Carboxylic acid-functionalized porous silica particles by a co-condensation approach
Source abstract
Abstract
Novel stable carboxylic acid derivatized alkoxy silanes are co-condensed with tetraethyl orthosilicate in the presence of a structure-directing agent in a direct “one-pot” synthesis to porous carboxy-modified silica particles. Special emphasis is given to the influence of an increasing amount of 5-(triethoxysilyl)pentanoic acid and sodium hydroxide on the morphology and porous structure of the co-condensation products. The simultaneous conversion of both silanes resulted in the formation of mesoporous, monodisperse spherical particles with diameters between 100 and 140 nm and specific surface areas up to 900 m2 g−1. Additionally, adsorption equilibrium studies were performed, in which the particles modified with carboxylic acid groups showed an increased adsorption rate toward methylene blue compared to pure silica materials.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Mesoporous Materials and Catalysis · Covalent Organic Framework Applications · Photonic Crystals and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (43)
Show source-provided references
1. Bruzzoniti MC, Prelle A, Sarzanini C, Onida B, Fiorilli S, Garrone E (2007) J Sep Sci 30:2414–242010.1002/jssc.200700182 ↗
2. Yu Y, Chen B, Qi W, Li X, Shin Y, Lei C, Liu J (2012) Microporous Mesoporous Mater 153:166–17010.1016/j.micromeso.2011.12.005 ↗
3. Colilla M, Izquierdo-Barba I, Sánchez-Salcedo S, Fierro JL, Hueso JL, Ma Vallet-Regí (2010) Chem Mater 22:6459–646610.1021/cm102827y ↗
4. Hüsing N, Schwertfeger F, Tappert W, Schubert U (1995) J Non-Cryst Solids 186:37–4310.1016/0022-3093(95)00031-3 ↗
5. Hüsing N, Brandhuber D, Kaiser P (2006) J Sol-Gel Sci Technol 40:131–13910.1007/s10971-006-8802-z ↗
6. Keppeler M, Hüsing N (2011) New J Chem 35:681–69010.1039/C0NJ00645A ↗
7. Keppeler M, Holzbock J, Akbarzadeh J, Peterlik H, Hüsing N (2011) Beilstein J. Nanotechnol. 2:486–49810.3762/bjnano.2.52 ↗
8. Burkett SL, Sims SD, Mann S (1996) Chem Commun 1367–136810.1039/CC9960001367 ↗
9. Huh S, Wiench JW, Yoo J-C, Pruski M, Lin VS-Y (2003) Chem Mater 15:4247–425610.1021/cm0210041 ↗
10. Burleigh MC, Markowitz MA, Spector MS, Gaber BP (2001) J Phys Chem B 105:9935–994210.1021/jp011814k ↗
11. Sujandi Park S, Han D, Han S, Jin M, Ohsuna T (2006) Chem Commun 4131–413310.1039/b608463j ↗
12. Yokoi T, Yoshitake H, Tatsumi T (2004) J Mater Chem 14:951–95710.1039/b310576h ↗
13. Sadasivan S, Khushalani D, Mann S (2003) J Mater Chem 13:1023–102910.1039/b300851g ↗
14. Ho KY, McKay G, Yeung KL (2003) Langmuir 19:3019–302410.1021/la0267084 ↗
15. Yang C-M, Zibrowius B, Schüth F (2003) Chem Commun 1772–177310.1039/B304626E ↗
16. Liu N, Assink RA, Brinker CJ (2003) Chem Commun 370–37110.1039/b210377j ↗
