Application of electrochemical impedance spectroscopy to commercial Li-ion cells: A review
Source abstract
Abstract
Electrochemical impedance spectroscopy (EIS) is a widely applied non-destructive method of characterisation of Li-ion batteries. Despite its ease of application, there are inherent challenges in ensuring the quality and reproducibility of the measurement, as well as reliable interpretation and validation of impedance data. Here, we present a focus review summarising best metrological practice in the application of EIS to commercial Li-ion cells. State-of-the-art methods of EIS interpretation and validation are also reported and examined to highlight the benefits and drawbacks of the technique.
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Research context
OpenAlex topics: Advanced Battery Technologies Research · Advancements in Battery Materials · Advanced Battery Materials and Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Beard · 2019
2. A study of the influence of measurement timescale on internal resistance characterisation methodologies for lithium-ion cells10.1038/s41598-017-18424-5 ↗
3. On-line adaptive battery impedance parameter and state estimation considering physical principles in reduced order equivalent circuit battery models part 2. Parameter and state estimation10.1016/j.jpowsour.2014.03.046 ↗
4. Experimental characterization of Li-Ion battery resistance at the cell, module and pack level
5. Ageing study of 26650 type li-ion batteries module at the charge-discharge rates of 1 C10.1063/1.5125355 ↗
6. Investigation into state-of-health impedance diagnostic for 26650 4P1S battery packs10.1149/2.0631701jes ↗
7. Impedance measurements of kilowatt-class lithium ion battery modules/cubicles in energy storage systems by square-current electrochemical impedance spectroscopy10.1016/j.electacta.2017.05.076 ↗
8. Quick testing of batteries in lithium-ion battery packs with impedance-measuring technology10.1016/j.jpowsour.2003.09.045 ↗
9. Current distribution within parallel-connected battery cells10.1016/j.jpowsour.2016.10.010 ↗
10. A fast classification method of retired electric vehicle battery modules and their energy storage application in photovoltaic generation
11. Parameter variations within Li-Ion battery packs - theoretical investigations and experimental quantification10.1016/j.est.2018.04.031 ↗
12. A comparison of methodologies for the non-invasive characterisation of commercial Li-ion cells10.1016/j.pecs.2019.01.001 ↗
13. Experimental investigation of parametric cell-to-cell variation and correlation based on 1100 commercial lithium-ion cells10.1016/j.est.2017.09.010 ↗
14. A study of 40 Ah lithium ion batteries at zero percent state of charge as a function of temperature10.1016/j.jpowsour.2014.06.064 ↗
15. Introduction to electrochemical impedance spectroscopy as a measurement method for the wetting degree of lithium-ion cells10.1149/2.0081814jes ↗
16. Pseudo-two-dimensional model and impedance diagnosis of micro internal short circuit in lithium-ion cells10.1016/j.est.2019.101085 ↗
17. Tracking of electrochemical impedance of batteries10.1016/j.jpowsour.2016.02.006 ↗
18. AC impedance and state-of-charge analysis of a sealed lithium-ion rechargeable battery10.1007/s100080050173 ↗
19. Review of state-of-charge indication of batteries by means of a.c. impedance measurements10.1016/S0378-7753(99)00351-1 ↗
20. A new method to estimate the state of charge of lithium-ion batteries based on the battery impedance model10.1016/j.jpowsour.2013.01.094 ↗
21. State-of-charge estimation of LiFePO4-Li4Ti5O12 batteries using history-dependent complex-impedance10.1149/2.0221916jes ↗
22. Soc li-ion battery monitoring with impedance spectroscopy
23. Capacity measurements of Li-ion batteries using AC impedance spectroscopy10.3390/wevj3010127 ↗
24. A practical framework of electrical based online state-of-charge estimation of lithium ion batteries10.1016/j.jpowsour.2014.01.020 ↗
25. EIS measurements for determining the SoC and SoH of Li-ion batteries10.1149/1.3589920 ↗
26. Variable fractional order - a comprehensive evaluation indicator of lithium-ion batteries10.1016/j.jpowsour.2019.227411 ↗
27. Fractional-order modeling and parameter identification for lithium-ion batteries10.1016/j.jpowsour.2015.05.059 ↗
28. A systematic model-based degradation behavior recognition and health monitoring method for lithium-ion batteries10.1016/j.apenergy.2017.05.124 ↗
29. Cycle life characterisation of large format lithium-ion cells, 2013 World Electric Vehicle Symposium and Exhibition
