journal article·2025-06Open access

On the plasticity of MnS at elevated temperatures and its influence on damage prevalence

Maximilian A. Wollenweber, Jonas Werner, Carl F. Kusche, Chunhua Tian, Pei-Ling Sun, Jannik Gerlach, Talal Al-Samman, Sandra Korte-Kerzel

Acta Materialia· Volume 291

Abstract

Forming-induced damage strongly influences the service life and mechanical properties of components made from 16MnCrS5 steel. This damage is initiated in the vicinity of MnS inclusions, which fracture or delaminate at their interfaces due to the mechanical contrast to the steel matrix. Forming processes are often conducted at elevated temperatures; however, the plasticity of MnS at these temperatures in correlation with crystallographic orientation have not been fully explored. In this study, we aim to uncover the high-temperature properties of MnS using micropillar compression and TEM analysis . We then relate them to damage prevalence observed in steel at elevated temperatures with high resolution SEM imaging in combination with AI-assisted damage analysis. We demonstrate that the mechanical contrast of MnS and steel influences the damage prevalence significantly showing a minimum at 400 °C. We additionally determine the CRSS for the primary { 1 1 0 } 〈 1 1 ¯ 0 〉 slip system in the temperature range from 20 °C to 600 °C and the CRSS for the secondary { 1 1 1 } 〈 1 1 ¯ 0 〉 slip system at temperatures of 400 °C and 600 °C. We show that MnS exhibits a yield strength anomaly at 400 °C in specific orientations and at slow loading rates that is accompanied by a change of the active slip system. We relate this yield strength anomaly to thermally activated cross-slip and increased impurity mobility at elevated temperatures.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Energetic Materials and Combustion · High-Velocity Impact and Material Behavior · Advanced Welding Techniques Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (58)

