journal article·2020-04

Surfactant-assisted imidacloprid intercalation of layered zinc hydroxide nitrate: synthesis, characterisation and controlled release formulation

Sharifah Norain Mohd Sharif, Norhayati Hashim, Illyas Md Isa, Suriani Abu Bakar, Mohamad Idris Saidin, Mohamad Syahrizal Ahmad, Mazidah Mamat, Mohd Zobir Hussein

Journal of Porous Materials· Volume 27· Issue 2
Publisher page

Abstract

A neutrally charged insecticide, imidacloprid (IC), has been intercalated into zinc hydroxide nitrate (ZHN) with the assistance of sodium dodecylsulphate (SDS). The presence of SDS assists the intercalation of IC by forming a hydrophobic region in the interlayer gallery of ZHN. The intercalated compound, ZHN–SDS–IC, was characterised using powder X-ray diffraction (PXRD), thermogravimetric analysis, Fourier transform infrared spectroscopy, elemental analysis, field emission scanning electron microscopy, and gas sorption analysis. The PXRD studies demonstrated intercalation peaks at lower 2θ, which confirmed the intercalation of IC and SDS in the interlayer gallery of ZHN. The release and kinetic studies of ZHN–SDS–IC reveals that the IC were successfully released in controlled manner (with release time up to 1478 min), and were governed by pseudo second order kinetic model. The ZHN–SDS–IC synthesised is hopefully beneficial in overcoming the consequences of excessive usage of insecticide in paddy cultivation.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Polymer-Based Agricultural Enhancements · Iron oxide chemistry and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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