30. Correlation between capacity and impedance of lithium-ion cells during calendar and cycle life10.1016/j.jpowsour.2015.11.096 ↗
31. Estimation of state of health of lithium-ion batteries based on charge transfer resistance considering different temperature and state of charge10.1016/j.est.2018.11.020 ↗
32. Review-Development of diagnostic process for commercially available batteries, especially lithium ion battery, by electrochemical impedance spectroscopy10.1149/2.0141514jes ↗
33. Performance analysis and SOH (state of health) evaluation of lithium polymer batteries through electrochemical impedance spectroscopy10.1016/j.energy.2015.05.148 ↗
34. SOH Estimation of lithium-ion batteries based on fast time domain impedance spectroscopy
35. Accelerated calendar and pulse life analysis of lithium-ion cells10.1016/S0378-7753(03)00193-9 ↗
36. Temperature measurement of large format pouch cells with impedance spectroscopy
37. Measurement of the internal cell temperature via impedance: evaluation and application of a new method10.1016/j.jpowsour.2013.06.013 ↗
38. Sensorless battery temperature measurements based on electrochemical impedance spectroscopy10.1016/j.jpowsour.2013.09.005 ↗
39. A new lithium-ion battery internal temperature on-line estimate method based on electrochemical impedance spectroscopy measurement10.1016/j.jpowsour.2014.10.182 ↗
40. Lithium-ion battery temperature on-line estimation based on fast impedance calculation10.1016/j.est.2019.100952 ↗
41. A comparison and accuracy analysis of impedance-based temperature estimation methods for Li-ion batteries10.1016/j.apenergy.2016.04.103 ↗
42. Internal cell temperature measurement and thermal modeling of lithium ion cells for automotive applications by means of electrochemical impedance spectroscopy
43. In situ X-ray diffraction and electrochemical impedance spectroscopy of a nanoporous Li2FeSiO4/C cathode during the initial charge/discharge cycle of a Li-ion battery10.1016/j.jpowsour.2013.03.193 ↗
44. Sustainability assessment of second use applications of automotive batteries: ageing of Li-ion battery cells in automotive and grid-scale applications10.3390/wevj9020024 ↗
45. Performance assessment and classification of retired lithium ion battery from electric vehicles for energy storage10.1016/j.ijhydene.2017.06.043 ↗
46. Good practice guide for papers on batteries for the Journal of Power Sources10.1016/j.jpowsour.2020.227824 ↗
47. 2018
48. Ac impedance analysis of lithium ion battery under temperature control10.1016/j.jpowsour.2012.05.095 ↗
49. A novel method for high frequency battery impedance measurements
50. Influence of cell design on impedance characteristics of cylindrical lithium-ion cells: a model-based assessment from electrode to cell level10.1016/j.est.2017.05.002 ↗
51. Polarization mechanism of high temperature electrolysis in a Ni-YSZ/YSZ/LSM solid oxide cell by parametric impedance analysis10.1016/j.ssi.2012.10.028 ↗
52. Time-domain fitting of battery electrochemical impedance models10.1016/j.jpowsour.2015.04.099 ↗
53. On the interpretation of impedance spectra of large-format lithium-ion batteries and its application in aging studies
54. Impedance spectroscopic investigation of the impact of erroneous cell assembly on the aging of lithium-ion batteries
55. Understanding the impedance spectrum of 18650 LiFePO4-cells10.1016/j.jpowsour.2012.12.020 ↗
56. Impedance characterization of lithium-ion batteries aging under high-temperature cycling: importance of electrolyte-phase diffusion10.1016/j.jpowsour.2019.04.040 ↗
57. Impedance based time-domain modeling of lithium-ion batteries: Part I10.1016/j.jpowsour.2018.01.043 ↗
58. An analysis protocol for three-electrode Li-ion battery impedance spectra: Part I. Analysis of a high-voltage positive electrode10.1149/2.0131709jes ↗
59. Impact of electrolyte solvent and additive choices on high voltage Li-ion pouch cells10.1016/j.jpowsour.2016.08.100 ↗
60. A novel mechanistic modeling framework for analysis of electrode balancing and degradation modes in commercial lithium-ion cells10.1016/j.jpowsour.2017.01.026 ↗
61. Towards understanding heat generation characteristics of Li-ion batteries by calorimetry, impedance, and potentiometry studies10.1149/2.1811712jes ↗
62. Effects of anode active materials to the storage-capacity fading on commercial lithium-ion batteries10.1016/j.jpowsour.2007.06.169 ↗
63. Electrolyte system for high voltage li-ion cells10.1149/2.0321613jes ↗
64. Optimizing current terminals of 18 650 lithium-ion power batteries under high discharge current10.1002/ente.201700008 ↗
65. Ageing mechanisms in lithium-ion batteries10.1016/j.jpowsour.2005.01.006 ↗
