journal article·2019-07

Supercapacitor performance of MnO2/NiCo2O4@N-MWCNT hybrid nanocomposite electrodes

A. Kathalingam, Sivalingam Ramesh, Arumugam Sivasamy, Heung-Soo Kim, Hyun-Seok Kim

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Abstract

MnO2/NiCo2O4@N-MWCNT hybrid nanocomposite was synthesized by the hydrothermal route using ammonia and urea as catalysts. The structural, morphological and compositional properties of the hybrid composites were analyzed using XRD, SEM, HR-TEM SEM-EDAX, XPS, FTIR, and Raman measurements. The electrochemical properties of the prepared hybrid composite were studied by cyclic voltammetry analysis. The outcome of the electrochemical studies revealed a specific capacitance of ~543 Fg−1 at 0.5 A g−1 current density in the KOH (6 M) electrolyte, with a stability of ~88% up to 5000 cycles. The obtained results clearly demonstrated the significance of the nanostructured MnO2/NiCo2O4@N-MWCNT hybrid composite in supercapacitor applications.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Electrochemical sensors and biosensors

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References (46)

Show source-provided references
1. Wang L, Zheng Y, Chen S, Ye Y, Xu F, Tan H, Li Z, Hou H, Song Y (2014) Three-dimensional kenaf stem-derived porous carbon/MnO2 for high-performance supercapacitors. Electrochimica Acta 135:380–38710.1016/j.electacta.2014.05.044 ↗
2. Sathishkumar K, Shanmugam N, Kannadasan N, Cholan S, Viruthagiri G (2015) Synthesis and characterization of Cu2 + doped NiO electrode for supercapacitor application. Journal of Sol-Gel Science and Technology 74:621–63010.1007/s10971-015-3641-4 ↗
3. Wei W, Cui X, Chen W, Ivey DG (2011) Manganese oxide-based materials as electrochemical supercapacitor electrodes. Chemical Society Reviews 40(3):1697–1721. https://doi.org/10.1039/C0CS00127A10.1039/C0CS00127A ↗
4. Ramesh S, Kathalingam A, Karuppasamy K, Kim H-S, Kim HS (2019) Nanostructured CuO/Co2O4@ nitrogen doped MWCNT hybrid composite electrode for high-performance supercapacitors. Composites Part B: Engineering 166:74–85. https://doi.org/10.1016/j.compositesb.2018.11.11610.1016/j.compositesb.2018.11.116 ↗
5. Fang L, Xie Y, Wang Y, Zhang Z, Liu P, Cheng N, Liu J, Tu Y, Zhao H, Zhang J (2019) Facile synthesis of hierarchical porous carbon nanorods for supercapacitors application. Applied Surface Science 464:479–487. https://doi.org/10.1016/j.apsusc.2018.09.12410.1016/j.apsusc.2018.09.124 ↗
6. Ramesh S, Haldorai Y, Kim HS, Kim J-H (2017) A nanocrystalline Co3O4@polypyrrole/MWCNT hybrid nanocomposite for high performance electrochemical supercapacitors. RSC Advances 7(58):36833–3684310.1039/C7RA06093A ↗
7. Deng S, Sun D, Wu C, Wang H, Liu J, Sun Y, Yan H (2013) Synthesis and electrochemical properties of MnO2 nanorods/graphene composites for supercapacitor applications. Electrochimica Acta 111:707–71210.1016/j.electacta.2013.08.055 ↗
8. Ko TH, Radhakrishnan S, Choi W-K, Seo M-K, Kim B-S (2016) Core/shell-like NiCo2O4-decorated MWCNT hybrids prepared by a dry synthesis technique and its supercapacitor applications. Materials Letters 166:105–10910.1016/j.matlet.2015.12.053 ↗
