Stainless steel bipolar plates for proton exchange membrane fuel cells: Materials, flow channel design and forming processes
Source abstract
Abstract
Abstract Bipolar plate (BPP) is a key component for proton exchange membrane fuel cell (PEMFC) stack. Stainless steel BPPs possess high electrical and thermal conductivity, good gas impermeability, superior mechanical properties and formability. Furthermore, stainless steel BPPs as thin as 0.1 mm or even thinner can be manufactured by plastic forming methods in mass production with relatively lower cost for PEMFCs, especially for the application of automotive. However, relatively lower corrosion resistance and higher interfacial contact resistance (ICR) may be the two main obstacles hindering full commercialization of stainless steel BPPs. In addition, formability needs to be further improved for higher performance BPPs with fine flow channel geometries while its cost should be reduced to meet the 2020 targets set by the U.S. Department of Energy (DOE). This paper tries to present a comprehensive review of major findings of researches on base and coating materials, channel structure design and forming processes of stainless steel BPPs in recent years. The optimum materials, channel geometries and manufacturing processes currently used or investigated are summarized. In the meanwhile, challenges and future research trends on materials and forming processes of stainless steel BBPs are proposed.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Fuel Cells and Related Materials · Electrocatalysts for Energy Conversion · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Formation of 3D graphene–Ni foam heterostructures with enhanced performance and durability for bipolar plates in a polymer electrolyte membrane fuel cell10.1039/C7TA07598G ↗
2. Molybdenum carbide coated 316L stainless steel for bipolar plates of proton exchange membrane fuel cells10.1016/j.ijhydene.2018.12.184 ↗
3. Effect of manufacturing processes on contact resistance characteristics of metallic bipolar plates in PEM fuel cells10.1016/j.ijhydene.2011.06.091 ↗
4. A review of polymer electrolyte membrane fuel cell stack testing10.1016/j.jpowsour.2010.07.072 ↗
5. The durability investigation of a 10‐cell metal bipolar plate proton exchange membrane fuel cell stack10.1002/er.4283 ↗
6. Corrosion of metal bipolar plates for PEM fuel cells: a review10.1016/j.ijhydene.2010.01.059 ↗
7. Direct hydrogen fuel cell electric vehicle cost analysis: system and high-volume manufacturing description, validation, and outlook10.1016/j.jpowsour.2018.07.100 ↗
8. Techno-economic challenges of fuel cell commercialization10.1016/j.eng.2018.05.007 ↗
9. Fabrication of metallic bipolar plate for proton exchange membrane fuel cells by using polymer powder medium based flexible forming10.1016/j.jmatprotec.2018.06.014 ↗
10. Manufacturing metallic bipolar plate fuel cells through rubber pad forming process
11. Metallic bipolar plate fabrication process of fuel cell by rubber pad forming and its performance evaluation10.4028/www.scientific.net/KEM.535-536.310 ↗
12. Fabrication of metallic bipolar plate for proton exchange membrane fuel cells by rubber pad forming10.1016/j.jpowsour.2009.12.046 ↗
13. Surface conductivity and stability of metallic bipolar plate materials for polymer electrolyte fuel cells10.1016/j.electacta.2005.10.015 ↗