66. Temperature-adaptive alternating current preheating of lithium-ion batteries with lithium deposition prevention10.1149/2.0961602jes ↗
67. Factors responsible for impedance rise in high power lithium ion batteries10.1016/S0378-7753(01)00701-7 ↗
68. In operando impedance based diagnostics of electrode kinetics in Li-ion pouch cells10.1149/2.1191910jes ↗
69. Critical review of the use of reference electrodes in Li-ion batteries: a diagnostic perspective10.3390/batteries5010012 ↗
70. Electrode-Resolved monitoring of the ageing of large-scale lithium-ion cells by using electrochemical impedance spectroscopy10.1002/celc.201700686 ↗
71. Equivalent circuit model parameters of a high-power Li-ion battery: thermal and state of charge effects10.1016/j.jpowsour.2010.12.107 ↗
72. Temperature dependence studies of a.c. impedance of lithium-ion cells10.1023/A:1015565404343 ↗
73. On the interpretation of measured impedance spectra of insertion cathodes for lithium-ion batteries10.1149/1.3489353 ↗
74. Charge and discharge characteristics of a commercial LiCoO2-based 18650 Li-ion battery10.1016/j.jpowsour.2006.03.037 ↗
75. Analysis of aging of commercial composite metal oxide - Li 4Ti5O12 battery cells10.1016/j.jpowsour.2014.07.050 ↗
76. Electrode contributions to the impedance of a high-energy density Li-ion cell designed for EV applications10.1016/j.ssi.2013.02.016 ↗
77. Electrochemical modeling of commercial LiFePO4 and graphite electrodes: kinetic and transport properties and their temperature dependence10.1149/2.1151613jes ↗
78. Non-invasive investigation of predominant processes in the impedance spectra of high energy lithium-ion batteries with Nickel-Cobalt-Aluminum cathodes10.1016/j.jpowsour.2018.10.024 ↗
79. Calendar life study of Li-ion pouch cells10.1016/j.jpowsour.2007.08.044 ↗
80. Capacity fade of Sony 18650 cells cycled at elevated temperatures: Part I. Cycling performance10.1016/S0378-7753(02)00474-3 ↗
81. Deterioration of lithium iron phosphate/graphite power batteries under high-rate discharge cycling10.1016/j.electacta.2015.06.096 ↗
82. Influence of over-discharge on the lifetime and performance of LiFePO4/graphite batteries10.1039/C6RA01677D ↗
83. Impedance characterization of an LCO-NMC/graphite cell: ohmic conduction, sei transport and charge-transfer phenomenon10.3390/batteries4030043 ↗
84. Studies on capacity fade of spinel-based Li-ion batteries10.1149/1.1426399 ↗
85. A physically-based equivalent circuit model for the impedance of a LiFePO4/graphite 26650 cylindrical cell10.1149/2.1071709jes ↗
86. Comparison of the capacity fade of Sony US 18650 cells charged with different protocols10.1016/S0378-7753(03)00027-2 ↗
87. Performance degradation of high-power lithium-ion cells—electrochemistry of harvested electrodes10.1016/j.jpowsour.2007.03.071 ↗
88. Distinction of impedance responses of Li-ion batteries for individual electrodes using symmetric cells10.1016/j.electacta.2014.01.091 ↗
89. Two- and three-electrode impedance studies on 18650 Li-ion cells10.1016/S0378-7753(99)00469-3 ↗
90. Non-invasive yet separate investigation of anode/cathode degradation of lithium-ion batteries (nickel–cobalt–manganese vs. graphite) due to accelerated aging10.1016/j.jpowsour.2019.227369 ↗
91. Symmetric cell approach towards simplified study of cathode and anode behavior in lithium ion batteries10.1016/S1388-2481(00)00145-4 ↗
92. Resistance growth in lithium-ion pouch cells with LiNi0.80Co0.15Al0.05O2 positive electrodes and proposed mechanism for voltage dependent charge-transfer resistance10.1149/2.0361910jes ↗
93. Characterization of high-power lithium-ion batteries by electrochemical impedance spectroscopy. I. Experimental investigation10.1016/j.jpowsour.2010.12.102 ↗
94. Experimental investigation of the lithium-ion battery impedance characteristic at various conditions and aging states and its influence on the application10.1016/j.apenergy.2012.09.030 ↗
95. Rate dependence of cell-to-cell variations of lithium-ion cells10.1038/srep35051 ↗
96. Effect of temperature and charge stand on performance of lithium-ion polymer pouch cell10.1016/j.est.2016.02.002 ↗
97. Testing of lithium-ion 18650 cells and characterizing/predicting cell performance10.1016/S0378-7753(98)00238-9 ↗
98. Influence of operational condition on lithium plating for commercial lithium-ion batteries – electrochemical experiments and post-mortem-analysis10.1016/j.apenergy.2017.08.034 ↗
99. A comparative testing study of commercial 18650-format lithium-ion battery cells10.1149/2.0721508jes ↗
100. The effect of the charging protocol on the cycle life of a Li-ion battery10.1016/j.jpowsour.2006.06.040 ↗