journal article·2022-12

Phase-formation maps of CuZrAlCo metallic glass explored by in situ ultrafast techniques

Xiaoliang Han, Ivan Kaban, Jiri Orava, Qi Cheng, Yong Hao Sun, Ivan Soldatov, Martin v. Zimmermann, Kaikai Song, Kornelius Nielsch

Acta Materialia· Volume 241
Publisher page

Abstract

Crystallization of Cu$47.5$Zr$48$Al$_4$Co$0.5$ metallic glass upon isokinetic and isothermal annealing is studied by conventional and ultrafast differential scanning calorimetry, resistive flash-annealing, and in situ high-energy X-ray diffraction. The fast-heating experiments of Cu$47.5$Zr$48$Al$_4$Co$0.5$ metallic glass are complemented by in situ high-energy XRD studies of the undercooled liquid by using electromagnetic levitation. The combination of complementary techniques reveals a competition between the Cu$10$Zr$_7$, B$_2$ CuZr and $τ_4$ Cu$_2$ZrAl phases crystallization depending on heating rate and shows the specific role of Co alloying. A continuous-heating-transformation diagram for a heating rate exceeding six orders of magnitude, $Φ$ = 0.0833 − 90 000 K s$−1$, and a time-temperature-transformation diagram are constructed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · Phase-change materials and chalcogenides · Solidification and crystal growth phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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