Synthesis of LiFePO4/polyacenes using iron oxyhydroxide as an iron source

Abstract LiFePO 4 /polyacenes (PAS) composite is synthesized by iron oxyhydroxide as a new raw material and phenol–formaldehyde resin as both reducing agent and carbon source. The mechanism of the reaction is outlined by the analysis of XRD, FTIR as well as TG/DSC. The results show that the formation of LiFePO 4 is started at 300 °C, and above 550 °C, the product can be mainly ascribed to olivine LiFePO 4 . The electrochemical properties of the synthesized composites are investigated by charge–discharge tests. It is found that the prepared sample at 750 °C (S750) has a better electrochemical performance than samples prepared at other temperatures. A discharge capacity of 158 mAh g −1 is delivered at 0.2 C. Under high discharge rate of 10 C, a discharge capacity of 145 mAh g −1 and good capacity retention of 93% after 800 cycles are achieved. The morphology of S750 and PAS distribution in it are investigated by SEM and TEM.