Recent development of non-platinum catalysts for oxygen reduction reaction
Source abstract
Abstract
The slow oxygen reduction reaction (ORR) kinetics on Pt catalysts is among the most limiting factors in the energy conversion efficiency of the state-of-the-art PEMFC. Also, Pt is scarcely available at a high price. Alternative materials are therefore highly sought for fuel cell applications. This review will concentrate on the electrochemical ORR on non-Pt catalysts, especially the experimental development during the past five years. Emphasis is placed on the understanding of the fundamental materials chemistry. This understanding seems pivotal for new designs of PEM cathode materials. Future outlooks are provided for researchers in engineering to select promising candidates for ORR.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Electrochemical Analysis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (66)
Show source-provided references
1. For a general review of fuel cell vehicle technology, please visit Fuel Economy Agency Website at www.fueleconomy.gov.
2. Electrocatalytic activity of ruthenium for oxygen reduction in alkaline solution10.1016/S0013-4686(99)00439-9 ↗
3. Tailoring surface electronic states via strain to control adsorption: O/Cu/Ru(0001)10.1016/j.susc.2003.12.010 ↗
4. Adsorption and dissociation of O2 on gold surfaces: effect of steps and strain10.1021/jp034380x ↗
5. Evidence for molecularly chemisorbed oxygen on TiO2 supported gold nanoclusters and Au(111)10.1021/ja039214h ↗
6. J.D. Stiehl, T.S. Kim, S.M. McClure, C.B. Mullins, Formation of molecularly chemisorbed oxygen on TiO2-supported gold nanoclusters and Au(111) from exposure to an oxygen plasma jet, J. Phys. Chem. B 109 (2005) 6316–6322.10.1021/jp044553y ↗
7. Effect of metal ad-layers on Au(111) electrodes on electrocatalytic reduction of oxygen in an alkaline solution10.1016/j.elecom.2004.05.026 ↗
8. Thermodynamic guidelines for the design of bimetallic catalysts for oxygen electroreduction and rapid screening by scanning electrochemical microscopy. M–Co (M:Pd, Ag, Au)10.1021/ja0449729 ↗
9. Oxygen reduction at electrochemically deposited crystallographically oriented Au(100)-like gold nanoparticles10.1016/j.elecom.2004.10.010 ↗
10. Oxygen adsorption on hydrated gold cluster anions: experiment and theory10.1021/ja034905z ↗
11. Electrocatalytic reduction of oxygen to water at Au nanoclusters vacuum-evaporated on boron-doped diamond in acidic solution10.1016/j.elecom.2004.05.025 ↗
12. Simple preparation method of Pd nanoparticles on an Au electrode and its catalysis for dioxygen reduction10.1039/b300566f ↗
13. Electrocatalytic reactivity for oxygen reduction of palladium-modified carbon nanotubes synthesized in supercritical fluid10.1016/j.elecom.2005.01.007 ↗
14. Electroreduction of dioxygen (ORR) in alkaline medium on Ag/C and Pt/C nanostructured catalysts-effect of the presence of methanol10.1016/j.electacta.2004.05.009 ↗
15. Energy conversion catalysis using semiconducting transition metal cluster compounds10.1038/323431a0 ↗
16. Methanol-resistant cathodic oxygen reduction catalysts for methanol fuel cells10.1023/A:1017575008333 ↗
17. X. Chen, G. Chen, Stable Ti/RuO2–Sb2O5–SnO2 electrodes for O2 evolution, Electrochim. Acta 50 (2005) 4155–4159.10.1016/j.electacta.2005.01.032 ↗
18. Dissociation preference of oxygen molecules on an inhomogeneously strained Cu(001) surface10.1016/j.susc.2004.01.063 ↗
19. The kinetics of the reaction of gaseous hydrogen atoms with oxygen on Cu(111) surfaces toward water10.1021/jp0112222 ↗
20. Interaction of gaseous hydrogen atoms with oxygen covered Cu(100) surfaces10.1016/S0039-6028(01)00855-X ↗
21. Kinetics of abstraction of D and O on Cu(110) surfaces by gaseous H atoms10.1021/jp021928b ↗
22. Reduction of oxygen pre-treated Ni(111) by H2 exposure: UPS and MIES studies compared with Monte Carlo simulations10.1016/j.susc.2003.09.051 ↗
23. Oxygen reduction on anodically formed titanium dioxide10.1016/j.electacta.2004.07.009 ↗
24. Electrocatalyst materials for fuel cells based on the polyoxometalates [Pmo(12−n)VnO40](3+n)− (n=0–3)10.1016/j.electacta.2004.08.014 ↗
25. Stability and electrocatalytic activity for oxygen reduction in WC+Ta catalyst10.1016/j.electacta.2004.03.018 ↗
26. Reverse micelle assisted dispersion of lanthanum manganite on carbon support for oxygen reduction cathode10.1149/1.1633266 ↗
27. Adlayer structure of and electrochemical O2 reduction on cobalt porphine-modified and cobalt octaethylporphyrin-modified Au(111) in HClO410.1021/jp0366421 ↗
28. Proton-coupled O–O activation on a redox platform bearing a hydrogen-bonding scaffold10.1021/ja028548o ↗
29. Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin10.1039/b001620i ↗
30. Targeted proton delivery in the catalyzed reduction of oxygen to water by bimetallic Pacman porphyrins10.1021/ja049115j ↗
31. Mechanism of four-electron reduction of dioxygen to water by ferrocene derivatives in the presence of perchloric acid in benzonitrile, catalyzed by cofacial dicobalt poyphyrins10.1021/ja048403c ↗
