Biomass-based porous PDMS absorbents using spent coffee grounds for selective phase separation and sustainable waste valorization

1. M. Montazeri, R. Norouzbeigi, Fabrication and Characterization of Renewable Alginate-Lignin Aerogel for Efficient Oil Absorption. J. Polym. Environ. 32, 2937–2951 (2024)10.1007/s10924-023-03121-4 ↗

2. S. Mirshahghassemi, J.R. Lead, Oil recovery from water under environmentally relevant conditions using magnetic nanoparticles. Environ. Sci. Technol. 49, 11729–11736 (2015)10.1021/acs.est.5b02687 ↗

3. A.R. Oliveira, A. Neto, P.C.B. Medeiros, M.J.O. Andrade, N.A. dos Santos, Chronic organic solvent exposure changes visual tracking in men and women. Frot Neurosci 11, 666 (2017)

4. W. Ben, B. Zhu, X. Yuan, Y. Zhang, M. Yang, Z. Qiang, Occurrence, removal and risk of organic micropollutants in wastewater treatment plants across china: comparison of wastewater treatment processes. Water Res. 130, 38–46 (2018)10.1016/j.watres.2017.11.057 ↗

5. S.R. Churipard, K.S. Kanakikodi, D.A. Rambhia, C.S.K. Raju, A.B. Halgeri, N.V. Choudary, G.S. Ganesh, R. Ravishannkar, S.P. Maradur, Porous polydivinylbenzene (PDVB) as an efficient adsorbent for hydrocarbons: effect of porogens on adsorption capacity. Chem. Eng. J. 380, 122481 (2020)10.1016/j.cej.2019.122481 ↗

6. S.W. Zou, S.W. How, J.P. Chen, Photocatalytic treatment of wastewater contaminated with organic waste and copper ions from the semiconductor industry. Ind. Eng. Chem. Res. 46, 6566–6571 (2007)10.1021/ie070478c ↗

7. H. Bi, H. Yin, X. Cao, X. Xie, C. Tan, C. Huang, C. Chen, F. Chen, Q. Yang, X. Bu, X. Lu, L. Sun, H. Zhang, Carbon fiber aerogel made from raw cotton: a novel, efficient and recyclable sorbent for oils and organic solvents. Adv. Mater. 25, 5916–5921 (2013)10.1002/adma.201302435 ↗

8. B. Doshi, B. Sillanpaa, S. Kalliola, A review of bio-based mateirals for oil spill treatment. Water Res. 135, 262–277 (2018)10.1016/j.watres.2018.02.034 ↗

9. J. Eow, M. Ghadiri, Electrostatic enhancement of coalescence of water droplets in oil: a review of the technology. Chem. Eng. J. 85, 357–368 (2002)10.1016/S1385-8947(01)00250-9 ↗

10. EPA, 2017. Oil spill response techniques, EPA's response techniques [online] available at: https://www.epa.gov/emergency-response/epas-response-techniques

11. R. Gupta, G. Dunderdale, M. England, A. Hozumi, Oil/water separation techniques: a review of recent progresses and future directions. J Mater Chem A 5, 16025–16058 (2017)10.1039/C7TA02070H ↗

12. L. Feng, Z. Zhang, Z. Mai, Y. Ma, B. Liu, L. Jiang, D. Zhu, A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water. Angew. Chem. Int. Ed. 116, 2046–2048 (2004)10.1002/ange.200353381 ↗

13. C. Garcia, Y. Kim, Spent Coffee Grounds and Coffee Silverskin as Potential Materials for Packaging: A Review. J. Polym. Environ. 29, 2372–2384 (2021)10.1007/s10924-021-02067-9 ↗

14. C. Xia, Y. Li, Y. Fei, W. Gong, Facile one-pot synthesis of superhydrophobic reduced graphene oxide-coated polyurethane sponge at the presence of ethanol for oil-water separation. Chem. Eng. J. 345, 648–658 (2018)10.1016/j.cej.2018.01.079 ↗

15. N. Cao, B. Yang, A. Barras, S. Szunerits, R. Boukherroub, Polyurethane sponge functionalized with superhydrophobic nanodiamond particles for efficient oil/water separation. Chem. Eng. J. 307, 319–325 (2017)10.1016/j.cej.2016.08.105 ↗

16. S. Baskakov, Y. Baskakova, E. Kabachkov, N. Dremova, A. Michtchenko, Y. Shulga, Novel superhydrophobic aerogel on the base of polytetrafluoroethylene. ACS Appl. Mater. Interfaces 11, 32517–32522 (2019)10.1021/acsami.9b10455 ↗