14. Corrosion behavior of TiN coated type 316 stainless steel in simulated PEMFC environments10.1016/S0010-938X(03)00187-2 ↗
15. (Metal) bipolar plate testing
16. bipolar plate materials for proton exchange membrane fuel cell application10.2174/1874464808666150306223104 ↗
17. Bipolar plates for PEM fuel cells: a review10.1016/j.ijhydene.2005.04.016 ↗
18. Proton exchange membrane fuel cell from low temperature to high temperature: material challenges10.1016/j.jpowsour.2007.02.065 ↗
19. Review of materials and processing methods used in the production of bipolar plates for fuel cells10.1179/174328006X102556 ↗
20. Recent advances in materials for fuel cells10.1146/annurev.matsci.33.022802.094122 ↗
21. Review of the membrane and bipolar plates materials for conventional and unitized regenerative fuel cells10.1016/j.rser.2008.09.029 ↗
22. A review of thermoplastic composites for bipolar plate materials in PEM fuel cells
23. A review of metal separator plate materials suitable for automotive PEMfuel cells10.1039/B813231N ↗
24. Reviewing Metallic PEMFC bipolar plates10.1002/fuce.200900187 ↗
25. Review of materials and characterization methods for polymer electrolyte fuel cell flow-field plates10.1115/1.2393303 ↗
26. Characteristics of composite bipolar plates for polymer electrolyte membrane fuel cells10.1016/j.jpowsour.2003.08.039 ↗
27. Effect of carbon fillers on properties of polymer composite bipolar plates of fuel cells10.1016/j.jpowsour.2009.04.029 ↗
28. Electrically conductive nanocomposites of aromatic polydisulfide/expanded graphite10.1016/j.compscitech.2005.12.013 ↗
29. Effect of bipolar plate materials on performance of fuel cells
30. Carbon materials in composite bipolar plates for polymer electrolyte membrane fuel cells: a review of the main challenges to improve electrical performance10.1016/j.jpowsour.2010.12.041 ↗
31. Effect of different carbon fillers on the properties of graphite composite bipolar plate10.1016/j.jmatprotec.2007.10.044 ↗
32. Metal bipolar plates for PEM fuel cell—a review10.1016/j.jpowsour.2006.09.088 ↗
33. A review of composite and metallic bipolar plates in proton exchange membrane fuel cell: materials, fabrication, and material selection10.1016/j.jpowsour.2014.04.081 ↗
34. A review of metallic bipolar plates for proton exchange membrane fuel cells: materials and fabrication methods10.1155/2012/828070 ↗
35. Development of the fuel cell vehicle mirai10.1002/tee.22328 ↗
36. T. Ohtani, M. Tsuji, M. Utsunomiya.Metal separator for fuel cell and production method therefor [P].U.S. Patent 7,049,022. 2006-5-23.
37. K. Jonghee, K. Jo, Y. Kim, et alStainless Steel for Polymer Fuel Cell Separator and Method for Preparing Same [P].U.S. Patent 9290845. 2016-3-22.
38. S. Ide, A. Honda, S. Ishikawa, et alStainless steel having good conductivity and ductility for use in fuel cell and method for producing the same [P].U.S. Patent 8,440,029. 2013-5-14.
39. N. Yamano, T. Kawamura, S. Goto, et alFuel cell [P].U.S. Patent Application 10/186,718. 2019-1-22.
40. I. W. Lyo, J. U. An, S. G. Ahn, et alMetallic Bipolar Plate for Fuel Cell and Method for Forming Surface Layer of the Same [P].U.S. Patent 7914948B2. 2011-3-29.
41. Y. M. Nam, Y. C. Yang, S. M. Baeck, et alMetal separator for fuel cell and surface treatment method thereof [P].U.S. Patent 8,636,947. 2014-1-28.
