journal article·2015-10

Enhanced photocatalytic performance of Ag-decorated BiFeO3 in visible light region

Huidan Lu, Zhenyu Du, Jixiang Wang, Yongping Liu

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Abstract

In this paper, a novel photocatalyst, made up of Ag/BiFeO3 nanocomposites activated by visible light, was successfully synthesized using a sol–gel process, followed by a chemical reduction method. The as-prepared BiFeO3 particles and Ag/BiFeO3 nanocomposites were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy and diffuse reflectance spectroscopy. The results showed that the metal Ag nanoparticles with diameter of 20–50 nm are anchored on the surface of BiFeO3. Meanwhile, the photocatalytic experiments demonstrated that the Ag/BiFeO3 composites had excellent photocatalytic activity for the decomposition of methyl orange in visible light, which far exceeded that of the pure BiFeO3. These results revealed Ag loading could significantly improve the photocatalytic property of BiFeO3. Recycle experiments showed the nanocomposites had an excellent recoverability, suggesting stable photoactivity. Finally, we discuss the photocatalytic mechanism of nanocomposites. The enhanced photoactivity of Ag-decorated BiFeO3 photocatalyst is most likely attributed to the electronic effect of Ag nanoparticles including surface plasmon resonance.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Multiferroics and related materials · Advanced Photocatalysis Techniques · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Song CY, Xu J, Yimamu A, Wang L (2014) Hydrothermal synthesis of perovskite bismuth ferrite micro/nano powders. Integr Ferroelectr 153:33–4110.1080/10584587.2014.902668 ↗
2. Zhu X, Zhou J, Jiang M, Xie J, Liang S, Li S, Liu Z, Zhu Y, Zhu J, Liu Z (2014) Molten salt synthesis of bismuth ferrite nano- and microcrystals and their structural characterization. J Am Ceram Soc 97:2223–223210.1111/jace.12897 ↗
3. Ramesh R (2014) Electric field control of ferromagnetism using multi-ferroics: the bismuth ferrite story. Philos Trans R Soc A Math Phys Eng Sci 372:1471–296210.1098/rsta.2012.0437 ↗
4. Wang J, Neaton JB, Zheng H, Nagarajan V, Ogale SB, Liu B, Viehland D, Vaithyanathan V, Schlom DG, Waghmare UV, Spaldin NA, Rabe KM, Wuttig M, Ramesh R (2003) Epitaxial BiFeO3 multiferroic thin film heterostructures. Science 299:1719–172210.1126/science.1080615 ↗
5. Hopkins PE, Adamo C, Ye L, Huey BD, Lee SR, Schlom DG, Ihlefeld JF (2013) Effects of coherent ferroelastic domain walls on the thermal conductivity and Kapitza conductance in bismuth ferrite. Appl Phys Lett 102:12190310.1063/1.4798497 ↗
6. Seidel J, Martin LW, He Q, Zhan Q, Chu YH, Rother A, Hawkridge ME, Maksymovych P, Yu P, Gajek M, Balke N, Kalinin SV, Gemming S, Wang F, Catalan G, Scott JF, Spaldin NA, Orenstein J, Ramesh R (2009) Conduction at domain walls in oxide multiferroics. Nat Mater 8:229–23410.1038/nmat2373 ↗
7. Zhang D, Shi P, Wu X, Ren W (2013) Structural and electrical properties of sol–gel-derived Al-doped bismuth ferrite thin films. Ceram Int 39(Supplement 1):S461–S46410.1016/j.ceramint.2012.10.114 ↗
