High strain rate persistence of the strength anomaly in the L12 intermetallic compound Ni3Si evidenced by nanoindentation testing
Source abstract
Abstract
L1 2 intermetallic compounds are essential constituents of the nickel-based superalloys widely used in jet engines. They derive their exceptional high-temperature mechanical properties from the yield strength anomaly mechanism. Despite potential safety implications for collisions, e.g. bird strikes, conclusive evidence of its persistence at high strain rates has remained elusive. This is mostly due to experimental limitations, which are overcome here by combining high strain rate and high temperature testing within a single nanoindentation testing system to investigate the evolution of the strength anomaly in the L1 2 single-phase Ni 3 Si for strain rates between 0.1 and 100 s −1 . High strain rates are found to extend the anomalous behavior toward higher temperatures, while the onset and peak temperatures of the strength anomaly remain largely insensitive to the applied strain rate . These experimental findings validate basic assumptions from the Paidar–Pope–Vitek (PPV) theory of its origin. In addition, high strain rates are found to increase the peak anomalous hardness, owing to the overall positive strain rate sensitivity of the L1 2 compound.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal and Thin Film Mechanics · Intermetallics and Advanced Alloy Properties · Advanced Materials Characterization Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (75)
Show source-provided references
1. Nabarro · 1996
2. Mechanical-properties of L1(2) intermetallic compounds10.1088/0031-8949/1993/T49B/002 ↗
3. Microstructure, phase transition and tribological performances of Ni3Si-based self-lubricating composite coatings10.1016/j.jallcom.2012.12.079 ↗
4. The temperature dependence of the flow stress of the γ′ phase based upon Ni3Al10.1007/BF02819263 ↗
5. Temperature and orientation dependence of the yield stress in Ni3Ga single crystals10.1016/0001-6160(73)90198-3 ↗
6. A theory of the anomalous yield behavior in L12 ordered alloys10.1016/0001-6160(84)90117-2 ↗
7. Dislocation structures and anomalous flow in L12 compounds
8. The operation of Frank–Read sources, yield stress reversibility and the strain-rate dependence of the flow stress in the anomalous yielding regime of L12 alloys10.1080/01418619508239931 ↗
9. A new theory of the anomalous yield stress in L12 alloys10.1080/01418619208201539 ↗
10. The Flow Strength Anomaly in Metals and Intermetallic Compounds
11. A theory of the temperature and strain rate dependence of the yield stress of L12 compounds in the anomalous regime10.1016/0956-716X(91)90253-W ↗
12. On the abnormal negative temperature dependence of yield strength in the L12 compound Fe3Ge10.1080/01418619208205602 ↗
13. A simulation of dislocation dynamics and of the flow stress anomaly in L12 alloys10.1080/01418619708209856 ↗
14. A model for the anomalous mechanical properties of nickel-base L12 ordered alloys—II. Cross-slip processes and mechanical properties10.1016/1359-6454(95)00389-4 ↗
15. Influence of Fe substitutions on the deformation behavior and fault energies of Ni3Ge–Fe3Ge L12 intermetallic alloys10.1016/S1359-6454(01)00097-0 ↗
16. Hull · 2011
17. Kear–Wilsdorf locks and mechanical properties of L12 Alloys10.1557/PROC-288-411 ↗
18. Dislocation configurations in plastically deformed polycrystalline Cu3Au alloys
19. Hollomon · 1979
20. The effect of strain rate on the flow stress and dislocation behavior of a precipitation-hardened nickel-base alloy10.1016/0025-5416(71)90050-4 ↗
21. Temperature and strain rate dependence of stress-strain behavior in a nickel-base superalloy10.1007/BF02811675 ↗
22. Anomalous behaviors of a single-crystal Nickel-base superalloy over a wide range of temperatures and strain rates10.1016/j.mechmat.2015.11.015 ↗
23. New ultra-high temperature nanoindentation system for operating at up to 1100 °C10.1016/j.matdes.2020.108727 ↗
24. On extracting mechanical properties from nanoindentation at temperatures up to 1000 °C10.1016/j.eml.2017.09.007 ↗
25. High temperature nanoindentation: the state of the art and future challenges10.1016/j.cossms.2015.02.002 ↗
26. High-temperature scanning indentation: a new method to investigate in situ metallurgical evolution along temperature ramps10.1557/s43578-021-00107-7 ↗
27. Mechanical softening of CuX alloys at elevated temperatures studied via high temperature scanning indentation10.1016/j.matdes.2024.112865 ↗
28. Development of high temperature nanoindentation methodology and its application in the nanoindentation of polycrystalline tungsten in vacuum to 950 °C10.1007/s11340-016-0209-3 ↗
29. High temperature nanoindentation as a tool to investigate plasticity upon phase transformations demonstrated on Cobalt10.1016/j.mtla.2021.101084 ↗
30. Critical issues in conducting constant strain rate nanoindentation tests at higher strain rates10.1557/jmr.2019.292 ↗
31. Extending the range of constant strain rate nanoindentation testing10.1557/jmr.2019.408 ↗
32. Advances in the measurement of hardness at high strain rates by nanoindentation10.1557/s43578-023-00921-1 ↗
33. High strain rate nanoindentation testing: recent advancements, challenges and opportunities
34. P. Villars, H. Okamoto (Eds.), Binary Phase Diagram 0-27 at.% Si: Datasheet from “Pauling File Multinaries Edition-2022, SpringerMaterials, n.d.
