A short process for the efficient utilization of transition-metal chlorides in lithium-ion batteries: A case of Ni0.8Co0.1Mn0.1O1.1 and LiNi0.8Co0.1Mn0.1O2
Source abstract
Abstract
Abstract A short process for the efficient utilization of transition-metal chlorides in lithium-ion batteries (LIBs) is proposed. A uniformly dispersed tri-component nanocomposite of Ni 0.8 Co 0.1 Mn 0.1 O 1.1 microspheres with a porous structure has been prepared from the solution of transition-metal chlorides via spray pyrolysis. When evaluated as anode for LIBs, the Ni 0.8 Co 0.1 Mn 0.1 O 1.1 nanocomposite exhibits a reversible capacity of 1180 mAh g −1 after 120 cycles. More strikingly, the nanoparticles-assembled Ni 0.8 Co 0.1 Mn 0.1 O 1.1 precursor has its unique advantages in synthesizing well-ordered layered LiNi 0.8 Co 0.1 Mn 0.1 O 2 , owning to its excellent atomic uniformity, porous structure and Ni 3+ -rich surface. The as-prepared cathode material shows excellent structural stability. Discharge capacities of 173 mAh g −1 after 100 cycles at 1 C (1 C = 180 mA g -1 ) between 2.8 and 4.3 V are consistently obtained, corresponding to 95.6% capacity retention. These outstanding electrochemical results are obtained with minimal process optimization, indicating that spray pyrolysis is an efficient, robust synthesis technique for the production of Ni-rich layered cathode from solution of transition-metal chlorides.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
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