journal article·2015-06

KOH etched graphite for fast chargeable lithium-ion batteries

Qian Cheng, Ryota Yuge, Kentaro Nakahara, Noriyuki Tamura, Shigeyuki Miyamoto

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Abstract

Abstract Graphite is the most widely used anode material for lithium ion (Li-ion) batteries, although it has limited power performance at high charging rates (Li-ion input). Alternative materials such as silicon and tin alloys, however, have an even more inferior rate capability. We describe here a multi-channel structure with a graphite surface etched with pores that can greatly increase the number of sites for Li-ion intercalation/de-intercalation and reduce the Li-ion diffusion distance for fast chargeable Li-ion batteries by etching the graphite surface with pores. As a result, the multi-channel structure graphite anode shows better charging and discharging rate capability, cyclability, and higher coulombic efficiency than pristine graphite materials. The multi-channel anode material is proposed for use in fast chargeable Li-ion batteries for electric vehicles and plug-in hybrid vehicles.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Technologies Research

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References (29)

Show source-provided references
1. Wu · J. Power Sources · 2003 · 114 · 22810.1016/S0378-7753(02)00596-7 ↗
2. De Las Casas · J. Power Sources · 2012 · 208 · 7410.1016/j.jpowsour.2012.02.013 ↗
3. Marom · J. Mater. Chem. · 2011 · 21 · 993810.1039/c0jm04225k ↗
4. Kucinskis · J. Power Sources · 2013 · 240 · 6610.1016/j.jpowsour.2013.03.160 ↗
5. Guoping · Solid State Ionics · 2005 · 176 · 90510.1016/j.ssi.2004.11.009 ↗
6. Placke · J. Power Sources · 2012 · 200 · 8310.1016/j.jpowsour.2011.10.085 ↗
7. Aurbach · Electrochim. Acta · 1999 · 45 · 6710.1016/S0013-4686(99)00194-2 ↗
8. Zheng · RSC Adv. · 2012 · 2 · 490410.1039/c2ra20536j ↗
9. Sun · Electrochim. Acta · 2007 · 52 · 431210.1016/j.electacta.2006.12.012 ↗
10. Sheem · Electrochim. Acta · 2012 · 78 · 22310.1016/j.electacta.2012.05.135 ↗
11. Buiel · Electrochim. Acta · 1999 · 45 · 12110.1016/S0013-4686(99)00198-X ↗
12. Azuma · J. Power Sources · 1999 · 81–82 · 110.1016/S0378-7753(99)00122-6 ↗
13. Flandrois · Carbon · 1999 · 37 · 16510.1016/S0008-6223(98)00290-5 ↗
14. Wang · J. Mater. Chem. · 2012 · 22 · 2371010.1039/c2jm34066f ↗
15. Marsh · Carbon · 1984 · 22 · 60310.1016/0008-6223(84)90096-4 ↗
16. Yang · Microporous Mesoporous Mater. · 2003 · 63 · 11310.1016/S1387-1811(03)00456-6 ↗
17. Lillo-Ródenas · J. Anal. Appl. Pyrolysis · 2007 · 80 · 16610.1016/j.jaap.2007.01.014 ↗
18. Qu · Energy Environ. Sci. · 2011 · 4 · 398510.1039/c0ee00673d ↗
19. Luo · Chem. Mater. · 2007 · 19 · 479110.1021/cm0714180 ↗
20. Li · J. Phys. Chem. B · 2005 · 109 · 1401710.1021/jp051900a ↗
21. Zhu · Sci. (New York, N. Y.) · 2011 · 332 · 153710.1126/science.1200770 ↗
22. Dickinson · Carbon · 1968 · 6 · 93710.1016/0008-6223(68)90077-8 ↗
23. Acik · J. Phys. Chem. C · 2011 · 115 · 1976110.1021/jp2052618 ↗
24. Huh · Eng. Technol. · 2010 · 73
25. Naebe · Sci. Rep. · 2014 · 4 · 437510.1038/srep04375 ↗
26. Gomez-Serrano · J. Anal. Appl. Pyrolysis · 1996 · 36 · 7110.1016/0165-2370(95)00921-3 ↗
27. Childres · New Dev. Phot. Mater. Res. · 2013 · 1
28. Reich · Philosophical Trans. Ser. A Math. Phys. Eng. Sci. · 2004 · 362 · 227110.1098/rsta.2004.1454 ↗
29. Ferrari · Nat. Nanotechnol. · 2013 · 8 · 23510.1038/nnano.2013.46 ↗