17. J. Zhao, J. Xue, R. Qiu, W. Guo, L. Fan, P. Wang, Superoleophilic Ulva prolifera for oil/water separation: a repayment from the green tide. Chem. Eng. J. 292, 147–155 (2016)10.1016/j.cej.2016.02.016 ↗

18. J. Sun, H. Bi, H. Jia, S. Su, H. Dong, X. Xie, L. Sun, A low cost paper tissue-based PDMS/SiO2 composite for both high efficient oil absorption and water-in-oil emulsion separation. J. Clean. Prod. 244, 118814–118821 (2020)10.1016/j.jclepro.2019.118814 ↗

19. D. Zhu, S. Handschuh-Wang, S. Zhou, Recent progress in fabrication and application of polydimethylsiloxane sponges. J Mater Chem A 5, 16467 (2017)10.1039/C7TA04577H ↗

20. X. Zhao, L. Li, B. Li, J. Zhang, A. Wang, Durable superhydrophobic/superoleophilic PDMS sponges and their applications in selective oil absorption and in plugging oil leakages. J Mater Chem A 2, 18281–18287 (2014)10.1039/C4TA04406A ↗

21. S.J. Choi, T.H. Kwon, H. Im, H.D. Moon, J. Baek, M.L. Seol, J.P. Duarte, J.P. Choi, A polydimethylsiloxane (PDMS) sponge for the selective absorption of oil from water. ACS Appl. Mater. Interfaces 3, 4552–4556 (2011)10.1021/am201352w ↗

22. S. Kang, S. Lee, S. Lee, S. Kim, J. Kim, H. Algadi, S. Al-Sayari, D. Kim, D. Lee, Highly sensitive pressure sensor based on bioinspired porous structure for real-time tactile sensing. Adv Electron Mater 2, 1600356 (2016)10.1002/aelm.201600356 ↗

23. M. Grosse, M. Lamotte, M. Birot, H. Deleuze, Preparation of microcellular polysiloxane monoliths. J. Polym. Sci. A Polym. Chem. 24, 21–32 (2008)10.1002/pola.22351 ↗

24. D. Pahovnik, J. Majer, E. Žagar, S. Kovacic, Synthesis of hydrogel polyHIPEs from functionalized glycidyl methacrylate. Polym. Chem. 7, 5132 (2016)10.1039/C6PY01122E ↗

25. M. Tebboth, M. Jiang, A. Kogelbauer, A. Bismarck, Inflatable elastomeric macroporous polymers synthesized from medium internal phase emulsion templates. ACS Appl. Mater. Interfaces 7, 19243–19250 (2015)10.1021/acsami.5b05123 ↗

26. S. Li, Z. Song, Y. Fan, D. Wei, C. Liao, C. Du, X. Yan, Z. Han, Y. Liu, 3D printing of magnetically responsive superhydrophobic porous membranes with on-demand oil-absorption property. Coll. Suf. A. Colloid. Suf. A Physicochem. Eng. Asp. 682, 132965 (2024)10.1016/j.colsurfa.2023.132965 ↗

27. A. Zhang, M. Chen, C. Du, H. Guo, H. Bai, L. Li, Poly (dimethylsiloxane) oil absorbent with a three-dimensionally interconnected porous structure and swellable skeleton. ACS Appl. Mater. Interfaces 5, 10201–10206 (2013)10.1021/am4029203 ↗

28. U. Jamnonkhaow, P. Planklang, A. Reingsang, C. Peng, C. Chu, Valorization of spent coffee grounds through integrated bioprocess of fermentable sugars, volatile fatty acids, yeast-based single-cell protein and biofuels production. Bioresour. Technol. 393, 130107–130116 (2024)10.1016/j.biortech.2023.130107 ↗

29. J. Yoo, S.J. Chang, S.J. Wi, S. Kim, Spent coffee grounds as supporting materials to produce bio-composite PCM with natural waxes. Chemosphere 235, 625–635 (2019)10.1016/j.chemosphere.2019.06.195 ↗

30. J.H. Lee, J.H. Lee, J.H. Kim, H.Y. Yoo, H.Y. Park, H.Y. Kim, Biodiesel production by lipases co-immobilized on the functionalized activated carbon. Bioresou Tecnol Rep 7, 100248 (2019)

31. Y. Chun, Y. Ko, Y. Do, Y. Jung, Y. Kim, U. Choi, Spent coffee grounds: massively supplied carbohydrate polymer applicable to electrorheology. Colloid. Surface. A 562, 392–401 (2019)10.1016/j.colsurfa.2018.11.005 ↗

