journal article·2024-01

Orientation dependent plasticity of the refractory multi-principal element alloy MoNbTi investigated via micropillar compression

G.H. Balbus, S.I. Rao, O.N. Senkov, E.J. Payton

Acta Materialia· Volume 262
Publisher page

Abstract

Refractory multi-principal element alloys (RMPEAs) are promising candidate materials for use in high temperature structural applications and other extreme environments. Recent experiments and simulations have highlighted the unusual deformation behavior of an equiatomic MoNbTi alloy, which exhibits slip on higher order planes and sluggish edge dislocation mobility. In this work, we utilize micropillar compression and postmortem transmission electron microscopy to elucidate the orientation dependent deformation behavior of MoNbTi. Our results suggest that deformation in this system is largely mediated by kink-migration of screw dislocations, as evidenced by the presence of long screw dislocations and significant dislocation debris in postmortem observations, and the absence of twinning/anti-twinning asymmetry. Moreover, we report an unusual orientation dependence of the yield strength, owing to the high stress required to facilitate slip on {110} type planes. These results further demonstrate the unconventional plasticity in BCC RMPEAs, and provide experimental verification that kink-migration is the rate limiting feature in this alloy at low temperatures.
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Research context

OpenAlex topics: Intermetallics and Advanced Alloy Properties · High Entropy Alloys Studies · High-Temperature Coating Behaviors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Development and exploration of refractory high entropy alloys - A review10.1557/jmr.2018.153 ↗
2. Progress and challenges in the theory and modeling of complex concentrated alloys10.1557/s43577-022-00306-5 ↗
3. Caillard · 2003
4. Thermally-activated deformation of BCC metals and alloys10.1016/0079-6425(92)90004-Q ↗
5. An investigation of the mechanism of thermally activated deformation in tantalum and tantalum-base alloys10.1016/0001-6160(66)90003-4 ↗
6. The thermally activated deformation of niobium-molybdenum and niobium-rhenium alloy single crystals10.1080/14786437208227366 ↗
7. A detailed study of the deformation of high purity niobium single crystals10.1080/14786436908228040 ↗
8. Stress asymmetries in the deformation behaviour of niobium single crystals10.1016/0001-6160(83)90061-5 ↗
9. Plastic deformation of tantalum single crystals. II. The orientation dependence of yield10.1016/0022-5088(68)90115-X ↗
10. Some surprising features of the plastic deformation of body-centered cubic metals and alloys10.1007/BF02664806 ↗
11. Atomistic study of non-Schmid effects in the plastic yielding of bcc metals10.1080/01418610110033885 ↗
12. Non-planar dislocation cores: a ubiquitous phenomenon affecting mechanical properties of crystalline materials10.1016/S1572-4859(07)00007-1 ↗
13. Plastic anisotropy in b.c.c. transition metals10.1016/S1359-6454(97)00367-4 ↗
14. Slip planes in bcc transition metals10.1179/1743280412Y.0000000015 ↗
15. Kinetics of dislocations in pure Fe. Part I. In situ straining experiments at room temperature10.1016/j.actamat.2010.02.023 ↗
16. Kinetics of dislocations in pure Fe. Part II. In situ straining experiments at low temperature10.1016/j.actamat.2010.02.024 ↗
17. Geometry and kinetics of glide of screw dislocations in tungsten between 95K and 573K10.1016/j.actamat.2018.09.009 ↗
18. Mobility of screw dislocation in BCC tungsten at high temperature in presence of carbon10.1016/j.actamat.2021.117440 ↗
19. Predicting core structure variations and spontaneous partial kink formation for ½<111>screw dislocations in three BCC NbTiZr alloys10.1016/j.scriptamat.2021.113834 ↗
20. Modeling solution hardening in BCC refractory complex concentrated alloys: NbTiZr, Nb1.5TiZr0.5 and Nb0.5TiZr1.510.1016/j.actamat.2019.02.013 ↗
21. Theory of kink migration in dilute BCC alloys10.1016/j.actamat.2021.117078 ↗
22. Theory of screw dislocation strengthening in random BCC alloys from dilute to “High-Entropy” alloys10.1016/j.actamat.2019.10.007 ↗
23. Transitions in the morphology and critical stresses of gliding dislocations in multiprincipal element alloys10.1103/PhysRevMaterials.6.013605 ↗