9. Yang D, Qiu W, Xu J, Wang P, Jin D, Peng X, Hong B, Jin H, Ge H, Wang X (2016) Facilely Synthesized NiCo2O4/CNTs Nanocomposites for Surpercapacitors with Enhanced Performance. International Journal of Electrochemical Science 11(8):7262–726810.20964/2016.08.32 ↗
10. Wu Y-Z, Ding Y, Hayat T, Alsaedi A, Dai S-Y (2018) Enlarged working potential window for MnO2 supercapacitors with neutral aqueous electrolytes. Applied Surface Science 459:430–437. https://doi.org/10.1016/j.apsusc.2018.07.14710.1016/j.apsusc.2018.07.147 ↗
11. Ramesh S, Karuppasamy K, Msolli S, Kim H-S, Kim HS, Kim J-H (2017) A nanocrystalline structured NiO/MnO2@ nitrogen-doped graphene oxide hybrid nanocomposite for high performance supercapacitors. New Journal of Chemistry 41(24):15517–1552710.1039/C7NJ03730A ↗
12. Yu L, Zhang G, Yuan C, Lou XW (2013) Hierarchical NiCo2O4@MnO2 core–shell heterostructured nanowire arrays on Ni foam as high-performance supercapacitor electrodes. Chemical Communications 49(2):137–139. https://doi.org/10.1039/C2CC37117K10.1039/C2CC37117K ↗
13. Yun YS, Park HH, Jin H-J (2012) Pseudocapacitive effects of N-doped carbon nanotube electrodes in supercapacitors. Materials 5(7):1258–126610.3390/ma5071258 ↗
14. Zhang J, Zhang X, Zhou Y, Guo S, Wang K, Liang Z, Xu Q (2014) Nitrogen-doped hierarchical porous carbon nanowhisker ensembles on carbon nanofiber for high-performance supercapacitors. ACS Sustainable Chemistry & Engineering 2(6):1525–153310.1021/sc500221s ↗
15. Sevilla M, Yu L, Zhao L, Ania CO, Titiricic M-M (2014) Surface modification of CNTs with N-doped carbon: an effective way of enhancing their performance in supercapacitors. ACS Sustainable Chemistry & Engineering 2(4):1049–105510.1021/sc500069h ↗
16. Gueon D, Moon JH (2015) Nitrogen-doped carbon nanotube spherical particles for supercapacitor applications: emulsion-assisted compact packing and capacitance enhancement. ACS applied materials & interfaces 7(36):20083–2008910.1021/acsami.5b05231 ↗
17. Sachin Kumar B, Dhanasekhar C, Venimadhav A, Kalpathy SK, Anandhan S (2018) Pyrolysis-controlled synthesis and magnetic properties of sol–gel electrospun nickel cobaltite nanostructures. Journal of Sol-Gel Science and Technology 86:664–67410.1007/s10971-018-4672-4 ↗
18. Garg N, Basu M, Ganguli AK (2014) Nickel cobaltite nanostructures with enhanced supercapacitance activity. The Journal of Physical Chemistry C 118(31):17332–1734110.1021/jp5039738 ↗
19. Zou R, Xu K, Wang T, He G, Liu Q, Liu X, Zhang Z, Hu J (2013) Chain-like NiCo2O4 nanowires with different exposed reactive planes for high-performance supercapacitors. Journal of Materials Chemistry A 1(30):8560–856610.1039/c3ta11361b ↗
20. Zhang Y, Ma M, Yang J, Su H, Huang W, Dong X (2014) Selective synthesis of hierarchical mesoporous spinel NiCo2O4 for high-performance supercapacitors. Nanoscale 6(8):4303–430810.1039/c3nr06564b ↗
21. Bao F, Zhang Z, Guo W, Liu X (2015) Facile synthesis of three dimensional NiCo2O4@ MnO2 core–shell nanosheet arrays and its supercapacitive performance. Electrochimica Acta 157:31–4010.1016/j.electacta.2015.01.060 ↗