35. The formation of regular αNi-γ(Ni31Si12) eutectic structures from undercooled Ni–25 at.% Si melts10.1016/j.intermet.2011.10.021 ↗
36. On the strain rate sensitivity measured by nanoindentation at high strain rates10.1007/s11837-023-06338-9 ↗
37. Evolution of dislocation substructures in metals via high-strain-rate nanoindentation10.1073/pnas.2310500120 ↗
38. Creep of a thermally stable nanocrystalline nickel tungsten alloy as measured by high temperature nanoindentation10.1016/j.msea.2020.139309 ↗
39. Synthesis and characterization of metal carbides for nanoindentation tip applications10.1063/5.0140501 ↗
40. Invited article: indenter materials for high temperature nanoindentation10.1063/1.4824710 ↗
41. Nanomechanical behaviour of individual phases in WC-Co cemented carbides, from ambient to high temperature10.1016/j.mtla.2020.100713 ↗
42. Quantification of softening kinetics in cold-rolled pure aluminum and copper using high-temperature scanning indentation10.1016/j.matdes.2023.112171 ↗
43. Thermally activated deformation behavior of ufg-Au: environmental issues during long-term and high-temperature nanoindentation testing10.1007/s11837-015-1638-7 ↗
44. Elevated temperature, in situ indentation with calibrated contact temperatures10.1080/14786435.2012.674647 ↗
45. A micro-indentation study of superplasticity in Pb, Sn, and Sn-38 wt.% Pb10.1016/0001-6160(88)90319-7 ↗
46. Indentation power-law creep of high-purity indium10.1007/s11661-999-0051-7 ↗
47. High-strain-rate nanoindentation behavior of fine-grained magnesium alloys10.1557/jmr.2012.52 ↗
48. High strain rate testing at the nano-scale: a proposed methodology for impact nanoindentation10.1016/j.matdes.2018.04.045 ↗
49. New instrumentation and analysis methodology for nano-impact testing10.1016/j.matdes.2020.108715 ↗
50. Nano-impact indentation for high strain rate testing: the influence of rebound impacts10.1016/j.eml.2018.11.005 ↗
51. Exponential temperature dependence of Young’s modulus for several oxides10.1103/PhysRev.122.1754 ↗
52. Rösler · 2007
53. Elastic constants of face-centered cubic and L12 Ni-Si alloys: composition and temperature dependence10.1007/s11661-003-0151-8 ↗
54. Improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments10.1557/JMR.1992.1564 ↗
55. Mechanical properties and chemical bonding characteristics of WC and W2C compounds10.1016/j.ceramint.2013.10.022 ↗
56. The indentation size effect: a critical examination of experimental observations and mechanistic interpretations10.1146/annurev-matsci-070909-104456 ↗
57. Indentation size effects in crystalline materials: a law for strain gradient plasticity10.1016/S0022-5096(97)00086-0 ↗
58. Dynamic nanoindentation testing for studying thermally activated processes from single to nanocrystalline metals10.1016/j.cossms.2015.02.001 ↗
59. Advanced nanoindentation testing for studying strain-rate sensitivity and activation volume10.1007/s11837-017-2536-y ↗
60. Determination of plastic properties of polycrystalline metallic materials by nanoindentation: experiments and finite element simulations10.1080/14786430600735468 ↗
61. First-principles study of nickel-silicides ordered phases10.1016/j.jallcom.2010.10.118 ↗
62. The temperature dependence of hardness of Ll2 ordered alloys10.2320/matertrans1960.20.634 ↗
63. Tensile properties of Ni-based superalloy 720Li: temperature and strain rate effects10.1007/s11661-008-9585-3 ↗
64. Hot deformation behavior and flow stress modeling of a Ni-based superalloy10.1016/j.matchar.2019.109915 ↗
65. The activation parameters for dislocation glide10.1080/14786436708229259 ↗
66. Chen · 2010
67. An investigation of the mechanical properties of materials at very high rates of loading10.1088/0370-1301/62/11/302 ↗
68. Some experiments with the split hopkinson pressure bar10.1016/0022-5096(64)90028-6 ↗
69. Segregation-induced strength anomalies in complex single-crystalline superalloys10.1038/s43246-024-00447-x ↗
70. Nanoindentation strain-rate jump tests for determining the local strain-rate sensitivity in nanocrystalline Ni and ultrafine-grained Al10.1557/jmr.2011.156 ↗
71. An improved long-term nanoindentation creep testing approach for studying the local deformation processes in nanocrystalline metals at room and elevated temperatures10.1557/jmr.2013.39 ↗
72. A novel pillar indentation splitting test for measuring fracture toughness of thin ceramic coatings10.1080/14786435.2014.913110 ↗
73. Experimental determination of the effective indenter shape and epsilon-factor for nanoindentation by continuously measuring the unloading stiffness10.1557/jmr.2011.245 ↗
74. Temperature dependence of strain rate sensitivity, indentation size effects and pile-up in polycrystalline tungsten from 25 to 950 °C10.1016/j.matdes.2018.06.063 ↗
75. Influences of pileup on the measurement of mechanical properties by load and depth sensing indentation techniques10.1557/JMR.1998.0146 ↗