24. Cross-kinks control screw dislocation strength in equiatomic bcc refractory alloys10.1016/j.actamat.2021.116875 ↗
25. Strength can be controlled by edge dislocations in refractory high-entropy alloys
26. Multiplicity of dislocation pathways in a refractory multiprincipal element alloy10.1126/science.aba3722 ↗
27. Local slip resistances in equal-molar MoNbTi multi-principal element alloy10.1016/j.actamat.2020.10.042 ↗
28. High temperature strength of refractory complex concentrated alloys10.1016/j.actamat.2019.06.032 ↗
29. Comprehensive data compilation on the mechanical properties of refractory high-entropy alloys10.1016/j.dib.2018.10.071 ↗
30. Ductile Nb alloys with reduced density and cost10.1016/j.jallcom.2019.151685 ↗
31. Effect of Fe additions on the microstructure and properties of Nb-Mo-Ti alloys10.1016/j.ijrmhm.2020.105221 ↗
32. A methodology to investigate size scale effects in crystalline plasticity using uniaxial compression testing10.1016/j.msea.2005.03.082 ↗
33. Sample dimensions influence strength and crystal plasticity10.1126/science.1098993 ↗
34. Plasticity of micrometer-scale single crystals in compression10.1146/annurev-matsci-082908-145422 ↗
35. Dislocation structures and their relationship to strength in deformed nickel microcrystals10.1016/j.actamat.2008.02.046 ↗
36. Texture analysis with MTEX – free and open source software toolbox10.4028/www.scientific.net/SSP.160.63 ↗
37. Orientations – perfectly colored10.1107/S1600576716012942 ↗
38. pycotem: an open source toolbox for online crystal defect characterization from TEM imaging and diffraction10.1111/jmi.12982 ↗
39. The crystallographic aspect of slip in body-centered cubic single crystals. I. Theoretical considerations10.1063/1.1699870 ↗
40. Slip transmission of high angle grain boundaries in body-centered cubic metals: micropillar compression of pure Ta single and bi-crystals10.1016/j.actamat.2018.06.046 ↗
41. Influence of strain rate on the activation of {110}, {112}, {123} slip in ferrite of DP80010.1016/j.mtla.2020.100983 ↗
42. On the mechanical heterogeneity in dual phase steel grades: activation of slip systems and deformation of martensite in DP80010.1016/j.actamat.2019.11.002 ↗
43. Ferrite slip system activation investigated by uniaxial micro-tensile tests and simulations10.1016/j.actamat.2017.12.054 ↗
44. Low temperature atomic-scale observations of slip traces in niobium10.1016/j.scriptamat.2020.03.026 ↗
45. Avalanche statistics and the intermittent-to-smooth transition in microplasticity
46. Influence of loading control on strain bursts and dislocation avalanches at the nanometer and micrometer scale10.1103/PhysRevB.95.064103 ↗
47. The influence of nano/micro sample size on the strain-rate sensitivity of plastic flow in tungsten10.1016/j.ijplas.2020.102854 ↗
48. Temperature-dependent size effects on the strength of Ta and W micropillars10.1016/j.actamat.2015.10.016 ↗
49. Influence of orientation on the size effect in bcc pillars with different critical temperatures10.1016/j.msea.2010.10.073 ↗
50. Contribution to size effect of yield strength from the stochastics of dislocation source lengths in finite samples10.1016/j.scriptamat.2006.09.016 ↗
51. Strain bursts in plastically deforming molybdenum micro- and nanopillars10.1080/14786430802132522 ↗
52. Elastic constants of Ti –40 at .% Nb at 298° K10.1063/1.1662365 ↗
53. The plasticity of pure niobium single crystals
54. Orientation and temperature dependence of slip in iron single crystals10.1007/BF03037811 ↗
55. Anti-twinning in nanoscale tungsten
56. The flow-stress asymmetry of ultra-pure molybdenum single crystals10.2320/matertrans1989.41.141 ↗
57. Tensile and compressive behavior of tungsten, molybdenum, tantalum and niobium at the nanoscale10.1016/j.actamat.2009.12.022 ↗
58. Screw-controlled strength of BCC non-dilute and high-entropy alloys10.1016/j.actamat.2022.117617 ↗
59. Cross-kink unpinning controls the medium- to high-temperature strength of body-centered cubic NbTiZr medium-entropy alloy10.1016/j.scriptamat.2021.114367 ↗
60. Plastic deformation of solid-solution strengthened Hf-Nb-Ta-Ti-Zr body-centered cubic medium /high-entropy alloys10.1016/j.scriptamat.2021.113927 ↗
61. Surface-controlled dislocation multiplication in metal micropillars10.1073/pnas.0806118105 ↗