32. Catalytically active μ-oxodiiron(IV) oxidants from iron(III) and dioxygen10.1021/ja0460458 ↗
33. meso-Tetrakis(4-N-benzylpyridyl)-porphyrin and its supramolecular complexes formed with anionic metal-oxo cluster: spectroscopy and electrocatalytic reduction of dioxygen10.1016/S0020-1693(00)00154-7 ↗
34. Fabrication of a metallopoyphyrin-polyoxometalate hybrid film by a layer-by-layer method and its catalysis for hydrogen evolution and dioxygen reduction10.1021/jp035274y ↗
35. A new highly efficient tetra-electronic catalyst based on a cobalt porphyrin bound to four μ3-oxo-ruthenium acetate clusters10.1016/S0022-0728(00)00348-X ↗
36. Supramolecular tetracluster-cobalt porphyrin: a four-electron transfer catalyst for dioxygen reduction10.1016/j.electacta.2003.12.052 ↗
37. Charge transfer at electrostatically assembled tetraruthenated porphyrin modified electrodes10.1016/S0022-0728(02)00769-6 ↗
38. Effect of electron availability on selectivity of O2 reduction by synthetic monometallic Fe porphyrins10.1021/ic034488r ↗
39. Reactivity of electrodes modified with substituted metallophthalocyanines. Correlations with redox potentials, Hammett parameters and donor–acceptor intermolecular hardness10.1016/S0013-4686(01)00614-4 ↗
40. Electrocatalytic reduction of oxygen in a novel catalytic system with cobalt phthalocyanines and manganese oxide10.1149/1.1813654 ↗
41. Adlayer structures and electrocatalytic activity for O2 of metallophthalocyanines on Au(111): in situ scanning tunnelling microscopy study10.1021/jp027825a ↗
42. Electrochemical properties of vanadium(III, IV, V)–salen complexes in acetonitrile. Four-electron reduction of O2 by V(III)–salen10.1021/ic990958z ↗
43. Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics10.1021/ja028779v ↗
44. Dioxygen binding to complexes with Fe(II)2(μ-OH)2 cores: steric control of activation barriers and O2-adduct formation10.1021/ic0485312 ↗
45. Spectroscopic elucidation of a peroxo Ni2(μ-O2) intermediate derived from a nickel(I) complex and dioxygen10.1002/anie.200460747 ↗
46. β-Ditetiminate ligand backbone structural effects on Cu(I)/O2 reactivity: unique copper–superoxo and bis(μ-oxo) complexes10.1021/ja017820b ↗
47. Snapshots of dioxygen activation by copper: the structure of a 1:1Cu/O2 adduct and its use in syntheses of asymmetric bis(μ-oxo) complexes10.1021/ja027164v ↗
48. Dioxygen activation at a single copper site: structure, bonding, and mechanism of formation of 1:1 Cu–O2 adducts10.1021/ja045678j ↗
49. Dioxygen activation by a nickel thioether complex: characterization of a Ni(III)2(μ-O)2 core10.1021/ja016209+ ↗
50. A monomeric nickel-dioxygen adduct derived from a nickel(I) complex and O210.1021/ic049876n ↗
51. Oxygen activation by nonheme iron(II) complexes: α-keto carboxylate versus carboxylate10.1021/ja028867f ↗
52. Heat-treated iron(III) tetramethoxyphenyl porphyrin chloride supported on high-area carbon as an electrocatalyst for oxygen reduction: part 3, detection of hydrogen-peroxide during oxygen reduction10.1016/S0013-4686(99)00294-7 ↗
53. On active-site heterogeneity in pyrolyzed carbon-supported iron poyphyrin catalysts for the electrochemical reduction of oxygen: an in situ Mössbauer study10.1021/jp0266087 ↗
54. O2 reduction in PEM fuel cells: activity and active site structural information for catalysts obtained by the pyrolysis at high temperature of Fe precursors10.1021/jp002444n ↗
55. Molecular oxygen reduction in PEM fuel cells: evidence for the simultaneous presence of two active sites in Fe-based catalysts10.1021/jp020267f ↗
56. Oxygen reduction catalysts for polymer electrolyte fuel cells from the pyrolysis of iron acetate adsorbed on various carbon supports10.1021/jp021634q ↗
57. Fe-based catalysts for oxygen reduction in PEM fuel cells, pre-treatment of the carbon support10.1149/1.1781611 ↗
58. Direct preparation of carbon nanofiber electrodes via pyrolysis of iron(II) phthalocyanine: electrocatalytic aspects for oxygen reduction10.1021/jp0496553 ↗
59. Heat-treated transition metal hexacyanometallates as electrocatalysts for oxygen reduction insensitive to methanol10.1149/1.1690287 ↗
60. PEM fuel cell electrodes10.1016/j.jpowsour.2003.12.055 ↗
61. Ni0.3Co2.7O4 spinel particles/polypyrrole composite electrode: study by X-ray photoelectron spectroscopy10.1016/S0013-4686(02)00514-5 ↗
62. Oxygen reduction on oxide/polypyrrole composite electrode: effect of doping anions10.1016/j.electacta.2004.08.025 ↗
63. Electrocatalytic activity of electrodeposited composite films of polypyrrole and CoFe2O4 nanoparticles towards oxygen reduction reaction10.1016/j.electacta.2004.05.015 ↗
64. J. Kim, A.A. Gewirth, Electrocatalysis of peroxide reduction by Au-stabilized, Fe-containing poly(vinylpyridine) films, J. Phys. Chem. B 109 (2005) 9684–9690.10.1021/jp050672h ↗
65. Effective utilization of nanospaces in activated carbon for enhancing catalytic activity in fuel cell electrodes10.1149/1.1644134 ↗
66. An analytical approach on effect of diffusion layer on ORR for PEMFCs10.1016/j.jpowsour.2003.11.096 ↗