42. K. I. Han.Fuel cell stack with improved corrosion resistance [P].U.S. Patent 9,172,098. 2015-10-27.
43. M. K. Budinski, G. Vyas, A. O. K. Neto, et al Nitrided bipolar plates [P].U.S. Patent 7,687,177. 2010-3-30.
44. D. R. Sigler, Y.-L. Chen, X. Gayden.Bipolar plate fabrication [P].U.S. Patent 7,258,263. 2007-8-21.
45. Stainless steel as a bipolar plate material for solid polymer fuel cells10.1016/S0378-7753(99)00524-8 ↗
46. Stainless steel as bipolar plate material for polymer electrolyte membrane fuel cells10.1016/S0378-7753(03)00023-5 ↗
47. Manufacturing and performance assessment of stamped, laser welded, and nitrided FeCrV stainless steel bipolar plates for proton exchange membrane fuel cells10.1016/j.ijhydene.2013.01.143 ↗
48. Evaluation of materials for bipolar plates in PEMFCs
49. Materials for bipolar plates in polymer electrolyte membrane fuel cell: performance criteria and current benchmarks10.1016/j.promfg.2016.12.011 ↗
50. Design and manufacturing of stainless steel bipolar plates for proton exchange membrane fuel cells10.1016/j.ijhydene.2014.08.113 ↗
51. Review on current research of materials, fabrication and application for bipolar plate in proton exchange membrane fuel cell
52. Manufacturing methods for metallic bipolar plates for polymer electrolyte membrane fuel cell10.1080/10426914.2019.1605170 ↗
53. Meeting cost and manufacturing expectations for automotive fuel cell bipolar plates10.1149/08301.0093ecst ↗
54. Ashby · 2010
55. Materials selection for bipolar plates for polymer electrolyte membrane fuel cells using the Ashby approach10.1016/j.jpowsour.2012.01.104 ↗
56. Astm · 2016
57. Richardson · 2009
58. Influence of Ti, C and N concentration on the intergranular corrosion behaviour of AISI 316Ti and 321 stainless steels10.1016/j.actamat.2006.11.021 ↗
59. Resistance to intergranular corrosion of ferritic and martensitic stainless chromium steels
60. Role of carbon and nitrogen on the toughness and intergranular corrosion of ferritic stainless steel
61. Formability of stainless steel10.1007/s11661-998-0041-1 ↗
62. Pre-oxidized and nitrided stainless steel alloy foil for proton exchange membrane fuel cell bipolar plates. Part 2: single-cell fuel cell evaluation of stamped plates10.1016/j.jpowsour.2010.03.056 ↗
63. Pre-oxidized and nitrided stainless steel alloy foil for proton exchange membrane fuel cell bipolar plates: Part 1. Corrosion, interfacial contact resistance, and surface structure10.1016/j.jpowsour.2010.03.055 ↗
64. Ishii · 2017
65. Tarutani · 2018
66. Tarutani · 2017
67. Corrosion behaviors and contact resistances of the low-carbon steel bipolar plate with a chromized coating containing carbides and nitrides10.1016/j.ijhydene.2009.05.103 ↗
68. Evaluation of Ni-Cr-P coatings electrodeposited on low carbon steel bipolar plates for polymer electrolyte membrane fuel cell10.1016/j.ijhydene.2018.10.218 ↗
69. Anodic behavior of high nitrogen-bearing steels in PEMFC environments10.1016/j.jpowsour.2008.02.085 ↗
70. Bipolar plate materials for PEMFCs: a conductivity and stability study10.1016/j.jpowsour.2008.01.038 ↗
71. Effects of metal buffer layer for amorphous carbon film of 304 stainless steel bipolar plate10.1016/j.tsf.2016.07.043 ↗
72. Effect of plasma nitriding on behavior of austenitic stainless steel 304L bipolar plate in proton exchange membrane fuel cell10.1016/j.jpowsour.2006.09.053 ↗
73. Nanoparticle TiN-coated type 310S stainless steel as bipolar plates for polymer electrolyte membrane fuel cell10.1016/j.elecom.2008.01.001 ↗
74. Corrosion resistant low temperature carburized SS 316 as bipolar plate material for PEMFC application10.1016/j.electacta.2007.10.061 ↗