62. Size-dependent plasticity in an Nb25Mo25Ta 25W25 refractory high-entropy alloy10.1016/j.actamat.2013.11.049 ↗
63. Eine neue methode zur herstellung verformungsfreier Einkristall-Zugproben hochschmelzender Metalle und einige Ergebnisse über de plastische Deformation von Niob-Einkristallen10.1002/pssb.19640050218 ↗
64. Three-stage hardening in tantalum single crystals10.1016/0001-6160(65)90054-4 ↗
65. Über die plastische dehnung von α-Eisenkristallen10.1007/BF01342203 ↗
66. The effect of orientation and temperature on the plastic flow properties of iron single crystals10.1016/0001-6160(70)90090-8 ↗
67. Line-length-dependent dislocation glide in refractory multi-principal element alloys10.1063/5.0080849 ↗
68. Theory of solid solution strengthening of BCC chemically complex alloys10.1016/j.actamat.2021.116758 ↗
69. Mechanistic origin of high strength in refractory BCC high entropy alloys up to 1900K10.1016/j.actamat.2019.10.015 ↗
70. Atomic scale structure of sputtered metal multilayers10.1016/S1359-6454(01)00287-7 ↗
71. A model for interstitial solid solution strengthening of body centered cubic metals10.1016/j.mtla.2020.100611 ↗
72. Long-range empirical potential model: extension to hexagonal close-packed metals10.1088/0953-8984/21/38/385402 ↗
73. FIB damage of Cu and possible consequences for miniaturized mechanical tests10.1016/j.msea.2007.01.046 ↗
74. Chemical short range order strengthening in BCC complex concentrated alloys10.1016/j.actamat.2021.117012 ↗
75. {110} Slip with {112} slip traces in bcc Tungsten10.1038/srep02547 ↗
76. Slip line pattern and active slip systems of tungsten and molybdenum single crystals weakly deformed in tension at room temperature10.1002/pssb.19680260212 ↗
77. Plastic Deformation of Tungsten Single Crystals at Low Temperatures10.1016/0001-6160(66)90165-9 ↗
78. Slip planes and kink properties of screw dislocations in high-purity niobium10.1080/14786430500531769 ↗
79. Dislocation relaxation processes in bcc metals: β versus γ relaxation10.1080/09500830310001628239 ↗
80. Frottement intérieur à basse température dans le fer de haute pureté
81. Temperature and strain-rate dependence of the tensile flow stress of high-purity α-iron below 250K. I. Stress/temperature regime III10.1002/pssa.2211240210 ↗
82. Work hardening and flow stress of ultrapure molybdenum single crystals10.1016/S0921-5093(01)01002-4 ↗
83. The flow stress of ultra-high-purity mo single crystals10.1002/1521-396X(199704)160:2<329::AID-PSSA329>3.0.CO;2-O ↗
84. Progress and problems in the understanding of the dislocation relaxation processes in metals10.1016/j.msea.2003.08.072 ↗
85. A TEM in situ study of the softening of tungsten by Rhenium10.1016/j.actamat.2020.04.039 ↗
86. Effect of rhenium on the dislocation core structure in tungsten10.1103/PhysRevLett.104.195503 ↗
87. On the importance of sample compliance in uniaxial microtesting10.1016/j.scriptamat.2008.09.024 ↗
88. Micro-compression testing: a critical discussion of experimental constraints10.1016/j.msea.2009.01.005 ↗
89. A phenomenological dislocation mobility law for bcc metals10.1016/j.actamat.2016.08.016 ↗
90. Multiscale modeling of plastic deformation of molybdenum and tungsten: I. Atomistic studies of the core structure and glide of 1/2〈1 1 1〉 screw dislocations at 0K10.1016/j.actamat.2008.07.018 ↗
91. Non-glide effects and dislocation core fields in BCC metals10.1038/s41524-019-0247-3 ↗
92. Impact of non-Schmid stress components present in the yield criterion for bcc metals on the activity of {110}〈111〉 slip systems10.1016/j.commatsci.2018.12.021 ↗
93. Size-affected single-slip behavior of René N5 microcrystals10.1016/j.msea.2011.12.041 ↗
94. Breakdown of Schmid's law in micropillars10.1016/j.scriptamat.2008.06.019 ↗
95. Deformation and fracture of tungsten single crystals10.1016/0022-5088(65)90094-9 ↗
96. Plastic anisotropy and dislocation trajectory in BCC metals10.1038/ncomms11695 ↗
97. Ab initio informed yield criterion across body-centered cubic transition metals10.1016/j.actamat.2022.118098 ↗
98. Screw dislocations in BCC transition metals: from ab initio modeling to yield criterion10.5802/crphys.75 ↗
99. Theory of double-kink nucleation in dilute BCC alloys10.1016/j.actamat.2020.07.008 ↗
100. Orientation dependent plastic localization in the refractory high entropy alloy HfNbTaTiZr at room temperature10.1016/j.msea.2022.143291 ↗