journal article·2023-07Open access

Hybrid sol-gel materials for realization of radiation protective coatings—a review with emphasis on UV protective materials

Boris Mahltig, Tilmann Leisegang, Melanie Jakubik, Helfried Haufe

Abstract

Abstract This review reports on hybrid sol-gel coatings used for radiation protective purposes. The different types of electromagnetic radiation are usually distinguished by their wavelength, frequency or photon energy. There is a broad range of types of radiation that humans, materials or electric devices are exposed to, starting from radio waves, microwaves, infrared radiation, visible light, UV light, X-ray and gamma-ray radiation. Gamma-ray radiation is thus at the end of the electromagnetic spectrum with smallest wavelengths, highest frequencies and highest photon energies. Protection against radiation make sense, as it can pose health risks or interfere with technical and electronic equipment for example. Radiation protection can be realized by materials that are able to absorb or reflect the radiation, which leads to a considerable reduction in radiation transmission. These radiation protection materials are specific to different types of radiation or spectral widths, e.g., a material with excellent protective properties against UV light is not automatically suitable for protection against infrared light. The main aim of this review article is to report, what types of hybrid sol-gel materials can be used to provide ideal protection against a specific category of radiation. Additional to the broad view on all types of radiations, focusing in particular on materials exhibiting UV protective properties.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Skin Protection and Aging · Pigment Synthesis and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (67)

Show source-provided references
1. Zamanian A, Hardiman CJHFE (2005) Electromagnetic radiation and human health: a review of sources and effects. High Freq Electron 4:16–26
2. Hoque MT, Mahltig B (2020) Realisation of polyester fabrics with low transmission for ultraviolet light. Coloration Technol 136:346–35510.1111/cote.12470 ↗
3. Liu Y, Liu Y, Lin J, Tan H, Zhang C (2014) UV-protective treatment for Vectran® fibers with hybrid coatings of TiO2/organic UV absorbers. J Adhesion Sci Technol 28:1773–178210.1080/01694243.2014.921130 ↗
4. Luo Y-R (1999) Why is the human visual system sensitive only to light of wavelengths from approximately 760 to 380 nm?: an answer from thermochemistry and chemical kinetics. Biophys Chem 83:179–18410.1016/S0301-4622(99)00137-4 ↗
5. Kojima D, Mori S, Torii M, Wada A, Morishita R, Fukada Y (2011) UV-sensitive photoreceptor protein OPN5 in humans and mice. PLoS ONE 6(10):e26638810.1371/journal.pone.0026388 ↗
6. Wardman RH (2018) An introduction to textile coloration. John Wiley & Sons Ltd, Hoboken
7. Mahltig B, Zhang J, Wu L, Darko D, Wendt M, Lempa E, Rabe M, Haase H (2017) Effect pigments for textile coating: a review of the broad range of advantageous functionalization. J Coat Technol Res 14:35–5510.1007/s11998-016-9854-9 ↗
8. Yener SC, Cerezci O (2016) Material analysis and application for radio frequency electromagnetic wave shielding. Acta Phys Polonica A 129:635–63810.12693/APhysPolA.129.635 ↗
9. Geetha S, Kumar KKS, Rao CRK, Yijayan M, Trivedi DC (2009) EMI shielding: methods and materials – a review. J Appl Polym Sci 112:2073–208610.1002/app.29812 ↗
10. Poser M (2017) Elektrosmog. Crotona Verlag GmbH, Amerang
11. Topp K, Haase H, Degen C, Illing G, Mahltig B (2014) Coatings with metallic effect pigments for antimicrobial and conductive coating of textiles with electromagnetic shielding properties. J Coat Technol Res 11:943–95710.1007/s11998-014-9605-8 ↗