8. Bu Y, Zhong Q, Xu D, Tan W (2013) Redox stability and sulfur resistance of Sm0.9Sr0.1CrxFe1−xO3−δ perovskite materials. J Alloys Compd 578:60–6610.1016/j.jallcom.2013.05.020 ↗
9. Jeon NJ, Noh JH, Kim YC, Yang WS, Ryu S, Seok SI (2014) Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells. Nat Mater 13:897–90310.1038/nmat4014 ↗
10. Armstrong EN, Duncan KL, Wachsman ED (2013) Effect of A and B-site cations on surface exchange coefficient for ABO3 perovskite materials. PCCP 15:2298–230810.1039/c2cp42919e ↗
11. Ryu S, Noh JH, Jeon NJ, Chan Kim Y, Yang WS, Seo J, Seok SI (2014) Voltage output of efficient perovskite solar cells with high open-circuit voltage and fill factor. Energy Environ Sci 7:2614–261810.1039/C4EE00762J ↗
12. Li S, Lin Y, Zhang B, Wang Y, Nan C (2010) Controlled fabrication of BiFeO3 uniform microcrystals and their magnetic and photocatalytic behaviors. J Phys Chem C 114:2903–290810.1021/jp910401u ↗
13. Wang X, Lin Y, Ding X, Jiang J (2011) Enhanced visible-light-response photocatalytic activity of bismuth ferrite nanoparticles. J Alloys Compd 509:6585–658810.1016/j.jallcom.2011.03.074 ↗
14. Tan G, Zheng Y, Miao H, Xia A, Ren H (2012) Controllable microwave hydrothermal synthesis of bismuth ferrites and photocatalytic characterization. J Am Ceram Soc 95:280–28910.1111/j.1551-2916.2011.04775.x ↗
15. Wang W, Li N, Chi Y, Li Y, Yan W, Li X, Shao C (2013) Electrospinning of magnetical bismuth ferrite nanofibers with photocatalytic activity. Ceram Int 39:3511–351810.1016/j.ceramint.2012.10.175 ↗
16. Fei L, Yuan J, Hu Y, Wu C, Wang J, Wang Y (2011) Visible light responsive perovskite BiFeO3 pills and rods with dominant {111}c Facets. Cryst Growth Des 11:1049–105310.1021/cg101144s ↗
17. Tholkappiyan R, Vishista K (2014) Effect of niobium on the optical and magnetic properties of bismuth ferrite (BiFeO3). Adv Sci Eng Med 6:311–31710.1166/asem.2014.1489 ↗
18. Mukherjee A, Banerjee M, Basu S, Pal M (2014) Electrical and optical properties of gadolinium doped bismuth ferrite nanoparticles. AIP Conf Proc 1591:1339–134110.1063/1.4872951 ↗
19. MacLaren I, Wang LQ, Schaffer B, Ramasse QM, Craven AJ, Selbach SM, Spaldin NA, Miao S, Kalantari K, Reaney IM (2013) Nanorods: novel nanorod precipitate formation in neodymium and titanium codoped bismuth ferrite. Adv Funct Mater 23:65410.1002/adfm.201370027 ↗
20. Guo R, Fang L, Dong W, Zheng F, Shen M (2010) Enhanced photocatalytic activity and ferromagnetism in Gd doped BiFeO3 nanoparticles. J Phys Chem C 114:21390–2139610.1021/jp104660a ↗
21. Zhao G, Liu S, Lu Q, Xu F, Sun H, Yu J (2013) Synthesis of TiO2/Bi2WO6 nanofibers with electrospinning technique for photocatalytic methyl blue degradation. J Sol Gel Sci Technol 66:406–41210.1007/s10971-013-3023-8 ↗
22. Talebian N, Nilforoushan M, Memarnezhad P (2013) Photocatalytic activities of multilayered ZnO-based thin films prepared by sol–gel route: effect of SnO2 heterojunction layer. J Sol Gel Sci Technol 65:178–18810.1007/s10971-012-2922-4 ↗
23. Li Z, Shen Y, Yang C, Lei Y, Guan Y, Lin Y, Liu D, Nan C (2013) Significant enhancement in the visible light photocatalytic properties of BiFeO3-graphene nanohybrids. J Mater Chem A 1:823–82910.1039/C2TA00141A ↗