22. Lai F, Miao Y-E, Huang Y, Chung T-S, Liu T (2015) Flexible hybrid membranes of NiCo2O4-doped carbon nanofiber@MnO2 core–sheath nanostructures for high-performance supercapacitors. The Journal of Physical Chemistry C 119(24):13442–13450. https://doi.org/10.1021/acs.jpcc.5b0273910.1021/acs.jpcc.5b02739 ↗
23. Jia L, Shi Y, Zhang Q, Xu X (2018) Green synthesis of ultrafine methyl-cellulose-derived porous carbon/MnO2 nanowires for asymmetric supercapacitors and flexible pattern stamping. Applied Surface Science 462:923–931. https://doi.org/10.1016/j.apsusc.2018.08.21310.1016/j.apsusc.2018.08.213 ↗
24. Teng F, Santhanagopalan S, Meng DD (2010) Microstructure control of MnO2/CNT hybrids under in-situ hydrothermal conditions. Solid State Sciences 12(9):1677–168210.1016/j.solidstatesciences.2010.07.026 ↗
25. Thostenson ET, Ren Z, Chou T-W (2001) Advances in the science and technology of carbon nanotubes and their composites: a review. Composites science and technology 61(13):1899–191210.1016/S0266-3538(01)00094-X ↗
26. Lee C-W, Yoon S-B, Bak S-M, Han J, Roh KC, Kim K-B (2014) Soft templated mesoporous manganese oxide/carbon nanotube composites via interfacial surfactant assembly. Journal of Materials Chemistry A 2(10):3641–364710.1039/C3TA15001A ↗
27. Li L, Hu ZA, An N, Yang YY, Li ZM, Wu HY (2014) Facile synthesis of MnO2/CNTs composite for supercapacitor electrodes with long cycle stability. The Journal of Physical Chemistry C 118(40):22865–2287210.1021/jp505744p ↗
28. Chen S, Zhu J, Wu X, Han Q, Wang X (2010) Graphene oxide- MnO2 nanocomposites for supercapacitors. ACS nano 4(5):2822–283010.1021/nn901311t ↗
29. Sawangphruk M, Srimuk P, Chiochan P, Krittayavathananon A, Luanwuthi S, Limtrakul J (2013) High-performance supercapacitor of manganese oxide/reduced graphene oxide nanocomposite coated on flexible carbon fiber paper. Carbon 60:109–11610.1016/j.carbon.2013.03.062 ↗
30. Jayaseelan SS, Radhakrishnan S, Saravanakumar B, Seo M-K, Khil M-S, Kim H-Y, Kim B-S (2018) Mesoporous 3D NiCo2O4/MWCNT nanocomposite aerogels prepared by a supercritical CO2 drying method for high performance hybrid supercapacitor electrodes. Colloids and Surfaces A: Physicochemical and Engineering Aspects 538:451–45910.1016/j.colsurfa.2017.11.037 ↗
31. Deng D, Kim B-S, Gopiraman M, Kim IS (2015) Needle-like MnO2/activated carbon nanocomposites derived from human hair as versatile electrode materials for supercapacitors. RSC Advances 5(99):81492–8149810.1039/C5RA16624A ↗
32. Xu K, Li W, Liu Q, Li B, Liu X, An L, Chen Z, Zou R, Hu J (2014) Hierarchical mesoporous NiCo2O4@MnO2 core–shell nanowire arrays on nickel foam for aqueous asymmetric supercapacitors. Journal of Materials Chemistry A 2(13):4795–480210.1039/c3ta14647b ↗
33. Zhang Z, Bao F, Zhang Y, Feng L, Ji Y, Zhang H, Sun Q, Feng S, Zhao X, Liu X (2015) Formation of hierarchical CoMoO4@MnO2 core–shell nanosheet arrays on nickel foam with markedly enhanced pseudocapacitive properties. Journal of Power Sources 296:162–16810.1016/j.jpowsour.2015.07.042 ↗
34. Ko T-H, Devarayan K, Seo M-K, Kim H-Y, Kim B-S (2016) Facile synthesis of core/shell-like NiCo2O4-decorated MWCNTs and its excellent electrocatalytic activity for methanol oxidation. Scientific Reports 6:20313. https://doi.org/10.1038/srep2031310.1038/srep20313 ↗
