doped GaN on Si(111) by nitrogen plasma-assisted molecular-beam epitaxy. J Mater Res 22(9):2623–263010.1557/jmr.2007.0336 ↗
25. Davydov VY, Kitaev YE, Goncharuk IN, Smirnov AN, Graul J, Semchinova O, Uffmann D, Smirnov MB, Mirgorodsky AP, Evarestov RA (1998) Phonon dispersion and Raman scattering in hexagonal GaN and AlN. Phys Rev B 58(19):12899–1290710.1103/PhysRevB.58.12899 ↗
26. Perlin P, Carillon CJ, Itic JP, Miguel AS, Grzegory I, Polian A (1992) Raman scattering and x-ray-absorption spectroscopy in gallium nitride under high pressure. Phys Rev B 45(1):83–8910.1103/PhysRevB.45.83 ↗