Porous nitrogen-doped carbon supported MoO2/Mo2C hybrid catalyst for efficient oxidative coupling of primary amines to imines
Source abstract
Abstract
A MoO2/Mo2C hybrid catalyst supported on N-doped carbon (Mo2C/MoO2@NC) was successfully prepared, which is featured with moderate mesoporosity, uniform metallic nanoparticles, and rich oxygen-vacancies. It showed excellent efficiency (99% imine yield) and good reusability for oxidative self-coupling of benzylamine to N-benzylbenzaldimine under mild conditions (85 °C, 3 h, 1 bar O2). In addition, the catalyst Mo2C/MoO2@NC also exhibited a universal applicability for oxidative coupling of other primary amines to imines with impressive conversion and satisfying target product selectivity. This method provides an efficient and environment friendly strategy for catalytic synthesis of complex imines from primary amines.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Asymmetric Hydrogenation and Catalysis · Chemical Synthesis and Characterization · Chemical Synthesis and Reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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