On the use of electrochemical impedance spectroscopy to characterize and model the aging phenomena of lithium-ion batteries: a critical review
Source abstract
Abstract
Electrochemical Impedance Spectroscopy (EIS) is a powerful non-invasive technique used to characterize Lithium-ion cells. Its application allows to identify and track the evolutions of cell degradation processes within a short testing time. This review collects all the available works which have used EIS spectra either to characterize Li-ion cell degradation or to develop Electric Circuit Models (ECMs). The objectives of this work are: (i) to highlight the influence of different aging test conditions on the EIS spectra; (ii) to find the correlations between EIS spectra variations and the underlying degradation mechanisms and (iii) to list the available options to formulate ECMs from EIS spectra of aged cells. After an exhaustive analysis of the state-of-the-art, a critical review is presented to discuss the existing links between degradation mechanisms and the most reliable solutions to model them.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Battery Technologies Research · Advancements in Battery Materials · Advanced Battery Materials and Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (92)
Show source-provided references
1. European Commission
2. Degradation mechanisms in Li-ion batteries: a state-of-the-art review: degradation mechanisms in Li-ion batteries: a state-of-the-art review10.1002/er.3762 ↗
3. A review of the state of health for lithium-ion batteries: research status and suggestions10.1016/j.jclepro.2020.120813 ↗
4. Electro-thermal battery model identification for automotive applications10.1016/j.jpowsour.2010.06.037 ↗
5. Critical review of state of health estimation methods of Li-ion batteries for real applications10.1016/j.rser.2015.11.042 ↗
6. Weicker · 2013
7. Battery state of health estimation: a structured review of models, methods and commercial devices: battery State of Health Estimation: a Structured Review10.1002/er.3598 ↗
8. Studies on the degradation of Li-ion batteries by the use of microreference electrodes10.1016/j.jpowsour.2007.11.032 ↗
9. ‘Understanding long-term cycling performance of Li1.2Ni0.15Mn0.55Co0.1O2–graphite lithium-ion cells’10.1149/2.002305jes ↗
10. Study of the storage performance of a Li-ion cell at elevated temperature10.1016/j.electacta.2009.09.077 ↗
11. ‘Electrochemical characterization and post-mortem analysis of aged LiMn2O4–Li(Ni0.5Mn0.3Co0.2)O2/graphite lithium ion batteries. Part I: cycle aging’10.1016/j.jpowsour.2013.11.080 ↗
12. Degradation mechanisms of high capacity 18650 cells containing Si-graphite anode and nickel-rich NMC cathode10.1016/j.electacta.2018.11.194 ↗
13. Electrochemical investigations on advanced lithium-ion batteries by three-electrode measurements10.1149/1.1825385 ↗
14. Aging analysis of graphite/LiNi1/3Mn1/3Co1/3O2 cells using XRD, PGAA, and AC impedance10.1149/2.0721514jes ↗
15. ‘Studies on the cycle life of commercial lithium ion batteries during rapid charge–discharge cycling’10.1016/S0378-7753(01)00821-7 ↗
16. Understanding lithium inventory loss and sudden performance fade in cylindrical cells during cycling with deep-discharge steps10.1021/jp510071d ↗
17. The influence of high C rate pulsed discharge on lithium-ion battery cell degradation
18. Postmortem analysis of calendar-aged graphite/LiFePO4 cells10.1016/j.jpowsour.2013.01.147 ↗
19. Cycle aging of commercial NMC/graphite pouch cells at different temperatures10.1016/j.apenergy.2015.04.110 ↗
20. Cycle-life characterization of automotive lithium-ion batteries with LiNiO2 cathode10.1149/1.3126385 ↗
21. Cycle aging studies of lithium nickel manganese cobalt oxide-based batteries using electrochemical impedance spectroscopy10.1016/j.electacta.2018.04.045 ↗
22. Degradation mechanism and life prediction of lithium-ion batteries10.1149/1.2162467 ↗
23. Effects of dissolved transition metals on the electrochemical performance and SEI growth in lithium-ion batteries10.1149/2.0861412jes ↗
24. A novel quantitative electrochemical aging model considering side reactions for lithium-ion batteries10.1016/j.electacta.2020.136070 ↗
25. Aging characteristics of high-power lithium-ion cells with LiNi0.8Co0.15Al0.05O2 and Li4/3Ti5/3O4 electrodes10.1016/j.electacta.2005.05.008 ↗