12. Gonzalez M, Soares BG, Magioli M, Marins JA, Rieumont J (2012) Facile method for synthesis of polyaniline/silica hybrid composites by simultaneous sol-gel process and “in situ” polymerization of aniline. J Sol-Gel Sci Technol 63:373–38110.1007/s10971-012-2796-5 ↗
13. Nasirizadeh N, Dehghani M, Yazdanshenas ME (2015) Preparation of hydrophobic and conductive cotton fabrics using multi-wall carbon nanotubes by the sol-gel method. J Sol-Gel Sci Technol 73:14–2110.1007/s10971-014-3488-0 ↗
14. An Z, Ye C, Zhang R, Qu Q (2019) Multifunctional C/SiO2/SiC-based aerogels and composites for thermal insulators and electromagnetic interference shielding. J Sol-Gel Sci Technol 89:623–63310.1007/s10971-019-04916-5 ↗
15. Reshi HA, Singh AP, Pillai S, Yadav RS, Dhawan SK, Shelke V (2015) Nanostructured La0.7Sr0.3MnO3 compounds for effective electromagnetic interference shielding in X-band frequency range. J Mater Chem C 3:820–82710.1039/C4TC02040E ↗
16. Stevanovic S (2013) Optimization of passive solar design strategies: a review. Renew Sustain Energy Rev 25:177–19610.1016/j.rser.2013.04.028 ↗
17. Sliney DH (2002) How light reaches the eye and its components. Int J Toxicol 21:501–50910.1080/10915810290169927 ↗
18. Rubežienė V, Padleckienė I, Baltušnikaitė J, Varnaitė S (2008) Evaluation of camouflage effectiveness of printed fabrics in visible and near infrared radiation spectral ranges. Mater Sci Medziagotyra 14:361–365
19. Rashid MM, Mahltig B, Mamun K (2019) Surface modification of cotton fabric with effect pigment – a review of improved textile optical functionalization. Int J Text Sci 8:10–15
20. Malshe VC, Bendiganavale AK (2008) Infrared reflective inorganic pigments. Recent Pat Chem Eng 1:67–7910.2174/2211334710801010067 ↗
21. Meenakshi P, Selvaraj M (2018) Bismuth titanate as an infrared reflective pigment for cool roof coating. Sol Energy Mater Sol Cells 174:530–53710.1016/j.solmat.2017.09.048 ↗
22. Mahltig B, Bendt E, Grethe T, Hess O, Weide T (2021) Biophysical concept for textile skin protection. Technical Textiles 64:154-15610.51202/0323-3243-2021-3-068 ↗
23. Gosh S, Biswas PK, Neogi S (2014) Effect of solar radiation at various incident angles on transparent conducting antimony doped indium oxide (IAO) film developed by sol-gel method on glass substrate as heat absorbing window glass fenestration. Sol Energy 109:54–6010.1016/j.solener.2014.08.020 ↗
24. Li F, Bao W, Ni DW, Huang X, Zhang GJ (2019) A thermoset hybrid sol for the syntheses of zirconium carbide–silicon carbide foam via replica method. J Porous Mater 26:409–41710.1007/s10934-018-0618-z ↗
25. Wang JX, Ni DW, Dong SM, Yang G, Gao YF, Kan YM, Chen X-W, Cao Y-P, Zhang XY (2017) Synthesis of nanocrystallized zirconium carbide based on an aqueous solution-derived precursor. RSC Adv 7:22722–2272710.1039/C7RA02586F ↗
26. Mahltig B (2021) High performance fibers – a review of properties and IR-spectra. Tekstilec 64:96–11810.14502/Tekstilec2021.64.96-118 ↗
27. Flesner J, Mahltig B (2017) In: Thakur VK, Thakur MK, Kessler MR (eds) Handbook of composites from renewable materials, vol 4–Functionalization. Srivener Publishing LLC Wiley, New Jersey
28. Günzler H, Gremlich H-U (2002) IR Spectroscopy. Wiley-VCH, Weinheim
29. Moreno-Maldonado V, Acosta-Torres LS, Barcelo-Santana FH, Vanegas-Lancon RD, Plata-Rodriguez ME, Castano VM (2012) Fiber-reinforced nanopigmented poly(methyl methacrylate) as improved denture base. Appl Polym Sci 126:289–29610.1002/app.36913 ↗
30. Ravichandran R, Gandhi S, Sundaramurthi D, Sethuraman S, Krishnan UM (2013) Hierarchical mesoporous silica nanofibers as multifunctional scaffolds for bone tissue regeneration. J Biomater Sci Polym Edition 24:1988–200510.1080/09205063.2013.816930 ↗
