Low power reconfigurable multilevel nanophotonic devices based on Sn-doped Ge2Sb2Te5 thin films
Source abstract
Abstract
In the past years, Ge2Sb2Te5 has been considered a promising functional material for a variety of reconfigurable multilevel devices, including photonic integrated circuits for the post-von Neumann arithmetic processing. However, despite significant advances, it is necessary to reduce the switching energy of Ge2Sb2Te5 for creation of the on-chip low power all-photonic spiking neural networks. The present work focuses on the effect of tin ion implantation on the properties of amorphous Ge2Sb2Te5 thin films, as well as on the performance of Mach-Zehnder interferometers and balanced beam splitters based on them. As a result, Sn-doping accompanied by the formation of weaker bonds in Ge2Sb2Te5 thin films is an efficient approach to significantly reduce the threshold energy of fs-laser initiated phase transitions and change the effective absorption coefficient. The possibility of using the Sn-doped Ge2Sb2Te5 thin films for fully optical multilevel reversible recording between 9 different levels (3 bits) has been demonstrated by experimental measurements of fabricated on-chip balanced beam splitters. The obtained results show that the Sn doping of Ge2Sb2Te5 layer can be used to optimize the properties of the GST225 thin films, in particular to reduce the switching energy. So, it has the potential to improve the characteristics of reconfigurable multilevel nanophotonic devices using the GST225 thin films, including fully non-volatile memory and developed on-chip low power all-photonic circuits for post-von Neumann arithmetic processing
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Phase-change materials and chalcogenides · Photonic and Optical Devices · Advanced Optical Imaging Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (91)
Show source-provided references
1. Single-chip microprocessor that communicates directly using light10.1038/nature16454 ↗
2. Integrating photonics with silicon nanoelectronics for the next generation of systems on a chip10.1038/s41586-018-0028-z ↗
3. Overview of Blu-Ray DiscTM recordable/rewritable media technology10.1007/s12200-014-0413-7 ↗
4. 3D cross-point phase-change memory for storage-class memory10.1088/1361-6463/ab39a0 ↗
5. Consulting Agency “Reports and data”. Phase Change Memory Market By Form (Standalone, and Embedded), By Technology, and By Applications, 2016-2026 (Industry report: https://www.reportsanddata.com/report-detail/phase-change-memory-market). 2019, p. 143.
6. Wide bandgap phase change material tuned visible photonics10.1002/adfm.201806181 ↗
7. Active-tuning and polarization-independent absorber and sensor in the infrared region based on the phase change material of Ge2Sb2Te5 (GST)10.1038/s41598-018-30550-2 ↗
8. Thermal camouflage based on the phase-changing material GST10.1038/s41377-018-0038-5 ↗
9. Rewritable full-color computer-generated holograms based on color-selective diffractive optical components including phase-change materials10.1039/C8NR04471F ↗
10. Threshold switching and phase transition numerical models for phase change memory simulations10.1063/1.2931951 ↗
11. New structural picture of the Ge2Sb2Te5 phase-change alloy10.1103/PhysRevLett.106.025501 ↗
12. A review of germanium-antimony-telluride phase change materials for non-volatile memories and optical modulators10.3390/app9030530 ↗
13. Phase-change materials for non-volatile photonic applications10.1038/nphoton.2017.126 ↗
14. Structures of stable and metastable Ge2Sb2Te5, an intermetallic compound in GeTe–Sb2Te3 pseudobinary systems10.1107/S0108768104022906 ↗
15. Real-space imaging of atomic arrangement and vacancy layers ordering in laser crystallised Ge2Sb2Te5 phase change thin films10.1016/j.actamat.2015.12.010 ↗
16. Direct observation of amorphous to crystalline phase transitions in Ge–Sb–Te thin films by grazing incidence X-ray diffraction method
17. Resonant bonding in crystalline phase-change materials10.1038/nmat2226 ↗
18. Chalcogenides by design: functionality through metavalent10.1002/adma.201908302 ↗
19. Bonding origin of optical contrast in phase-change memory materials10.1103/PhysRevB.81.081204 ↗
