journal article·2018-04Open access

All-solid-state lithium-ion and lithium metal batteries – paving the way to large-scale production

Joscha Schnell, Till Günther, Thomas Knoche, Christoph Vieider, Larissa Köhler, Alexander Just, Marlou Keller, Stefano Passerini, Gunther Reinhart

Abstract

Abstract Challenges and requirements for the large-scale production of all-solid-state lithium-ion and lithium metal batteries are herein evaluated via workshops with experts from renowned research institutes, material suppliers, and automotive manufacturers. Aiming to bridge the gap between materials research and industrial mass production, possible solutions for the production chains of sulfide and oxide based all-solid-state batteries from electrode fabrication to cell assembly and quality control are presented. Based on these findings, a detailed comparison of the production processes for a sulfide based all-solid-state battery with conventional lithium-ion cell production is given, showing that processes for composite electrode fabrication can be adapted with some effort, while the fabrication of the solid electrolyte separator layer and the integration of a lithium metal anode will require completely new processes. This work identifies the major steps towards mass production of all-solid-state batteries, giving insight into promising manufacturing technologies and helping stakeholders, such as machine engineering, cell producers, and original equipment manufacturers, to plan the next steps towards safer batteries with increased storage capacity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. The manufacturing of electrodes. Key process for the future success of lithium-ion batteries
2. Flammability of Li-Ion battery electrolytes. Flash point and self-extinguishing time measurements10.1149/2.0121502jes ↗
3. A failure modes, mechanisms, and effects analysis (FMMEA) of lithium-ion batteries10.1016/j.jpowsour.2015.07.100 ↗
4. In situ visualization of the electrolyte solvent filling process by neutron radiography10.1016/j.jpowsour.2016.09.037 ↗
5. Prospects for reducing the processing cost of lithium ion batteries10.1016/j.jpowsour.2014.11.019 ↗
6. Challenges and prospects of the role of solid electrolytes in the revitalization of lithium metal batteries10.1039/C6TA07384K ↗
7. A solid future for battery development10.1038/nenergy.2016.141 ↗
8. All-solid-state Li/S batteries with highly conductive glass–ceramic electrolytes10.1016/S1388-2481(03)00167-X ↗
9. 5 V class all-solid-state composite lithium battery with Li3PO4 coated LiNi0.5Mn1.5O410.1149/1.1619988 ↗
10. Solid electrolyte. The key for high-voltage lithium batteries10.1002/aenm.201401408 ↗
11. Kariatsumari · 2010
12. Ceramic and polymeric solid electrolytes for lithium-ion batteries10.1016/j.jpowsour.2010.01.076 ↗
13. Batteries. Getting solid10.1038/nenergy.2016.42 ↗
14. Grape · 2015
15. Fabrications and properties of composite solid-state electrolytes10.1016/S0167-2738(02)00889-5 ↗
16. A rocking chair type all-solid-state lithium ion battery adopting Li2O–ZrO2 coated LiNi0.8Co0.15Al0.05O2 and a sulfide based electrolyte10.1016/j.jpowsour.2013.10.005 ↗
17. All-solid-state lithium ion battery using garnet-type oxide and Li3BO3 solid electrolytes fabricated by screen-printing10.1016/j.jpowsour.2013.02.073 ↗
18. Bendable and thin sulfide solid electrolyte film: a new electrolyte opportunity for free-standing and stackable high-energy all-solid-state lithium-ion batteries10.1021/acs.nanolett.5b00538 ↗
19. Life Cycle Assessment and resource analysis of all-solid-state batteries10.1016/j.apenergy.2016.02.064 ↗
20. Review—practical challenges hindering the development of solid state Li ion batteries10.1149/2.1571707jes ↗
21. Rapidly falling costs of battery packs for electric vehicles10.1038/nclimate2564 ↗
22. Quality management for battery production. A quality gate concept10.1016/j.procir.2016.11.098 ↗
23. Evaluation of technology chains for the production of all-solid-state batteries
24. Future generations of cathode materials: an automotive industry perspective10.1039/C5TA00361J ↗
25. Lithium ion, lithium metal, and alternative rechargeable battery technologies. The odyssey for high energy density10.1007/s10008-017-3610-7 ↗
26. In situ SEM study of a lithium deposition and dissolution mechanism in a bulk-type solid-state cell with a Li2S-P2S5 solid electrolyte10.1039/c3cp51059j ↗
27. Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte10.1016/j.elecom.2015.05.001 ↗
28. Key parameters governing the densification of cubic-Li7La3Zr2O12 Li + conductors10.1016/j.jpowsour.2017.03.126 ↗
29. Materials and manufacturing technologies for solid oxide fuel cells10.1007/s10853-010-4279-9 ↗
30. Wachsman · 2014
31. Challenges for rechargeable Li batteries10.1021/cm901452z ↗
32. Oxide electrolytes for lithium batteries10.1111/jace.13844 ↗
33. www.bluecar.fr. Available at: http://www.bluecar.fr/les-batteries-lmp-lithium-metal-polymere (2014) (accessed 14 December 2017).