31. Tshabalala MA, Libert R, Schaller CM (2011) Photostability and moisture uptake properties of wood veneers coated with a combination of thin sol-gel films and light stabilizers. Holzforschung 65:215–22010.1515/hf.2011.022 ↗
32. Zheng R, Tshabalala MA, Li Q, Wang H (2015) Weathering performance of wood coated with a combination of alkoxysilanes and rutile TiO2 hierarchical nanostructures. BioResources 10:7053–706410.15376/biores.10.4.7053-7064 ↗
33. Lu Y, Xiao S, Gao R, Li J, Sun Q (2014) Improved weathering performance and wettability of wood protected by CeO2 coating deposited onto the surface. Holzforschung 68:345–35110.1515/hf-2013-0119 ↗
34. Schauwecker CF, McDonald AG, Preston AF, Morrell JJ (2014) Use of iron oxides to influence the weathering characteristics of wood surfaces: a systematic survey of particle size, crystal shape and concentration. Eur J Wood Wood Products 72:669–68010.1007/s00107-014-0831-7 ↗
35. Christie RM (2001) Colour Chemistry. Royal Society of Chemistry RSC, Cambridge10.1039/9781847550590 ↗
36. Seilnacht T (2018) Pigment und Bindemittel, 2nd edn. Seilnacht Verlag & Atelier, Bern
37. Mahltig B, Haufe H, Böttcher H (2005) Functionalization of textiles by inorganic sol–gel coatings. J Mater Chem 15:4385–439810.1039/b505177k ↗
38. dos Santos C, Brum LFW, Vasconcelos RDF, Velho SK, dos Santos JHZ (2018) Color and fastness of natural dyes encapsulated by a sol–gel process for dyeing natural and synthetic fibers. J Sol–Gel Sci Technol 86:351–36410.1007/s10971-018-4631-0 ↗
39. Trepte J, Böttcher H (2000) Improvement in the leaching behavior of dye-doped modified silica layers coated onto paper or textiles. J Sol–Gel Sci Technol 19:691–69410.1023/A:1008766807514 ↗
40. Mahltig B, Knittel D, Schollmeyer E, Böttcher H (2004) Incorporation of triarylmethane dyes into sol-gel matrices deposited on textiles. J Sol-Gel Sci Technol 31:293–29710.1023/B:JSST.0000048006.70681.7c ↗
41. Mahltig B, Textor T (2006) Combination of silica sol and dyes on textiles. J Sol-Gel Sci Technol 39:111–11810.1007/s10971-006-7744-9 ↗
42. Mahltig B, Böttcher H, Knittel D, Schollmeyer E (2004) Light fading and wash fastness of dyed nanosol-coated textiles. Text Res J 74:521–52710.1177/004051750407400610 ↗
43. Armstrong BK, Kricker A (2001) The epidemiology of UV induced skin cancer. J Photochem Photobio B 63:8–1810.1016/S1011-1344(01)00198-1 ↗
44. Narayanan DL, Saladi RN, Fox JL (2010) Ultraviolet radiation and skin cancer. Int J Dermatol 49:978–98610.1111/j.1365-4632.2010.04474.x ↗
45. Böttcher H, Mahltig B, Sarsour J, Stegmaier T (2010) Qualitative investigations of the photocatalytic dye destruction by TiO2-coated polyester fabrics. J Sol-Gel Sci Technol 55:177–18510.1007/s10971-010-2230-9 ↗
46. Dalponte E, Mahltig B, Breckenfelder C (2018) In: Mahltig B (eds) Textiles advances in research and applications. Nova Science Publishers Inc, New York
47. Zayat M, Pardo R, Castellon E, Torres L, Almendro D, Parejo PC, Alvarez A, Belenguer T, Garcia-Revilla S, Balda R, Fernandez J, Levy D (2011) Optical and electro-optical materials prepared by the sol-gel method. Adv Mater 23:5318–532310.1002/adma.201101927 ↗
48. Mahltig B, Textor T (2008) Nanosols and Textiles. World Scientific, Singapore10.1142/6961 ↗
49. Mahltig B, Böttcher H, Rauch K, Dieckmann U, Nitsche R, Fritz T (2005) Optimized UV protecting coatings by combination of organic and inorganic UV absorbers. Thin Solid Films 485:108–11410.1016/j.tsf.2005.03.056 ↗
50. Mahltig B, Günther K, Askani A, Bohnet F, Brinkert N, Kyosev Y, Weide T, Krieg M, Leisegang T (2017) X-ray-protective organic/inorganic fiber–along the textile chain from fiber production to clothing application. J Text Inst 108:1975–198410.1080/00405000.2017.1303122 ↗
