The shape-retention and heat-tolerant elastic helix based on azobenzene-polyimide supramolecular assembly

Helical structures are ubiquitous in natural and engineered systems across multiple length scales, while they often exhibit nearly uniform radius and pitch. Utilization of biomimetic structure design to develop stretchable and robust 3D helical structures that are shape-preserving and heat-tolerant is of great interest. Herein, we devise flexible 3D helixes by supramolecular self-assembly and high voltage electric field orientation of molecular chains. The 3D helixes not only inherit buffering mechanics with exceptional shape-retention ability against cyclic stretching but also exhibit excellent heat-resistant quality. The results of the experimental tests confirm that the helix can recover its original shape without obvious residual strain and basically withstand after 2000 cycles under force loading of 10 cN. Such robust biomimetic materials hold great prospects in the fields of artificial muscles, wearable materials, and so on.