26. Capacity fade study of lithium-ion batteries cycled at high discharge rates10.1016/S0378-7753(03)00029-6 ↗
27. Studies on capacity fade of lithium-ion batteries10.1016/S0378-7753(00)00469-9 ↗
28. Critical review of non-invasive diagnosis techniques for quantification of degradation modes in lithium-ion batteries10.1016/j.rser.2019.03.060 ↗
29. Critical review of the methods for monitoring of lithium-ion batteries in electric and hybrid vehicles10.1016/j.jpowsour.2014.02.064 ↗
30. Lasia · 2014
31. Ageing mechanisms in lithium-ion batteries10.1016/j.jpowsour.2005.01.006 ↗
32. A comparison between electrochemical impedance spectroscopy and incremental capacity-differential voltage as Li-ion diagnostic techniques to identify and quantify the effects of degradation modes within battery management systems10.1016/j.jpowsour.2017.03.042 ↗
33. Modeling and applications of electrochemical impedance spectroscopy (EIS) for lithium-ion batteries10.33961/jecst.2019.00528 ↗
34. Increasing the cycle life of lithium ion cells by partial state of charge cycling10.1016/j.microrel.2015.08.014 ↗
35. Influence of capacity fading on commercial lithium-ion battery impedance10.1016/S0378-7753(03)00233-7 ↗
36. Characterizing aging effects of lithium ion batteries by impedance spectroscopy
37. PSOC cycle testing method for lithium-ion secondary batteries10.1016/S0378-7753(03)00157-5 ↗
38. ‘Electrochemical impedance analysis on degradation of commercially available lithium ion battery during charge–discharge cycling’10.1246/cl.2012.444 ↗
39. SOH estimation of lithium-ion batteries based on fast time domain impedance spectroscopy
40. A novel mechanistic modeling framework for analysis of electrode balancing and degradation modes in commercial lithium-ion cells10.1016/j.jpowsour.2017.01.026 ↗
41. ‘Lithium plating in a commercial lithium-ion battery – a low-temperature aging study’10.1016/j.jpowsour.2014.11.065 ↗
42. Cycling degradation of an automotive LiFePO4 lithium-ion battery10.1016/j.jpowsour.2010.08.070 ↗
43. Lithium-ion batteries: evaluation study of different charging methodologies based on aging process10.1016/j.apenergy.2015.02.064 ↗
44. Lithium-ion battery power degradation modelling by electrochemical impedance spectroscopy10.1049/iet-rpg.2016.0958 ↗
45. Aging in lithium-ion batteries: model and experimental investigation of harvested LiFePO4 and mesocarbon microbead graphite electrodes10.1016/j.electacta.2013.05.081 ↗
46. Estimation of state of health of lithium-ion batteries based on charge transfer resistance considering different temperature and state of charge10.1016/j.est.2018.11.020 ↗
47. Electrochemical cycle-life characterization of high energy lithium-ion cells with thick Li(Ni0.6Mn0.2Co0.2)O2 and graphite electrodes10.1149/2.0451706jes ↗
48. Nonlinear aging characteristics of lithium-ion cells under different operational conditions10.1016/j.est.2015.05.003 ↗
49. Impedance characterization of lithium-ion batteries aging under high-temperature cycling: importance of electrolyte-phase diffusion10.1016/j.jpowsour.2019.04.040 ↗
50. Analysis of lithium-ion battery models based on electrochemical impedance spectroscopy10.1002/ente.201600154 ↗
51. State-of-health estimation of lithium-ion battery based on fractional impedance model and interval capacity10.1016/j.ijepes.2020.105883 ↗
52. Electrochemical impedance spectroscopic analysis of lithium-ion battery aging mechanisms10.1149/MA2013-01/4/254 ↗
53. Electrode behavior RE-visited: monitoring potential windows, capacity loss, and impedance changes in Li1.03(Ni0.5Co0.2Mn0.3)0.97O2/silicon-graphite full cells10.1149/2.0271606jes ↗
54. On the interpretation of impedance spectra of large-format lithium-ion batteries and its application in aging studies10.1002/ente.201900279 ↗
55. Impedance spectroscopic investigation of the impact of erroneous cell assembly on the aging of lithium-ion batteries10.1002/ente.201900288 ↗
56. A systematic model-based degradation behavior recognition and health monitoring method for lithium-ion batteries10.1016/j.apenergy.2017.05.124 ↗
57. ‘Electrochemical characterization and post-mortem analysis of aged LiMn2O4–NMC/graphite lithium ion batteries part II: calendar aging’10.1016/j.jpowsour.2014.02.019 ↗