75. Silver implanted 316L stainless steel as bipolar plates in polymer electrolyte membrane fuel cells10.1016/j.matchemphys.2010.11.029 ↗
76. Carbon coated stainless steel bipolar plates in polymer electrolyte membrane fuel cells10.1016/j.diamond.2010.07.003 ↗
77. Conductive amorphous carbon-coated 316L stainless steel as bipolar plates in polymer electrolyte membrane fuel cells10.1016/j.ijhydene.2009.06.030 ↗
78. An investigation into nickel implanted 316L stainless steel as a bipolar plate for PEM fuel cell10.1016/j.jpowsour.2008.03.088 ↗
79. Preparation and performance of nanometric Ti/TiN multi-layer physical vapor deposited coating on 316L stainless steel as bipolar plate for proton exchange membrane fuel cells
80. Corrosion resistant quaternary Al–Cr–Mo–N coating on type 316L stainless steel bipolar plates for proton exchange membrane fuel cells10.1016/j.ijhydene.2019.11.119 ↗
81. Electrochemical properties of tungsten-alloying-modified AISI 430 stainless steel as bipolar plates for PEMFCs used in marine environment10.1007/s40195-016-0464-4 ↗
82. Ferritic stainless steels as bipolar plate material for polymer electrolyte membrane fuel cells10.1016/j.jpowsour.2003.09.075 ↗
83. Process modification for coating SnO2:F on stainless steels for PEM fuel cell bipolar plates10.1016/j.jpowsour.2007.12.010 ↗
84. Effects of low-temperature nitridation on the electrical conductivity and corrosion resistance of 446M stainless steel as bipolar plates for proton exchange membrane fuel cell10.1016/j.ijhydene.2009.10.107 ↗
85. Design and testing criteria for bipolar plate materials for PEM fuel cell applications
86. Metallic bipolar plates for PEM fuel cells10.1016/S0378-7753(01)00950-8 ↗
87. Review and analysis of PEM fuel cell design and manufacturing10.1016/S0378-7753(02)00542-6 ↗
88. Testing and evaluation of aluminum coated bipolar plates of pem fuel cells operating at 70°C10.1016/j.jpowsour.2006.09.013 ↗
89. Coating of stainless steel and titanium bipolar plates for anticorrosion in PEMFC: a review10.1016/j.ijhydene.2016.06.241 ↗
90. Ex situ evaluation of nanometer range gold coating on stainless steel substrate for automotive polymer electrolyte membrane fuel cell bipolar plate10.1016/j.jpowsour.2009.09.022 ↗
91. Chromium nitride films on stainless steel as bipolar plate for proton exchange membrane fuel cell10.1016/j.jpowsour.2009.06.029 ↗
92. Coated 316L stainless steel with CrxN film as bipolar plate for PEMFC prepared by pulsed bias arc ion plating10.1016/j.jpowsour.2007.10.038 ↗
93. Corrosion and interfacial contact resistance of 316L stainless steel coated with magnetron sputtered ZrN and TiN in the simulated cathodic environment of a proton-exchange membrane fuel cell10.1016/j.surfcoat.2019.02.027 ↗
94. Carbon-based films coated 316L stainless steel as bipolar plate for proton exchange membrane fuel cells10.1016/j.ijhydene.2008.10.068 ↗
95. Chromium-containing carbon film on stainless steel as bipolar plates for proton exchange membrane fuel cells10.1016/j.ijhydene.2010.09.036 ↗
96. Niobium doped amorphous carbon film on metallic bipolar plates for PEMFCs: first principle calculation, microstructure and performance10.1016/j.ijhydene.2018.12.040 ↗
97. C/CrN multilayer coating for polymer electrolyte membrane fuel cell metallic bipolar plates10.1016/j.jpowsour.2012.08.087 ↗
98. Investigation of C/Al–Cr–N multilayer coatings for stainless steel bipolar plate in polymer electrolyte membrane fuel cells10.1016/j.surfcoat.2014.07.028 ↗
99. Corrosion and electrical properties of carbon/ceramic multilayer coated on stainless steel bipolar plates10.1016/j.surfcoat.2016.03.072 ↗
100. Characteristics of amorphous carbon films to resist high potential impact in PEMFCs bipolar plates for automotive application10.1016/j.ijhydene.2017.04.113 ↗