Synergistic effect between CeO2 and Cu for ethylene carbonate hydrogenation
Source abstract
Abstract
Cu–CeO2/C composite catalysts with porous structure were prepared by a microwave-assisted carbonization–impregnation method, which demonstrated a significant performance enhancement for the selective hydrogenation of ethylene carbonate. It was shown by XRD, BET, SEM, TEM, XPS and H2-TPR that Cu–CeO2/C catalysts with appropriate copper-ceria interactions improving the dispersion of copper particles and providing a higher ratio of Cu+/(Cu+ + Cu0) and more oxygen vacancies on the surface. These interactions resulted in an enhanced adsorption of ethylene carbonate and a high hydrogenation activity. The effect of significant operating conditions such as reaction temperature, H2 pressure and substrate ratio on the EC hydrogenation activity over the Cu–CeO2/C catalyst was also investigated to predict the optimal conditions to achieve maximum activity in this process.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Carbon dioxide utilization in catalysis · Catalysis for Biomass Conversion · Catalysts for Methane Reforming
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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