51. Attwood D (2007) Soft X-rays and extreme ultraviolet radiation. Cambridge University Press, Cambridge
52. Chen LM, Forget P, Toth R, Kieffer JC, Krol A, Chamberlain CC, Hou BX, Nees J, Mourou G (2003) High resolution hard X-ray spectroscopy of femtosecond laser-produced plasmas with a CZT detector. Rev Sci Instrum 74:5035–503810.1063/1.1628824 ↗
53. Kirz J, Jacobsen C, Howells M (1995) Soft X-ray microscopes and their biological applications. Q Rev Biophysics 28:33–13010.1017/S0033583500003139 ↗
54. Mahltig B, Haufe H, Leisegang T, Gutmann JS, Textor T (2011) Verminderte Röntgentransmission durch beschichtete Textilien. Melliand Textilber 92:36–39
55. Zhang Q-P, Liang D-M, Zhu W-F, Liu J-H, Wu Y, Xu D-G, Bai X-Y, Wie M, Zhou Y-L (2019) Fabrication of h-BN@PbWO4 with a facile sol-gel method towards enhanced photocatalytic and radiation shielding properties. J Solid State Chem 269:594–5910.1016/j.jssc.2018.10.043 ↗
56. Henke BL, Gullikson EM, Davis JC (1993) X-ray interactions: photoabsorption, scattering, transmission, and reflection at E=50-30000eV, Z=1-92. At Data Nucl Data Tables 54(2):181–342. https://henke.lbl.gov/optical_constants/filter2.html10.1006/adnd.1993.1013 ↗
57. Hubbell JH, Veigele WJ, Briggs EA, Brown RT, Cromer DT, Howerton RJ (1975) Atomic form factors, incoherent scattering functions, and photon scattering cross sections. J Phys Chem Ref Data 4:471–538. erratum in 6, 615-616 (1977)10.1063/1.555523 ↗
58. van Aert H, van Damme M, Nuyken O, Schnöller U, Eichhorn K-J, Grundke K, Voit B (2001) Imagewise structuring of diazosulfonate polymer films by UV light and laser irradiation – a comparison. Macromol Mater Eng 286:488–49610.1002/1439-2054(200108)286:8<488::AID-MAME488>3.0.CO;2-F ↗
59. Zhu C, Lin W, Chen L, Lv J, Zhang J, Feng J (2019) Deep color, heat-reflective, superhydrophobic and anti-soiling coatings with waterborne silicone emulsion. Sol Energy Mater Sol Cells 199:129–13510.1016/j.solmat.2019.04.029 ↗
60. Feng X, Mao Q, Lv Q, Wang Z, Cui S (2016) Solar reflection characteristics of phthalocyanine green / TiO2 composite green pigments prepared via different approaches. Mater Sci Forum 849:725–73110.4028/www.scientific.net/MSF.849.725 ↗
61. Rashid MM, Mahltig B (2018) Inorganic effect pigment-binder system following sol-gel process–application for optical textile functionalization. J Fash Technol Text Eng 6:2
62. Mahltig B, Swaboda C, Roessler A, Böttcher H (2008) Functionalising wood by nanosol application. J Mater Chem 18:3180–319210.1039/b718903f ↗
63. Mahltig B, Arnold M, Löthman P (2010) Surface properties of sol-gel treated thermally modified wood. J Sol-Gel Sci Technol 55:221–22710.1007/s10971-010-2236-3 ↗
64. Abidi N, Hequet E, Tarimala S, Dai LL (2007) Cotton fabric surface modification for improved UV radiation protection using sol-gel process. J Appl Polym Sci 104:111–11710.1002/app.24572 ↗
65. Farouk A, Textor T, Schollmeyer E, Tarbuk A, Grancacic AM (2009) Sol-gel derived inorganic-organic hybrid polymers filled with ZnO nanoparticles as ultraviolet protection finish for textiles. AUTEX Res J 9:114–12010.1515/aut-2009-090404 ↗
66. Aklalouch M, Calleja A, Granados X, Ricart S, Boffa V, Ricci F, Puig T, Obradors X (2014) Hybrid sol-gel layers containing CeO2 nanoparticles as UV-protection of plastic lenses for concentrated photovoltaics. Sol Energy Mater Sol Cells 120A:175–18210.1016/j.solmat.2013.08.040 ↗
67. Wang W, Zhang B, Jiang S, Bai H, Zhang S (2019) Use of CeO2 nanoparticles to enhance UV-shielding of transparent regenerated cellulose films. Polymers 11:45810.3390/polym11030458 ↗