A hybrid electro-responsive SWNT/PEDOT: PSS-based membrane towards soft actuator applications

The flexible soft actuators of conducting polymers can directly convert electrical stimulus into mechanical motions, which can be used for robotics and biomimetic applications. Herein, an electro-responsive membrane actuator based on poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate), functionalized single-walled carbon nanotube was fabricated using solution casting method with poly(vinyl alcohol) as a base intermediate polymer membrane. The poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) was evenly ornamented onto the single-walled carbon nanotube/poly(vinyl alcohol) membrane (single-walled carbon nanotube/ poly(vinyl alcohol)/ poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate)) surfaces through dip coating and verified by scanning electron and transmission electron microscopy analysis. The desirable bending response of the fabricated single-walled carbon nanotube/ poly(vinyl alcohol)/poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) membrane with time at different voltages and generated tip force makes it a promising material as a new-generation conductive polymer-based soft actuator. A permutation of the electrical conductivity, more surface area, and admirable electromechanical properties of the single-walled carbon nanotube/poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) components consequences in the composite electrode exhibited excellent actuation performance compared to the ionic polymer-metal composite actuators with Pt electrodes surface. The fabricated actuator membrane can be employed for artificial muscles, robotics, and other bio-mimetic applications.