journal article·2017-02Open access

Interface dynamics in one-dimensional nanoscale Cu/Sn couples

Qiyue Yin, Fan Gao, Zhiyong Gu, Jirui Wang, Eric A. Stach, Guangwen Zhou

Acta Materialia· Volume 125

Abstract

Abstract The isothermal metallurgical reaction in two-segmented Cu-Sn nanowires results in the formation of a Sn/Cu6Sn5/Cu3Sn/Cu sandwich structure. In-situ transmission electron microscopy is used to study how Cu6Sn5/Sn and Cu/Cu3Sn interfaces propagate and change shape during the intermetallic compound growth. The Cu6Sn5/Sn interface is observed to evolve from an inclined configuration to a vertical, edge-on configuration with the propagation of the Cu6Sn5 phase towards the Sn segment. The Cu/Cu3Sn interface also becomes less inclined as it propagates toward the Cu segment. This interface evolution is driven by the minimization of the interface energy associated with minimizing the interface area associated with the edge-on interface. The Kirkendall void growth induces the breakage of the Cu segment and results in the Cu3Sn → Cu6Sn5 transformation with the final Sn/Cu6Sn5/void/Cu sandwich structure.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electronic Packaging and Soldering Technologies · Advancements in Semiconductor Devices and Circuit Design · Surface and Thin Film Phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (26)

Show source-provided references
1. Scalable synthesis and device integration of self-registered one-dimensional zinc oxide nanostructures and related materials10.1039/C2CS35164A ↗
2. Review: developments in micro/nanoscale fabrication by focused ion beams10.1016/j.vacuum.2011.11.004 ↗
3. Reflow and electrical characteristics of nanoscale solder10.1002/smll.200500296 ↗
4. Well-aligned open-ended carbon nanotube architectures: an approach for device assembly10.1021/nl052183z ↗
5. Nanowire joining methods10.2174/1876531901103010091 ↗
6. Self-generated local heating induced nanojoining for room temperature pressureless flexible electronic packaging
7. Robust Ag nanoplate ink for flexible electronics packaging10.1039/C5NR00312A ↗
8. Long term stability of nanowire nanoelectronics in physiological environments10.1021/nl500070h ↗
9. Sub-10-nm intracellular bioelectronic probes from nanowire–nanotube heterostructures10.1073/pnas.1323389111 ↗
10. Intracellular recordings of action potentials by an extracellular nanoscale field-effect transistor10.1038/nnano.2011.223 ↗
11. Toward the development of printable nanowire electronics and sensors10.1002/adma.200900860 ↗
12. Silicon nanowire field-effect transistor-based biosensors for biomedical diagnosis and cellular recording investigation10.1016/j.nantod.2011.02.001 ↗
13. Nanoscale characterization of 1D Sn-3.5 Ag nanosolders and their application into nanowelding at the nanoscale10.1088/0957-4484/25/42/425301 ↗
14. Realization of the welding of individual TiO 2 semiconductor nano-objects using a novel 1D Au 80 Sn 20 nanosolder10.1039/C5TC01267H ↗
15. Microstructure and interdiffusion of template-synthesized Au/Sn/Au junction nanowires10.1021/nl0492988 ↗
16. Synthesis, characterization, and thermal properties of nanoscale lead-free solders on multisegmented metal nanowires10.1021/jp8112396 ↗
17. In situ visualization of metallurgical reactions in nanoscale Cu/Sn diffusion couples10.1039/C4NR06757F ↗
18. Tu · 2007
19. Eliminate Kirkendall voids in solder reactions on nanotwinned copper10.1016/j.scriptamat.2012.10.024 ↗
20. The Cu-Sn (copper-tin) system10.1007/BF03029299 ↗
21. The Cu–Sn phase diagram part II: new thermodynamic assessment10.1016/j.intermet.2012.10.010 ↗
22. Some aspects of the growth of diffusion layers in binary systems10.1016/0022-3115(61)90175-1 ↗
23. Interface thermodynamics of nano-sized crystalline, amorphous and liquid metallic systems10.1016/j.jallcom.2007.11.106 ↗
24. Crystallization of amorphous superlattices in the limit of ultrathin films with oxide interfaces10.1103/PhysRevB.62.8391 ↗
25. Thermodynamic stability of amorphous oxide films on metals: application to aluminum oxide films on aluminum substrates10.1103/PhysRevB.62.4707 ↗
26. Grain boundary complexions: the interplay of premelting, prewetting, and multilayer adsorption,10.1063/1.3212733 ↗