journal article·2015-04

Stacked ZnO nanorods synthesized by solution precipitation method and their photocatalytic activity study

Myo Thuya Thein, Swee-Yong Pung, Azizan Aziz, Mitsuru Itoh

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Abstract

ZnO has been considered as a promising photocatalyst for wastewater treatment. Although many works have been done to enhance the photocatalytic activity of ZnO particles, it is difficult to synthesize well-controlled morphology of ZnO particles having high photocatalytic activity. In this work, stacked ZnO nanorods were synthesized at different growth time via solution precipitation method. Their length and diameter of stacked ZnO nanorods increased with growth time. The formation of stacked ZnO nanorods was attributed to the joining of (002) polar surfaces at the tips of a smaller ZnO nanorods during the synthesis process. A small amount of PVP was added to minimize the agglomeration and to reduce the secondary nucleation of ZnO nanorods. The photocatalytic study showed that the photodegradation of RhB solution by stacked ZnO nanorods under UV light followed first-order kinetic. The results also indicated that a larger effective surface area of stacked ZnO nanorods leads to a higher adsorption of organic molecules, causing a better photocatalytic activity for RhB dye removal. Stacked ZnO nanorods synthesized by solution precipitation method and their photocatalytic activity study.
Source: openaire · Quality: candidate unverified · Source record ↗

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OpenAlex topics: ZnO doping and properties · Ga2O3 and related materials · Copper-based nanomaterials and applications

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References (50)