34. Review on composite polymer electrolytes for lithium batteries10.1016/j.polymer.2006.05.069 ↗
35. All solid-state polymer electrolytes for high-performance lithium ion batteries10.1016/j.ensm.2016.07.003 ↗
36. A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries10.1039/C3EE41655K ↗
37. High-power all-solid-state batteries using sulfide superionic conductors10.1038/nenergy.2016.30 ↗
38. Ionic conductivity of solid electrolytes based on lithium titanium phosphate10.1149/1.2086597 ↗
39. Garnet-type solid-state fast Li ion conductors for Li batteries: critical review10.1039/c4cs00020j ↗
40. Fast lithium ion conduction in garnet-type Li7La3Zr2O1210.1002/anie.200701144 ↗
41. Optimizing Li+ conductivity in a garnet framework10.1039/c2jm31413d ↗
42. Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries10.1073/pnas.1600422113 ↗
43. A lithium superionic conductor10.1038/nmat3066 ↗
44. A novel sol-gel method for large-scale production of nanopowders. Preparation of Li1.5Al0.5Ti1.5(PO4)3 as an example10.1111/jace.13997 ↗
45. Structural change of Li2S–P2S5 sulfide solid electrolytes in the atmosphere10.1016/j.ssi.2010.10.013 ↗
46. Li7La3Zr2O12 electrolyte stability in air and fabrication of a Li/Li7La3Zr2O12/Cu0.1V2O5 solid-state battery10.1016/j.jpowsour.2013.03.155 ↗
47. Sulfide solid electrolyte with favorable mechanical property for all-solid-state lithium battery10.1038/srep02261 ↗
48. Compliant yet brittle mechanical behavior of Li2S-P2S 5 lithium-ion-conducting solid electrolyte10.1002/aenm.201602011 ↗
49. Mechanical behavior of Li-ion-conducting crystalline oxide-based solid electrolytes. A brief review
50. Interfacial challenges in solid-state Li ion batteries10.1021/acs.jpclett.5b02352 ↗
51. Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems10.1039/C6TA05439K ↗
52. Negating interfacial impedance in garnet-based solid-state Li metal batteries10.1038/nmat4821 ↗
53. Origin of outstanding stability in the lithium solid electrolyte materials: insights from thermodynamic analyses based on first-principles calculations10.1021/acsami.5b07517 ↗
54. Degradation of NASICON-type materials in contact with lithium metal. Formation of mixed conducting interphases (MCI) on solid electrolytes10.1021/jp4051275 ↗
55. Interphase formation on lithium solid electrolytes—an in situ approach to study interfacial reactions by photoelectron spectroscopy10.1016/j.ssi.2015.06.001 ↗
56. Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte10.1016/j.ssi.2015.11.034 ↗
57. Interfacial observation between LiCoO2 electrode and Li2S−P2S5 solid electrolytes of all-solid-state lithium secondary batteries using transmission electron microscopy10.1021/cm901819c ↗
58. Plating a dendrite-free lithium anode with a polymer/ceramic/polymer sandwich electrolyte10.1021/jacs.6b05341 ↗
59. Li-ion transport in all-solid-state lithium batteries with LiCoO2 using NASICON-type glass ceramic electrolytes10.1016/j.jpowsour.2008.08.015 ↗
60. Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification10.1002/adma.200502604 ↗
61. Electrochemical properties of all-solid-state batteries with ZrO2-coated LiNi1/3Mn1/3Co1/3O2 as cathode materials10.1016/j.ssi.2011.11.026 ↗
62. Co-sinterable lithium garnet-type oxide electrolyte with cathode for all-solid-state lithium ion battery10.1016/j.jpowsour.2014.04.065 ↗
63. Effects of sintering temperature on interfacial structure and interfacial resistance for all-solid-state rechargeable lithium batteries10.1016/j.jpowsour.2016.06.068 ↗