20. Understanding the phase-change mechanism of rewritable optical media10.1038/nmat1215 ↗
21. Aging mechanisms in amorphous phase-change materials10.1038/ncomms8467 ↗
22. The interplay between Peierls distortions and metavalent bonding in IV–VI compounds: comparing GeTe with related monochalcogenides
23. Integrated all-photonic non-volatile multi-level memory10.1038/nphoton.2015.182 ↗
24. Tunable volatility of Ge2Sb2Te5 in integrated photonics10.1002/adfm.201807571 ↗
25. All-optical spiking neurosynaptic networks with self-learning capabilities10.1038/s41586-019-1157-8 ↗
26. Device level photonic memories and logic applications using phase-change materials
27. Optical switching at 1.55 µm in silicon racetrack resonators using phase change materials10.1063/1.4824714 ↗
28. Ultra-compact, self-holding asymmetric Mach-Zehnder interferometer switch using Ge2Sb2Te5 phase-change material
29. Toward fast neural computing using all-photonic phase change spiking neurons10.1038/s41598-018-31365-x ↗
30. Reducing the stochasticity of crystal nucleation to enable subnanosecond memory writing10.1126/science.aao3212 ↗
31. A new family of ultralow loss reversible phase-change materials for photonic integrated circuits: Sb2S3 and Sb2Se310.1002/adfm.202002447 ↗
32. Phase-change heterostructure enables ultralow noise and drift for memory operation10.1126/science.aay0291 ↗
33. In-situ transmission electron microscopy studies of the crystallization of N-doped Ge-rich GeSbTe materials10.1557/mrc.2018.168 ↗
34. Oxygen incorporation into GST phase-change memory matrix10.1016/j.apsusc.2015.01.203 ↗
35. Carbon ion implantation as healing strategy for improved reliability in phase-change memory arrays
36. Crystallization characteristics of Mg-doped Ge2Sb2Te5 films for phase change memory applications10.1016/j.apsusc.2012.09.181 ↗
37. Crystallization behavior of amorphous Alx(Ge2Sb2Te5)1−x thin films10.1063/1.3471799 ↗
38. Electronic structure and conductivity of off-stoichiometric and Si-doped Ge2Sb2Te5 crystals from multiple-scattering theory
39. Phase change behavior in titanium-doped Ge2Sb2Te5 films10.1063/1.3597617 ↗
40. Structural evolution and corresponding electrical properties of V-doped Ge2Sb2Te5 with increased temperature10.1016/j.matlet.2014.04.181 ↗
41. Cr-doped Ge2Sb2Te5 for ultra-long data retention phase change memory10.1063/1.4936847 ↗
42. Improving the performance of Ge2Sb2Te5 materials via nickel doping: towards RF-compatible phase-change devices10.1063/1.5053713 ↗
43. Study on the Cu-doped Ge2Sb2Te5 for low-power phase change memory10.1016/j.matlet.2014.03.180 ↗
44. Material design for Ge2Sb2Te5 phase-change material with thermal stability and lattice distortion10.1016/j.scriptamat.2019.05.024 ↗
45. Crystallization properties of arsenic doped GST alloys10.1038/s41598-019-49168-z ↗
46. Structural transition and enhanced phase transition properties of Se doped Ge2Sb2Te5 alloys10.1038/srep08050 ↗
47. Phase transition behaviors of Mo- and nitrogen-doped Ge2Sb2Te5 thin films investigated by in situ electrical measurements10.1063/1.3194787 ↗
48. Linear and non-linear optical properties of Ag-doped Ge2Sb2Te5 thin films estimated by single transmission spectra10.1088/1361-6641/aa5ee0 ↗
49. Effect of indium doping on Ge2Sb2Te5 thin films for phase-change optical storage10.1007/s00339-005-3232-2 ↗
50. Enhanced optical properties of Sn-doped Ge2Sb2Te5 thin film with structural evolution10.1016/j.jallcom.2018.08.169 ↗
51. Dependence of structural cross-linking, system energy and transition temperature on coordination number for Sm doped GST10.1016/j.rinp.2019.102276 ↗
52. Amorphous-to-crystalline transition in Ge8Sb(2-x)BixTe11 phase-change materials for data recording10.1016/j.jallcom.2016.03.019 ↗
53. Temperature and concentration dependent crystallization behavior of Ge2Sb2Te5 phase change films: tungsten doping effects10.1039/C4RA08790A ↗
54. Acceleration of crystallization speed by Sn addition to Ge–Sb–Te phase-change recording material10.1143/JJAP.40.5930 ↗
55. Influence of doping upon the phase change characteristics of Ge2Sb2Te510.1007/s00542-006-0156-5 ↗
