journal article·2017-09Open access

Advanced oxidation of rhodamine B with hydrogen peroxide over Zn Cr layered double hydroxide catalysts

Nguyen Tien Thao, Han Thi Phuong Nga, Nguyen Que Vo, Hong Dieu Khanh Nguyen

Abstract

Zn/Cr layered zinc hydroxide materials with different molar ratios of Cr/Zn have been synthesized through the coprecipitation method at pH of 9.0–9.5. At high Cr/Zn molar ratios of 0.5/1–1/3, the materials possess some layered structure with carbonate anions between the interlayer galleries. The catalysts present uniform particle sizes and quite high surface area. An isomorphous substitution of Zn2+ by Cr3+ in the brucite-like sheets makes the layered Cr-doped zinc hydroxides potential catalysts for efficient oxidation of rhodamine B with H2O2 solution. The experimental results indicated that the intra-lattice Cr3+ ions are more active than Cr2O3 components in the oxidative removal of rhodamine B. The degradation efficiency is dependent on the intra lattice Cr3+ contents and reaction variables. The Cr/Zn LDH gave a high decolorization (99%) of rhodamine B at near neutral pH and room temperature.
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Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Catalytic Processes in Materials Science · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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