journal article·2016-05Open access

Stability of three-phase ternary-eutectic growth patterns in thin sample

Sabine Bottin-Rousseau, Melis Şerefoğlu, Sinan Yücetürk, Gabriel Faivre, Silvère Akamatsu

Acta Materialia· Volume 109

Abstract

Near-eutectic ternary alloys subjected to thin-sample directional solidification can exhibit stationary periodic growth patterns with an ABAC repeat unit, where A, B and C are the three solid phases in equilibrium with the liquid at the eutectic point. We present an in-situ experimental study of the dynamical features of such patterns in a near-eutectic In-In 2 Bi-Sn alloy. We demonstrate that ABAC patterns have a wide stability range of spacing at given growth rate. We study quantitatively the-di↵usion process that is responsible for the spacing uniformity of steady-state patterns inside the stability interval. The instability processes that determine the limits of this interval are examined. Qualitatively, we show that ternary-eutectic ABAC patterns essentially have the same dynamical features as two-phase binary-eutectic patterns. However, lamella elimination (low-stability limit) occurs before any Eckhaus instability manifests itself. We also report observations of stationary patterns with an [AB] m [AC] n superstructure, where m and n are integers larger than unity.
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Research context

OpenAlex topics: Solidification and crystal growth phenomena · nanoparticles nucleation surface interactions · Aluminum Alloy Microstructure Properties

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References (18)

Show source-provided references
1. Lamellar and rod eutectic growth
2. In situ observation of microstructure evolution in low-melting Bi-In-Sn alloys by light microscopy10.1016/j.actamat.2005.04.015 ↗
3. Phase equilibria and eutectic growth in quaternary organic alloys amino-methyl-propanediol-(D)camphor-neopentylglycol-succinonitrile (AMPD-DC-NPG-SCN)10.1016/j.jcrysgro.2006.09.004 ↗
4. Theoretical and numerical study of lamellar eutectic three-phase growth in ternary alloys
5. Boettinger · 1972
6. Origin of microstructure in the 332 K eutectic of the Bi-In-Sn system10.1179/mst.1997.13.1.5 ↗
7. Morphological instabilities of lamellar eutectics10.1007/BF02648952 ↗
8. Experimental determination of the stability diagram of a lamellar eutectic growth front10.1103/PhysRevE.56.780 ↗
9. Overstability of lamellar eutectic growth below the minimum-undercooling spacing10.1007/s11661-004-0090-z ↗
10. Determination of the Jackson-Hunt constants of the In-In2​Bi eutectic alloy based on in situ observation of its solidification dynamics10.1016/j.actamat.2011.08.036 ↗
11. P. Manneville, Dissipative structures and weak turbulence, Academic Press.
12. Thermodynamic re-optimisation of the Bi-In-Sn system based on new experimental data10.1016/j.jallcom.2006.03.050 ↗
13. Real-time study of thin and bulk eutectic growth in succinonitrile-(D)camphor alloys10.1016/j.jcrysgro.2006.11.271 ↗
14. Lamellar eutectic growth of CBr4-C2Cl6: effect of crystal anisotropy on lamellar orientations and wavelength dispersion10.1016/0022-0248(92)90058-Q ↗
15. A theory of thin lamellar eutectic growth with anisotropic interphase boundaries10.1016/j.actamat.2012.02.031 ↗
16. The formation of lamellar-eutectic grains in thin samples10.1007/s11661-001-0016-y ↗
17. Transient eutectic solidification in In-Bi-Sn: Two-dimensional experiments and numerical simulation10.1016/j.msea.2005.09.019 ↗
18. Critical role of crystalline anisotropy in the stability of cellular array structures in directional solidification10.1103/PhysRevLett.77.3387 ↗