32. L. Ceseracciu, J.A. Heredia-Guerrero, S. Dante, A. Athanassiou, I.S. Bayer, Robust and biodegradable elastomers based on corn starch and polydimethylsiloxane (PDMS). ACS Appl. Mater. Interfaces 7, 3742–3753 (2015)10.1021/am508515z ↗

33. Z. Chu, Y. Feng, Y. Seeger, Oil water separation with selective super antiwetting superwetting surface materials. Angew. Chem. Int. Ed. 54, 2328–2338 (2015)10.1002/anie.201405785 ↗

34. Y. Wang, Y. Huang, R.S. Gurney, R.S. Liu, Superhydrophobic and photocatalytic PDMS/TiO2 coating with environmental stability and multifunctionality. Colloids Surf A Physicochem Eng Asp 561, 101–108 (2019)10.1016/j.colsurfa.2018.10.054 ↗

35. M. Mahrashi, R. Bairwan, R. Mushtaq, H. Khali, M. Badr, M. Alissa, C. Abdullah, B. Ali, W. Rizg, K. Kosny, Novel enhancement of interfacial interaction and properties in biodegradable polymer composites using green chemically treated spent coffee ground microfiller. Int. J. Biol. Macromol. 264, 131333–131346 (2024)10.1016/j.ijbiomac.2024.131333 ↗

36. C. Yu, C. Yu, L. Cui, L. Song, L. Zhao, L. Ma, L. Jiang, Facile preparation of the porous PDMS oil-absorbent of oil/water separation. Adv. Mater. Interfaces 4, 1600862 (2017)10.1002/admi.201600862 ↗

37. J.H. Lee, D.H. Kim, Y.D. Kim, High-performance, recyclable and superhydrophobic oil absorbents consisting of cotton with a polydimethylsiloxane shell. J. Ind. Eng. Chem. 35, 140–145 (2016)10.1016/j.jiec.2015.12.025 ↗

38. P. Biard, P. Couvert, P. Giraudet, Volatile organic compounds absorption in packed column: theoretical assessment of water, DEHA and PDMS 50 as absorbents. J. Ind. Eng. Chem. 59, 70–78 (2018)10.1016/j.jiec.2017.10.008 ↗

39. Q. Zhang, K. Li, J. Li, Y. Li, Fabrication of hierarchically porous superhydrophobic polystyrene foam for self-cleaning, oil absorbent, highly efficient oil–water separation. Chem. Eng. J. 483, 149338–149349 (2024)10.1016/j.cej.2024.149338 ↗

40. J. Wang, Y. Wang, F. Yang, F. Cui, S. Cui, Z. Nie, Q. Wei, Facile fabrication of expanded graphite/polydimethylsiloxane foams for oil–water separation. Sep. Purif. Technol. 334, 126053–126067 (2024)10.1016/j.seppur.2023.126053 ↗

41. A. Turco, E. Primiceri, M. Frigione, G. Maruccio, G. Malitesta, An innovative, fast and facile soft-template approach for the fabrication of porous PDMS for oil-water separation. J Mater Chem A 5, 23785–23793 (2017)10.1039/C7TA06840A ↗

42. H. Mi, H. Jing, H. Xie, H. Huang, H. Turung, Magnetically driven superhydrophobic silica sponge decorated with hierarchical cobalt nanoparticles for selective oil absorption and oil/water separation. Chem. Eng. J. 337, 541–551 (2018)10.1016/j.cej.2017.12.135 ↗

43. C. Yu, C. Yu, C. Cui, C. Song, C. Zhao, C. Ma, C. Jiang, Facile preparation of the porous PDMS oil-absorbent for oil/water separation. Adv. Mater. Interfaces 4, 1600862–1300866 (2017)10.1002/admi.201600862 ↗

44. T.H. Lowery, T.H. Richardson, Mechanism and Theory in Organic Chemistry, 3rd edn. (Harper Collins Publishers, New York, 1987)

45. S.B. Kim, Y. Zhang, S.M. Won, S.M. Bandodkar, S.M. Sekine, Y. Xue, Y. Koo, Y. Harshman, Y.J. Martin, M. Park, T.R. Ray, K.E. Crawford, K. Lee, J. Choi, R.L. Pitsch, C.C. Grigsby, A.J. Strang, Y. Chen, V. Xu, S. Kim, A. Koh, J.S. Ha, J.S. Hang, S.W. Kim, J.A. Rogers, Super-absorbent polymer valves and colorimetric chemistries for time-sequenced discrete sampling and chloride analysis of sweat via skin-mounted soft microfluidics. Small 14, 1703334–2170344 (2018)10.1002/smll.201703334 ↗