Catalytic Effects of Aluminum Butoxyethoxide in Sol-Gel Hybrid Hard Coatings
Source abstract
Abstract
Hybrid inorganic-organic hard coatings on PMMA substrate were obtained by sol-gel reaction of 3-glycidoxypropyltrimethoxysilane(GPTS), tetramethyl orthosilicate(TMOS) and aluminum butoxyethoxide (Al(OEtOBu)3). The catalytic effect of aluminum butoxyethoxide on inorganic condensation and epoxide polymerization has been studied by 13C, 29Si nuclear magnetic resonance spectroscopy and by Fourier transformed infrared spectroscopy. Hardness of hybrid inorganic-organic materials were measured by nanoindentor and mainly influenced by the extent of epoxide polymerization and inorganic condensation of their coating catalyzed by aluminum butoxyethoxide.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Inorganic and Organometallic Chemistry · Chemical Synthesis and Characterization · Thermal and Kinetic Analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (31)
Show source-provided references
1. L.-H. Lee (ed.), Polymer Wear and Its Control, ACS Symp. Ser 287; (Am. Chem. Soc, 1985), p. 77.10.1021/bk-1985-0287.ch006 ↗
2. J.D. Masso, Proc. SPIE-Int. Soc. Opt. Eng. 896, 148 (1988).
3. J.D. Masso, Proc. SPIE-Int. Soc. Opt. Eng. 601, 60 (1988).
4. F. Samson, Surf. Coat. Technol. 81, 79 (1996).10.1016/0257-8972(95)02532-4 ↗
5. L.N. Lewis and D.J. Katsamberies, J. Appl. Polym. Sci. 42, 1551 (1991).10.1002/app.1991.070420608 ↗
6. C.J. Brinker and G.W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, Boston, 1990).
7. L.C. Klein, Annu. Rev. Mater. Sci. 123, 437 (1993).10.1146/annurev.ms.23.080193.002253 ↗
8. L.L. Hench and J.K. West, Chem. Rev. 90, 33 (1990).10.1021/cr00099a003 ↗
9. J. Wen, V.J. Vasudevan, and G.L. Wilkes, J. Sol-Gel Sci. Technol. 5, 115 (1995).10.1007/BF00487727 ↗
10. K.H. Hass and S.A. Amberg-Schwab, Surface and Coating Technol. 111, 75 (1999).
11. P. Judeinstein and C. Sanchez, J. Mater. Chem. 6, 511 (1996).10.1039/JM9960600511 ↗
12. R. Wegler, Angew. Chem. 67, 582 (1955).10.1002/ange.19550671907 ↗
13. M. Templin, U. Weisner, and H.W. Spiess, Adv. Mater. 9, 814 (1997).10.1002/adma.19970091011 ↗
14. H. Schimidt and B. Seiferling, Mater. Res. Soc. Symp. Proc. 73, 739 (1986).10.1557/PROC-73-739 ↗
15. G. Phillips and H. Schmidt, J. Non-Cryst. Solids 82, 31 (1986).10.1016/0022-3093(86)90107-9 ↗
16. P. Innocenzi, G. Brusatin, M. Guglielmi, and R. Bertani, Chem. Mater. 11, 1672 (1999).10.1021/cm980734z ↗
17. D. Heobbel, M. Nacken, and H. Schmidt, J. Sol-Gel Sci. Techonol. 12, 169 (1988).10.1023/A:1008698201298 ↗
18. R. Kasemann, H. Schmidt, and E. Wintrich, Mat. Res. Soc. Symp. Proc. 346, 915 (1994).10.1557/PROC-346-915 ↗
19. H.K. Schimidt, J. Sol-Gel Sci. Technol. 8, 557 (1998).10.1023/A:1018387202515 ↗
20. M.W. Daniel and L.F. Francis, J. Colloid Interface Sci. 205, 191 (1998).10.1006/jcis.1998.5671 ↗
21. E. Geiter, Ph.D. Thesis, University of Saarland, Saarbrücken, Germany, 1997.
22. D. Heobbel, M. Nacken, and H. Schmidt, J. Sol-Gel Sci. Techonol. 21, 177 (2001).10.1023/A:1011274301896 ↗
23. W.C. Oliver and G.M. Pharr, J. Mater. Res. 7, 1564 (1992).10.1557/JMR.1992.1564 ↗
24. B. Ellis (ed.), Chemistry and Technology of Epoxy Resins (Blackie Academic and Professional, London, 1993).
25. E. Bayer, K. Albert, J. Reiners, M. Niedeer, and D. Müller, J. Chromatogr. 264, 197 (1983).10.1016/S0021-9673(01)95023-X ↗
26. S. Dier and F. Babonneau, J. Non-Cryst. Solids 167, 29 (1994).10.1016/0022-3093(94)90363-8 ↗
27. S. Ramdas and J. Klinowski, Nature 308, 521 (1984).10.1038/308521a0 ↗
28. W. Lwoswsi (ed.), Comprehensive Heterocyclic Chemistry, vol. 7 (Pergamon Press, Oxford, 1984).
29. R.M. Almeida and C.G. Pantano, J. Appl. Phys. 68, 4225 (1990).10.1063/1.346213 ↗
30. R.M. Almeida, T.A. Guitton, and C.G. Pantano, J. Non-Cryst. Solids 121, 193 (1990).10.1016/0022-3093(90)90130-E ↗
31. D. Heobbel, M. Nacken, and H. Schmidt, J. Sol-Gel Sci. Techonol. 19, 305 (2000).10.1023/A:1008777414416 ↗