64. High coulombic efficiency of lithium plating/stripping and lithium dendrite prevention
65. Capacity fade in solid-state batteries. Interphase formation and chemomechanical processes in nickel-rich layered oxide cathodes and lithium thiophosphate solid electrolytes10.1021/acs.chemmater.7b00931 ↗
66. Non-successive degradation in bulk-type all-solid-state lithium battery with rigid interfacial contact10.1016/j.elecom.2017.03.016 ↗
67. Development of a bipolar Li/composite polymer electrolyte/pyrite battery for electric vehicles10.1016/S0378-7753(01)00608-5 ↗
68. 2007
69. Method for quality parameter identification and classification in battery cell production quality planning of complex production chains for battery cells
70. 2014
71. Meyer · 2001
72. 2011
73. All solid-state sheet battery using lithium inorganic solid electrolyte, thio-LISICON10.1016/j.jpowsour.2009.06.100 ↗
74. Low temperature synthesis and ion conductivity of Li7La3Zr2O12 garnets for solid state Li ion batteries10.1016/j.ssi.2017.08.016 ↗
75. Toward practical all-solid-state lithium-ion batteries with high energy density and safety. Comparative study for electrodes fabricated by dry- and slurry-mixing processes10.1016/j.jpowsour.2017.11.031 ↗
76. Electrochemical performance of a solvent-free hybrid ceramic-polymer electrolyte based on Li7La3Zr2O12 in P(EO)15 LiTFSI10.1016/j.jpowsour.2017.04.014 ↗
77. Excess lithium salt functions more than compensating for lithium loss when synthesizing Li6.5La3Ta0.5Zr1.5O12 in alumina crucible10.1016/j.jpowsour.2014.02.065 ↗
78. Fabrication of all-solid-state lithium battery with lithium metal anode using Al2O3-added Li7La3Zr2O12 solid electrolyte10.1016/j.jpowsour.2011.04.047 ↗
79. Field assisted sintering of dense Al-substituted cubic phase Li7La3Zr2O12 solid electrolytes10.1016/j.jpowsour.2014.03.148 ↗
80. Lavoie · 2010
81. Lithium polymer battery development for electric vehicle application10.1016/S0378-7753(97)02646-3 ↗
82. Bae · 2018
83. Super soft all-ethylene oxide polymer electrolyte for safe all-solid lithium batteries10.1038/srep19892 ↗
84. Johnson · 2017
85. All-solid-state lithium batteries with inorganic solid electrolytes. Review of fundamental science10.1088/1674-1056/25/1/018802 ↗
86. Preparation of highly lithium-ion conductive 80Li2S·20P2S5 thin-film electrolytes using pulsed laser deposition10.1111/j.1551-2916.2009.03442.x ↗
87. Microstructure and ionic conductivity in Li7La3Zr2O12 film prepared by aerosol deposition method10.1149/2.0411501jes ↗
88. Issue and challenges facing rechargeable thin film lithium batteries10.1016/j.materresbull.2007.08.031 ↗
89. Atomic layer deposition of the solid electrolyte garnet Li7La3Zr2O1210.1021/acs.chemmater.7b00944 ↗
90. Kugai · 2003
91. An overview of the aerosol deposition method: process fundamentals and new trends in materials applications
92. Preparation of lithium aluminum titanium phosphate electrolytes thick films by aerosol deposition method10.1111/j.1551-2916.2011.04551.x ↗
93. Some practical aspects of handling lithium metal
94. Bouchard · 1996
95. Hovsepian · 1973
96. Belanger · 1993
97. Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating10.1073/pnas.1518188113 ↗
98. “Lithium-Free” thin-film battery with in situ plated Li anode10.1149/1.1393226 ↗
99. Challenges and issues facing lithium metal for solid-state rechargeable batteries10.1016/j.jpowsour.2017.04.018 ↗
100. Selection of binder and solvent for solution-processed all-solid-state battery10.1149/2.1341709jes ↗