24. Sakar M, Balakumar S, Saravanan P, Jaisankar SN (2013) Manifestation of weak ferromagnetism and photocatalytic activity in bismuth ferrite nanoparticles. AIP Conf Proc 1512:228–22910.1063/1.4790994 ↗
25. Kim JK, Kim SS, Kim W-J (2005) Sol–gel synthesis and properties of multiferroic BiFeO3. Mater Lett 59:4006–400910.1016/j.matlet.2005.07.050 ↗
26. Washio I, Xiong Y, Yin Y, Xia Y (2006) Reduction by the end groups of poly(vinyl pyrrolidone): a new and versatile route to the kinetically controlled synthesis of Ag triangular nanoplates. Adv Mater 18:1745–174910.1002/adma.200600675 ↗
27. Farhadi S, Rashidi N (2010) Preparation and characterization of pure single-phase BiFeO3 nanoparticles through thermal decomposition of the heteronuclear Bi[Fe(CN)6]·5H2O complex. Polyhedron 29:2959–296510.1016/j.poly.2010.08.019 ↗
28. Zhu X, Hang Q, Xing Z, Yang Y, Zhu J, Liu Z, Ming N, Zhou P, Song Y, Li Z, Yu T, Zou Z (2011) Microwave hydrothermal synthesis, structural characterization, and visible-light photocatalytic activities of single-crystalline bismuth ferric nanocrystals. J Am Ceram Soc 94:2688–269310.1111/j.1551-2916.2011.04430.x ↗
29. Huo Y, Jin Y, Zhang Y (2010) Citric acid assisted solvothermal synthesis of BiFeO3 microspheres with high visible-light photocatalytic activity. J Mol Catal A Chem 331:15–2010.1016/j.molcata.2010.08.009 ↗
30. Gao F, Chen XY, Yin KB, Dong S, Ren ZF, Yuan F, Yu T, Zou ZG, Liu JM (2007) Visible-light photocatalytic properties of weak magnetic BiFeO3 nanoparticles. Adv Mater 19:2889–289210.1002/adma.200602377 ↗
31. Romão J, Barata D, Habibovic P, Mul G, Baltrusaitis J (2014) High throughput analysis of photocatalytic water purification. Anal Chem 86:7612–761710.1021/ac501426f ↗
32. Song L, Li Y, Zhang S, Zhang S (2014) Synthesis and characterization of Bi3+-Doped Ag/AgCl and enhanced photocatalytic properties. J Phys Chem C 118:29777–2978710.1021/jp507816v ↗
33. Yamada Y, Mizutani M, Nakamura T, Yano K (2010) Mesoporous microcapsules with decorated inner surface: fabrication and photocatalytic activity. Chem Mater 22:1695–170310.1021/cm9031072 ↗
34. Yu J, Kudo A (2006) Effects of structural variation on the photocatalytic performance of hydrothermally synthesized BiVO4. Adv Funct Mater 16:2163–216910.1002/adfm.200500799 ↗
35. Fu H, Pan C, Yao W, Zhu Y (2005) Visible-light-induced degradation of rhodamine B by Nanosized Bi2WO6. J Phys Chem B 109:22432–2243910.1021/jp052995j ↗
36. Yang Y, Wen J, Wei J, Xiong R, Shi J, Pan C (2013) Polypyrrole-decorated Ag–TiO2 nanofibers exhibiting enhanced photocatalytic activity under visible-light illumination. ACS Appl Mater Interf 5:6201–620710.1021/am401167y ↗
37. Liu R, Wang P, Wang X, Yu H, Yu J (2012) UV- and visible-light photocatalytic activity of simultaneously deposited and doped Ag/Ag(I)-TiO2 photocatalyst. J Phys Chem C 116:17721–1772810.1021/jp305774n ↗
38. Zhang Z, Wang W, Gao E, Sun S, Zhang L (2012) Photocatalysis coupled with thermal effect induced by SPR on Ag-Loaded Bi2WO6 with enhanced photocatalytic activity. J Phys Chem C 116:25898–2590310.1021/jp309719q ↗