journal article·2010-06Open access

Influence of cerium concentration on the structure and properties of silica-methacrylate sol–gel coatings

Nataly Carolina Rosero-Navarro, Pawel Figiel, Roman Jedrzejewski, Anna Biedunkiewicz, Yolanda Castro, Mario Aparicio, Sergio Antonio Pellice, Alicia Durán

Abstract

The aim of this work was to study the effect of the incorporation of cerium nitrate in a silica-methacrylate sol–gel hybrid matrix reinforced with silica nanoparticles. Sols, coatings and powders have been studied, focusing specially in the determination of the redox ratio Ce3?/Ce4? and films structure. Sols have been characterised using viscosity measurements and FT-IR spectroscopy, and powders and coatings obtained with different Ce contents through UV–Vis and FT-IR spectroscopy, TGA, TEM, AFM and FE-SEM. The goal was to reach the best compromise between maximum cerium concentration and coating stability to better understand the mechanisms acting in active anti-corrosive processes.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Silicone and Siloxane Chemistry · Analytical Chemistry and Sensors

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