Show source-provided references
1. Fujishima A (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–3810.1038/238037a0 ↗
2. Fujishima A, Honda K, Kikuchi S (1969) Photosensitized electrolytic oxidation on semiconducting n-type TiO2 electrode. J Chem Soc Jpn (Kogyo Kagaku Zasshi) 72:108–113
3. Kawai T, Sakata T (1979) Hydrogen evolution from water using solid carbon and light energy. Nature 282:283–28410.1038/282283a0 ↗
4. Kawai T, Sakata T (1980) Conversion of carbohydrate into hydrogen fuel by a photocatalytic process. Nature 286:474–47610.1038/286474a0 ↗
5. Sato S, White JM (1980) Photodecomposition of water over Pt/TiO2 catalysts. Chem Phys Lett 72:83–8610.1016/0009-2614(80)80246-6 ↗
6. Fox MA, Dulay MT (1993) Heterogeneous photocatalysis. Chem Rev 93:341–35710.1021/cr00017a016 ↗
7. Cai X, Cai Y, Liu Y, Deng S, Wang Y, Wang Y, Djerdj I (2014) Photocatalytic degradation properties of Ni (OH)2 nanosheets/ZnO nanorods composites for azo dyes under visible-light irradiation. Ceram Int 40:57–6510.1016/j.ceramint.2013.05.103 ↗
8. Kuriakose S, Bhardwaj N, Singh J, Satpati B, Mohapatra S (2013) Structural, optical and photocatalytic properties of flower-like ZnO nanostructures prepared by a facile wet chemical method. Beilstein J Nanotechnol 4:763–77010.3762/bjnano.4.87 ↗
9. Aarthi T, Madras G (2007) Photocatalytic degradation of rhodamine dyes with nano-TiO2. Ind Eng Chem Res 46:7–1410.1021/ie060948n ↗
10. Hoffmann MR, Martin ST, Choi W, Bahnemann DW (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95:69–9610.1021/cr00033a004 ↗
11. Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochem Photobiol C 1:1–2110.1016/S1389-5567(00)00002-2 ↗
12. Linsebigler AL, Lu G, Yates JT Jr (1995) Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results. Chem Rev 95:735–75810.1021/cr00035a013 ↗
13. Arnold MS, Avouris P, Pan ZW, Wang ZL (2003) Field-effect transistors based on single semiconducting oxide nanobelts. J Phys Chem B 107:659–66310.1021/jp0271054 ↗
14. Ryu Y, Lee T-S, Lubguban JA, White HW, Kim B-J, Park Y-S, Youn C-J (2006) Next generation of oxide photonic devices: ZnO-based ultraviolet light emitting diodes. Appl Phys Lett 88:241108–241108-310.1063/1.2210452 ↗
15. Bhatkhande DS, Pangarkar VG, Beenackers AA (2002) Photocatalytic degradation for environmental applications—a review. J Chem Technol Biotechnol 77:102–11610.1002/jctb.532 ↗
16. Lim JH, Kang CK, Kim KK, Park IK, Hwang DK, Park SJ (2006) UV electroluminescence emission from ZnO light-emitting diodes grown by high-temperature radiofrequency sputtering. Adv Mater 18:2720–272410.1002/adma.200502633 ↗
17. Lansdown A, Taylor A (1997) Zinc and titanium oxides: Promising UV-absorbers but what influence do they have on the intact skin? Int J Cosmet Sci 19:167–17210.1111/j.1467-2494.1997.tb00180.x ↗
18. Mohammad MT, Hashim AA, Al-Maamory MH (2006) Highly conductive and transparent ZnO thin films prepared by spray pyrolysis technique. Mater Chem Phys 99:382–38710.1016/j.matchemphys.2005.11.009 ↗
19. Zhang Y, Yang Y, Zhao J, Tan R, Cui P, Song W (2009) Preparation of ZnO nanoparticles by a surfactant-assisted complex sol–gel method using zinc nitrate. J Sol–Gel Sci Technol 51:198–20310.1007/s10971-009-1959-5 ↗
20. Krishnan D, Pradeep T (2009) Precursor-controlled synthesis of hierarchical ZnO nanostructures, using oligoaniline-coated Au nanoparticle seeds. J Cryst Growth 311:3889–389710.1016/j.jcrysgro.2009.06.019 ↗
21. Pung S-Y, Lee W-P, Aziz A (2012) Kinetic study of organic dye degradation using ZnO particles with different morphologies as a photocatalyst. International Journal of Inorganic Chemistry 2012:1–910.1155/2012/608183 ↗
22. Wang M, Hahn SH, Kim JS, Chung JS, Kim EJ, Koo K-K (2008) Solvent-controlled crystallization of zinc oxide nano (micro) disks. J Cryst Growth 310:1213–121910.1016/j.jcrysgro.2008.01.001 ↗
23. Zhang L, Yang H, Ma J, Li L, Wang X, Zhang L, Tian S, Wang X (2010) Controllable synthesis and shape-dependent photocatalytic activity of ZnO nanorods with a cone and different aspect ratios and of short-and-fat ZnO microrods by varying the reaction temperature and time. Appl Phys A 100:1061–106710.1007/s00339-010-5737-6 ↗
24. Gao P, Ying C, Wang S, Ye L, Guo Q, Xie Y (2006) Low temperature hydrothermal synthesis of ZnO nanodisk arrays utilizing self-assembly of surfactant molecules at solid–liquid interfaces. J Nanopart Res 8:131–13610.1007/s11051-005-5130-0 ↗
25. Tonto P, Mekasuwandumrong O, Phatanasri S, Pavarajarn V, Praserthdam P (2008) Preparation of ZnO nanorod by solvothermal reaction of zinc acetate in various alcohols. Ceram Int 34:57–6210.1016/j.ceramint.2006.08.003 ↗
26. Abd Aziz SNQA, Pung S-Y, Lockman Z (2014) Growth of Fe-doped ZnO nanorods using aerosol-assisted chemical vapour deposition via in situ doping. Appl Phys A 116:1801–181110.1007/s00339-014-8333-3 ↗