56. Crystallization accompanied by local distortion behavior of Sn-doped amorphous Ge2Sb2Te5 induced by a picosecond pulsed laser10.1016/j.jnoncrysol.2019.04.004 ↗
57. Dean · 2004
58. Electrical percolation characteristics of Ge2Sb2Te5 and Sn doped Ge2Sb2Te5 thin films during the amorphous to crystalline phase transition
59. Electrical, optical, and thermal properties of Sn-doped phase change material Ge2Sb2Te510.1007/s10853-012-6745-z ↗
60. Phase transition characteristics and device performance of Sn-doped Ge2Sb2Te5 in phase change random access memory10.1143/JJAP.45.L1273 ↗
61. A study on the crystallization behavior of Sn-doped amorphous Ge2Sb2Te5 by ultraviolet laser radiation10.1016/j.apsusc.2014.08.007 ↗
62. Influence of partial substitution of Te by Se and Ge by Sn on the properties of the blu-ray phase-change material Ge8Sb2Te1110.1021/cm301809g ↗
63. Phase transition characteristics of Bi/Sn doped Ge2Sb2Te5 thin film for PRAM application10.1016/j.tsf.2006.10.045 ↗
64. Crystallization and thermal stability of Sn-doped Ge2Sb2Te5 phase change material10.1088/0022-3727/41/21/215402 ↗
65. Thermal phase change and activation energy of crystallization of Ge-Sb-Te-Sn thin films, Chin
66. Phase change behaviors of Sn-doped Ge–Sb–Te material10.1063/1.2475390 ↗
67. Material design for Ge2Sb2Te5 phase-change material with thermal stability and lattice distortion10.1016/j.scriptamat.2019.05.024 ↗
68. Enhanced optical properties of Sn-doped Ge2Sb2Te5 thin film with structural evolution10.1016/j.jallcom.2018.08.169 ↗
69. Characteristics of Sn-Doped Ge2Sb2Te5 films used for phase-change memory10.1088/0256-307X/22/11/056 ↗
70. Characterization of Ge ions implantation in Sb2Te3 thin films for high speed phase change memory application
71. S.M. Serena Privitera. Ion Implantation in Phase Change Ge2Sb2Te5 Thin Films For Non Volatile Memory Applications. Italy, 2012. https://doi.org/10.5772/35338.10.5772/35338 ↗
72. The vacuum arc ion source for indium and tin ions implantation into phase change memory thin films10.1063/1.5128561 ↗
73. Role of oxygen on chemical segregation in uncapped Ge2Sb2Te5 thin films on silicon nitride
74. Controlled switching of phase-change materials by evanescent-field coupling in integrated photonics10.1364/OME.8.002455 ↗
75. Integrated 256 cell photonic phase-change memory with 512-bit capacity10.1109/JSTQE.2019.2956871 ↗
76. On-chip photonic memory elements employing phase-change materials10.1002/adma.201304476 ↗
77. Amorphous and crystallized Ge–Sb–Te thin films deposited by pulsed laser: local structure using Raman scattering spectroscopy10.1016/j.matchemphys.2012.08.024 ↗
78. Optical constants acquisition and phase change properties of Ge2Sb2Te5 thin films based on spectroscopy10.1039/C8RA01382A ↗
79. Carbon doping induced Ge local structure change in as-deposited Ge2Sb2Te5 film by EXAFS and Raman spectrum
80. Pulsed laser deposited GeTe-rich GeTe-Sb2Te3 thin films10.1038/srep26552 ↗
81. Signature of tetrahedral ge in the raman spectrum of amorphous phase-change materials10.1103/PhysRevLett.104.085503 ↗
82. Nanoscale multilevel switching in Ge2Sb2Te5 thin film with conductive atomic force microscopy
83. One-step phase transition and thermal stability improvement of Ge2Sb2Te5 films by erbium-doping10.1016/j.vacuum.2017.09.008 ↗
84. The microstructural changes of Ge2Sb2Te5 thin film during crystallization process10.1063/1.5025204 ↗
85. Structural changes in doped Ge2Sb2Te5 thin films studied by Raman spectroscopy10.1016/j.phpro.2013.04.011 ↗
86. Raman spectra of cubic and amorphous GeSbTe from first principles10.1103/PhysRevB.83.134201 ↗
87. Direct evidence for phase transition in thin Ge1Sb4Te7 films using in situ UV–Vis–NIR spectroscopy and Raman scattering studies10.1002/pssb.201552803 ↗
88. Internal stress in polycrystalline Si film recrystallized by excimer laser annealing10.1143/JJAP.43.532 ↗
89. Raman scattering study of GeTe and Ge2Sb2Te5 phase-change materials10.1016/j.jpcs.2007.02.027 ↗
90. Modulation of phase change characteristics in Ag-incorporated Ge2Sb2Te5 owing to changes in structural distortion and bond strength10.1039/C6TC05412A ↗
91. Enhanced optical properties of Sn-doped Ge2Sb2Te5 thin film with structural evolution10.1016/j.jallcom.2018.08.169 ↗