17. Fiorilli S, Onida B, Bonelli B, Garrone E (2005) J Phys Chem B 109:16725–1672910.1021/jp045362y ↗
18. Yan Z, Tao S, Yin J, Li G (2006) J Mater Chem 16:2347–235310.1039/b600611f ↗
19. Chang B, Guo J, Liu C, Qian J, Yang W (2010) J Mater Chem 20:9941–994710.1039/c0jm01237h ↗
20. Fu X, Chen X, Wang J, Liu J (2011) Microporous Mesoporous Mater 139:8–1510.1016/j.micromeso.2010.10.004 ↗
21. Yang Q, Wang S, Fan P, Wang L, Di Y, Lin K, Xiao F-S (2005) Chem Mater 17:5999–600310.1021/cm051198v ↗
22. Han L, Terasaki O, Che S (2011) J Mater Chem 21:11033–1103910.1039/c1jm10561b ↗
23. Markowitz MA, Klaehn J, Hendel RA, Qadriq SB, Golledge SL, Castner DG, Gaber BP (2000) J Phys Chem B 104:10820–1082610.1021/jp0008389 ↗
24. Han L, Sakamoto Y, Terasaki O, Li Y, Che S (2007) J Mater Chem 17:1216–122110.1039/b615209k ↗
25. Gao C, Che S (2010) Adv Funct Mater 20:2750–276810.1002/adfm.201000074 ↗
26. Kayan A, Hoebbel D, Schmidt H (2005) J Appl Polym Sci 95:790–79610.1002/app.21315 ↗
27. Silva PR, Almeida VO, Machado GB, Benvenutti EV, Costa TM, Gallas MR (2011) Langmuir 28:1447–145210.1021/la203056f ↗
28. Radu DR, Lai CY, Huang J, Shu X, Lin VSY (2005) Chem Commun 1264–126610.1039/b412618a ↗
29. Feinle A, Flaig S, Puchberger M, Schubert U, Hüsing N (2015) Chem Commun 2339–234110.1039/C4CC08025D ↗
30. Feinle A, Lavoie-Cardinal F, Akbarzadeh J, Peterlik H, Adlung M, Wickleder C, Hüsing N (2012) Chem Mater 24:3674–368310.1021/cm300996j ↗
31. Brunauer S, Emmett PH, Teller E (1938) J Am Chem Soc 60:309–31910.1021/ja01269a023 ↗
32. Barrett EP, Joyner LG, Halenda PP (1951) J Am Chem Soc 73:373–38010.1021/ja01145a126 ↗
33. Hodgkins RP, Garcia-Bennett AE, Wright PA (2005) Microporous Mesoporous Mater 79:241–25210.1016/j.micromeso.2004.10.036 ↗
34. Möller K, Kobler J, Bein T (2007) J Mater Chem 17:624–63110.1039/B611931J ↗
35. C-m Yang, Wang Y, Zibrowius B, Schüth F (2004) Phys Chem Chem Phys 6:2461–246710.1039/B314538G ↗
36. Torma V, Peterlik H, Bauer U, Rupp W, Hüsing N, Bernstorff S, Steinhart M, Goerigk G, Schubert U (2005) Chem Mater 17:3146–315310.1021/cm047996n ↗
37. Che S, Garcia-Bennett AE, Yokoi T, Sakamoto K, Kunieda H, Terasaki O, Tatsumi T (2003) Nat Mater 2:801–80510.1038/nmat1022 ↗
38. Mercier L, Pinnavaia TJ (2000) Chem Mater 12:188–19610.1021/cm990532i ↗
39. Richer R, Mercier L (1998) Chem Commun 1775–177710.1039/a803285h ↗
40. Fiorilli S, Camarota B, Garrone E, Onida B (2011) Phys Chem Chem Phys 13:1201–120910.1039/C0CP01260B ↗
41. Shawwa AR, Smith DW, Sego DC (2001) Water Res 35:745–74910.1016/S0043-1354(00)00322-5 ↗
42. Chakrabarti S, Dutta BK (2005) J Colloid Interface Sci 286:807–81110.1016/j.jcis.2005.01.035 ↗
43. Gücek A, Şener S, Bilgen S, Mazmancı MA (2005) J Colloid Interface Sci 286:53–6010.1016/j.jcis.2005.01.012 ↗