27. Cho S, Jung S-H, Lee K-H (2008) Morphology-controlled growth of ZnO nanostructures using microwave irradiation: from basic to complex structures. J Phys Chem C 112:12769–1277610.1021/jp803783s ↗
28. Zak AK, Abrishami ME, Majid WHA, Yousefi R, Hosseini SM (2011) Effects of annealing temperature on some structural and optical properties of ZnO nanoparticles prepared by a modified sol–gel combustion method. Ceram Int 37:393–39810.1016/j.ceramint.2010.08.017 ↗
29. Vernardou D, Kenanakis G, Couris S, Koudoumas E, Kymakis E, Katsarakis N (2007) pH effect on the morphology of ZnO nanostructures grown with aqueous chemical growth. Thin Solid Films 515:8764–876710.1016/j.tsf.2007.03.108 ↗
30. Rodríguez-Paéz JE, Caballero AC, Villegas M, Moure C, Durán P, Fernández JF (2001) Controlled precipitation methods: formation mechanism of ZnO nanoparticles. J Eur Ceram Soc 21:925–93010.1016/S0955-2219(00)00283-1 ↗
31. Zhang H, Yang D, Ma X, Du N, Wu J, Que D (2006) Straight and thin ZnO nanorods: hectogram-scale synthesis at low temperature and cathodoluminescence. J Phys Chem B 110:827–83010.1021/jp055351k ↗
32. Gao X, Li X, Yu W (2005) Flowerlike ZnO nanostructures via hexamethylenetetramine-assisted thermolysis of zinc-ethylenediamine complex. J Phys Chem B 109:1155–116110.1021/jp046267s ↗
33. Jiang H, Hu J, Gu F, Li C (2009) Self-assembly of solid or tubular ZnO rods into twinning microprisms via a hydrothermal route. J Alloy Compd 478:550–55310.1016/j.jallcom.2008.11.086 ↗
34. Xia J, X-h Lu, C-s Wang, Y-x Tong, L-p Chen (2011) Electrochemical assemble of single crystalline twin ZnO nanorods. J Electrochem Soc 158:D244–D24710.1149/1.3556647 ↗
35. Thirugnanam T (2013) Effect of polymers (PEG and PVP) on sol-gel synthesis of microsized zinc oxide. J Nanomater 2013:1–710.1155/2013/362175 ↗
36. Kumar V, Kr Sharma S, Sharma T, Singh V (1999) Band gap determination in thick films from reflectance measurements. Opt Mater 12:115–11910.1016/S0925-3467(98)00052-4 ↗
37. Lee JR, Meulenberg RW, Hanif KM, Mattoussi H, Klepeis JE, Terminello LJ, van Buuren T (2007) Experimental observation of quantum confinement in the conduction band of CdSe quantum dots. Phys Rev Lett 98:146803–14680410.1103/PhysRevLett.98.146803 ↗
38. Zhang X, Qin J, Xue Y, Yu P, Zhang B, Wang L, Liu R (2014) Effect of aspect ratio and surface defects on the photocatalytic activity of ZnO nanorods. Scientific reports 4:1–8
39. Dhara S, Giri P (2011) Quick single-step mechanosynthesis of ZnO nanorods and their optical characterization: milling time dependence. Appl Nanosci 1:165–17110.1007/s13204-011-0026-z ↗
40. Ba-Abbad MM, Kadhum AAH, Bakar Mohamad A, Takriff MS, Sopian K (2013) The effect of process parameters on the size of ZnO nanoparticles synthesized via the sol–gel technique. J Alloy Compd 550:63–7010.1016/j.jallcom.2012.09.076 ↗
41. Cong Y, Zhang J, Chen F, Anpo M (2007) Synthesis and characterization of nitrogen-doped TiO2 nanophotocatalyst with high visible light activity. J Phys Chem C 111:6976–698210.1021/jp0685030 ↗
42. Djurišić A, Choy WC, Roy VAL, Leung YH, Kwong CY, Cheah KW, Gundu Rao T, Chan WK, Fei Lui H, Surya C (2004) Photoluminescence and electron paramagnetic resonance of ZnO tetrapod structures. Adv Funct Mater 14:856–86410.1002/adfm.200305082 ↗
43. Hassan N, Hashim M, Mahdi M, Allam NK (2012) A catalyst-free growth of ZnO nanowires on Si (100) substrates: effect of substrate position on morphological, structural and optical properties. ECS J Solid State Sci Technol 1:P86–P8910.1149/2.018202jss ↗
44. Wei A, Sun XW, Xu C, Dong ZL, Yang Y, Tan ST, Huang W (2006) Growth mechanism of tubular ZnO formed in aqueous solution. Nanotechnology 17:1740–174410.1088/0957-4484/17/6/033 ↗
45. Thein MT, Pung S-Y, Aziz A, Itoh M (2014) The role of ammonia hydroxide in the formation of ZnO hexagonal nanodisks using sol–gel technique and their photocatalytic study. J Exp Nanosci. doi: 10.1080/17458080.2014.95360910.1080/17458080.2014.953609 ↗
46. Wang ZL, Song J (2006) Piezoelectric nanogenerators based on zinc oxide nanowire arrays. Science 312:242–24610.1126/science.1124005 ↗
47. Jang ES, Won JH, Hwang SJ, Choy JH (2006) Fine tuning of the face orientation of ZnO crystals to optimize their photocatalytic activity. Adv Mater 18:3309–331210.1002/adma.200601455 ↗
48. Tian ZR, Voigt JA, Liu J, Mckenzie B, Mcdermott MJ, Rodriguez MA, Konishi H, Xu H (2003) Complex and oriented ZnO nanostructures. Nat Mater 2:821–82610.1038/nmat1014 ↗
49. Wang L, Chang L, Zhao B, Yuan Z, Shao G, Zheng W (2008) Systematic investigation on morphologies, forming mechanism, photocatalytic and photoluminescent properties of ZnO nanostructures constructed in ionic liquids. Inorg Chem 47:1443–145210.1021/ic701094a ↗
50. Mclaren A, Valdes-Solis T, Li G, Tsang SC (2009) Shape and size effects of ZnO nanocrystals on photocatalytic activity. J Am Chem Soc 131:12540–1254110.1021/ja9052703 ↗