35. Wang J-G, Yang Y, Huang Z-H, Kang F (2013) A high-performance asymmetric supercapacitor based on carbon and carbon–MnO2 nanofiber electrodes. Carbon 61:190–19910.1016/j.carbon.2013.04.084 ↗
36. Garakani MA, Abouali S, Xu Z-L, Huang J, Huang J-Q, Kim J-K (2017) Heterogeneous, mesoporous NiCo2O4–MnO2/graphene foam for asymmetric supercapacitors with ultrahigh specific energies. Journal of Materials Chemistry A 5(7):3547–3557. https://doi.org/10.1039/C6TA08929A10.1039/C6TA08929A ↗
37. Huang L, Chen D, Ding Y, Wang ZL, Zeng Z, Liu M (2013) Hybrid composite Ni(OH)2@NiCo2O4 grown on carbon fiber paper for high-performance supercapacitors. ACS Applied Materials & Interfaces 5(21):11159–11162. https://doi.org/10.1021/am403367u10.1021/am403367u ↗
38. Kong D, Ren W, Cheng C, Wang Y, Huang Z, Yang HY (2015) Three-dimensional NiCo2O4@polypyrrole coaxial nanowire arrays on carbon textiles for high-performance flexible asymmetric solid-state supercapacitor. ACS Applied Materials & Interfaces 7(38):21334–21346. https://doi.org/10.1021/acsami.5b0590810.1021/acsami.5b05908 ↗
39. Wang H, Casalongue HS, Liang Y, Dai H (2010) Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. Journal of the American Chemical Society 132(21):7472–7477. https://doi.org/10.1021/ja102267j10.1021/ja102267j ↗
40. Zhang G, Lou XW (2013) Controlled growth of NiCo2O4 nanorods and ultrathin nanosheets on carbon nanofibers for high-performance supercapacitors. Scientific Reports 3:1470. https://doi.org/10.1038/srep0147010.1038/srep01470 ↗
41. Wang H, Gao Q, Jiang L (2011) Facile approach to prepare nickel cobaltite nanowire materials for supercapacitors. Small (Weinheim an der Bergstrasse, Germany) 7(17):2454–2459. https://doi.org/10.1002/smll.20110053410.1002/smll.201100534 ↗
42. Shen P, Zhang H, Zhang S, Fei L (2018) Fabrication of completely interface-engineered Ni(OH)2/rGO nanoarchitectures for high-performance asymmetric supercapacitors. Applied Surface Science 460:65–73. https://doi.org/10.1016/j.apsusc.2017.09.14510.1016/j.apsusc.2017.09.145 ↗
43. Reddy ALM, Shaijumon MM, Gowda SR, Ajayan PM (2009) Coaxial MnO2/carbon nanotube array electrodes for high-performance lithium batteries. Nano Letters 9(3):1002–1006. https://doi.org/10.1021/nl803081j10.1021/nl803081j ↗
44. Ramesh S, Kim HS, Haldorai Y, Han Y-K, Kim J-H (2017) Fabrication of nanostructured MnO2/carbon nanotube composite from 3D precursor complex for high-performance supercapacitor. Materials Letters 196:132–136. https://doi.org/10.1016/j.matlet.2017.03.04410.1016/j.matlet.2017.03.044 ↗
45. Ramesh S, Haldorai Y, Sivasamy A, Kim HS (2017) Nanostructured Co3O4/nitrogen doped carbon nanotube composites for high-performance supercapacitors. Materials Letters 206:39–43. https://doi.org/10.1016/j.matlet.2017.06.11010.1016/j.matlet.2017.06.110 ↗
46. Chen H, Hu L, Chen M, Yan Y, Wu L (2014) Nickel–cobalt layered double hydroxide nanosheets for high-performance supercapacitor electrode materials. Advanced Functional Materials 24(7):934–942. https://doi.org/10.1002/adfm.20130174710.1002/adfm.201301747 ↗