58. Impedance change and capacity fade of lithium nickel manganese cobalt oxide-based batteries during calendar aging10.1016/j.jpowsour.2017.03.090 ↗
59. ‘Non-invasive yet separate investigation of anode/cathode degradation of lithium-ion batteries (nickel–cobalt–manganese vs. graphite) due to accelerated aging’10.1016/j.jpowsour.2019.227369 ↗
60. Development of a lifetime prediction model for lithium-ion batteries based on extended accelerated aging test data10.1016/j.jpowsour.2012.05.012 ↗
61. Experimental investigation of the lithium-ion battery impedance characteristic at various conditions and aging states and its influence on the application10.1016/j.apenergy.2012.09.030 ↗
62. Non-invasive investigation of predominant processes in the impedance spectra of high energy lithium-ion batteries with Nickel-Cobalt-Aluminum cathodes10.1016/j.jpowsour.2018.10.024 ↗
63. Impact of high rate discharge on the aging of lithium nickel cobalt aluminum oxide batteries10.1016/j.jpowsour.2015.01.110 ↗
64. Accelerated calendar and pulse life analysis of lithium-ion cells10.1016/S0378-7753(03)00193-9 ↗
65. Quantitative analysis of degradation modes of lithium-ion battery under different operating conditions10.3390/en14020350 ↗
66. Performance analysis and SOH (state of health) evaluation of lithium polymer batteries through electrochemical impedance spectroscopy10.1016/j.energy.2015.05.148 ↗
67. H. Popp, M. Einhorn, and F. V. Conte, ‘Capacity Decrease vs. Impedance Increase of Lithium Batteries. A comparative study.’, p. 6.
68. 30 Years of lithium-ion batteries10.1002/adma.201800561 ↗
69. J. Illig, ‘Physically Based Impedance Modelling of Lithium-Ion Cells’, p. 231.
70. Ageing monitoring of lithium-ion cell during power cycling tests10.1016/j.microrel.2011.07.013 ↗
71. Parameterization of linear equivalent circuit models over wide temperature and SOC spans for automotive lithium-ion cells using electrochemical impedance spectroscopy10.1016/j.est.2017.08.004 ↗
72. A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries10.1016/j.electacta.2010.05.072 ↗
73. Lithium ion battery anode aging mechanisms10.3390/ma6041310 ↗
74. Battery aging and its influence on the electromotive force10.1149/1.2742296 ↗
75. Synthesize battery degradation modes via a diagnostic and prognostic model10.1016/j.jpowsour.2012.07.016 ↗
76. Degradation diagnostics for lithium ion cells10.1016/j.jpowsour.2016.12.011 ↗
77. Evaluation of electrochemical impedance spectra by the distribution of relaxation times10.2109/jcersj2.16267 ↗
78. Two- and three-electrode impedance studies on 18650 Li-ion cells10.1016/S0378-7753(99)00469-3 ↗
79. Note on the parameterization of the constant-phase admittance element10.1016/0167-2738(84)90049-3 ↗
80. On the physical interpretation of constant phase elements10.1016/j.ssi.2009.04.002 ↗
81. New aspects of some small-signal ac frequency response functions10.1016/0167-2738(85)90095-5 ↗
82. ‘Solid polymer electrolytes based on polyethylene oxide and lithium trifluoro- methane sulfonate (PEO–LiCF3SO3): ionic conductivity and dielectric relaxation’10.1016/j.ssi.2008.04.034 ↗
83. Barsoukov · 2005
84. Diffusion impedance in planar, cylindrical and spherical symmetry10.1016/0013-4686(94)E0192-3 ↗
85. Theory of the impedance of electron diffusion and recombination in a thin layer10.1021/jp011941g ↗
86. An AC impedance spectroscopic study of LixCoO2 at different temperatures10.1021/jp013569a ↗
87. Distribution of relaxation times as a method of separation and identification of complex processes measured by impedance spectroscopy
88. Evaluation of lithium-ion battery equivalent circuit models for state of charge estimation by an experimental approach10.3390/en4040582 ↗
89. D.-W. H. Witzenhausen, ‘Elektrische Batteriespeichermodelle: Modellbildung, Parameteridentifikation und Modellreduktion’, p. 276.
90. Characterization of high-power lithium-ion batteries by electrochemical impedance spectroscopy. II: Modelling10.1016/j.jpowsour.2010.07.071 ↗
91. Equivalent circuit model parameters of a high-power Li-ion battery: thermal and state of charge effects10.1016/j.jpowsour.2010.12.107 ↗
92. Lithium-ion battery aging mechanisms and life model under different charging stresses10.1016/j.jpowsour.2017.04.084 ↗