Show source-provided references
1. Climate targets by major steel companies: an assessment of collective ambition and planned emission reduction measures
2. Sustainable development indicators in the steel industry
3. A techno-economic analysis and systematic review of carbon capture and storage (CCS) applied to the iron and steel, cement, oil refining and pulp and paper industries, as well as other high purity sources10.1016/j.ijggc.2017.03.020 ↗
4. Potential transitions in the iron and steel industry in Sweden: towards a hydrogen-based future?10.1016/j.jclepro.2018.05.142 ↗
5. The environmental impacts of an innovative modular lightweight steel system: The Elissa case10.1016/j.jclepro.2019.117905 ↗
6. The climate change challenge and transitions for radical changes in the European steel industry10.1016/j.jclepro.2007.03.001 ↗
7. Large-area, high-resolution characterisation and classification of damage mechanisms in dual-phase steel using deep learning10.1371/journal.pone.0216493 ↗
8. Characterization of damage in forward rod extruded parts10.1007/s12289-019-01525-z ↗
9. Low cycle fatigue of components manufactured by rod extrusion: Experiments and modeling
10. Lightweight in automotive components by forming technology10.1007/s42154-020-00103-3 ↗
11. Retardation of plastic instability via damage-enabled microstrain delocalization10.1007/s10853-015-9164-0 ↗
12. Martensite plasticity and damage competition in dual-phase steel: A micromechanical experimental–numerical study10.1016/j.actamat.2023.119020 ↗
13. Strain localization and damage in dual phase steels investigated by coupled in-situ deformation experiments and crystal plasticity simulations10.1016/j.ijplas.2014.06.004 ↗
14. An overview of dual-phase steels: advances in microstructure-oriented processing and micromechanically guided design10.1146/annurev-matsci-070214-021103 ↗
15. Damage in metal forming10.1016/j.cirp.2020.05.005 ↗
16. Fracture in sheet metal forming: Effect of ductile damage evolution10.1016/j.compstruc.2006.08.053 ↗
17. Forming-induced damage and its effects on product properties10.1016/j.cirp.2017.04.113 ↗
18. Damage-induced performance variations of cold forged parts10.1016/j.jmatprotec.2019.116556 ↗
19. On the automated characterisation of inclusion-induced damage in 16MnCrS5 case-hardening steel
20. Separation of damage mechanisms in full forward rod extruded case-hardening steel 16MnCrS5 using 3D image segmentation10.3390/ma17123023 ↗
21. Phase equilibria in the systems ZnS-MnS, ZnS-CuInS2, and MnS-CuInS210.1016/0022-4596(78)90125-1 ↗
22. On the mechanical properties and deformation mechanisms of manganese sulphide inclusions10.1016/j.matdes.2020.108801 ↗
23. Chao · 1962
24. Atomic-scale configurations of synchroshear-induced deformation twins in the ionic MnS crystal10.1038/srep05118 ↗
25. Mechanical properties of manganese sulphides in the temperature range between room temperature and 1000°C10.2355/isijinternational1966.25.989 ↗
26. Hardening and serrated flow behaviour in the 300–500 K range for eu-doped alkali halides10.1016/0001-6160(86)90117-3 ↗
27. Elektronenmikroskopie von Gleitlinien auf verformtem NaCl10.1002/pssb.19680260131 ↗
29. Nature of friction in extrusion process and its effect on material flow10.1179/026708303225004422 ↗
30. Deformation of non-metallic inclusions in steel during rolling process: a review10.2355/isijinternational.ISIJINT-2022-235 ↗
31. High resolution in situ mapping of microstrain and microstructure evolution reveals damage resistance criteria in dual phase steels10.1016/j.actamat.2015.05.038 ↗
32. Optical microscopy-based damage quantification: an example of cryogenic deformation of a dual-phase steel10.2355/isijinternational.ISIJINT-2017-468 ↗
33. Chao · 1962
34. The high-temperature hardness of various phases in steel10.1179/030716974803287834 ↗
35. High-temperature deformation behavior of MnS in 1215MS steel10.1007/s12540-018-0137-0 ↗
36. On the Mn-MnS phase diagram10.1007/BF02652829 ↗
37. Discrete dislocation simulations of compression of tapered micropillars10.1016/j.jmps.2017.01.015 ↗
38. Deformation of μm-and mm-sized Fe2. 4wt bi-crystals with a high angle grain boundary at room temperature10.1016/j.actamat.2020.04.011 ↗
39. Finding and characterising active slip systems: a short review and tutorial with automation tools10.3390/ma14020407 ↗
40. VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data10.1107/S0021889811038970 ↗
41. Investigation of cross-slip events in NaCl crystals by transmission electron microscopy10.1002/pssa.2210280111 ↗
42. First-principles calculations on slip system activation in the rock salt structure: Electronic origin of ductility in silver chloride10.1080/14786435.2017.1294270 ↗
43. Size-dependent plasticity in micron-and submicron-sized ionic crystals10.1080/09500839.2013.797616 ↗
44. Dislocations and plastic deformation in MgO crystals: a review10.3390/cryst8060240 ↗
45. Dislocations and the plasticity of ionic crystals10.1179/mst.1985.1.12.1013 ↗
46. Dislocations and mechanical properties of MgO-Al2O3 spinel single crystals10.1111/j.1151-2916.1999.tb02244.x ↗
47. Effect of impurities on the flow stress of LiF crystals10.1063/1.1728892 ↗
48. Yield-stress anomalies and high-temperature mechanical properties of intermetallics and disordered alloys10.1016/S0921-5093(00)02017-7 ↗
49. The yield strength and dynamic behaviour of dislocations in MgO crystals at high temperatures10.1007/BF00550578 ↗
50. Work hardening in ionic crystals10.1080/14786437008238483 ↗
51. Dislocation motion in secondary slip planes in alkali halide crystals at room temperature10.1002/pssb.19700380227 ↗
52. Discussion of the dependence of the effect of size on the yield stress in hard materials studied by microcompression of MgO10.1080/14786435.2010.505179 ↗
53. Microcompression of brittle and anisotropic crystals: recent advances and current challenges in studying plasticity in hard materials10.1557/mrc.2017.15 ↗
54. Effect of MnS inclusions on deformation behavior of matrix based on in-situ experiment10.1016/j.msea.2018.12.121 ↗
55. Effect of MnS inclusions on plastic deformation and fracture behavior of the steel matrix at high temperature10.1016/j.vacuum.2020.109209 ↗
56. Influence of non-metallic inclusions on local deformation and damage behavior of modified 16MnCrS5 steel10.3390/cryst12020281 ↗
57. Abnormal austenite–ferrite transformation behaviour of pure iron10.1080/14786430410001663178 ↗
58. On the properties of a-MnS and MnS210.3891/acta.chem.scand.19-1405 ↗