Properties of magnetic microbeads in removing bisphenol-A from aqueous phase

Bilgen Osman; Elif Tümay Özer; Ali Kara; Emel Yeşilova; Necati Beşirli

doi:10.1007/s10934-014-9870-z

journal article·2015-02

Properties of magnetic microbeads in removing bisphenol-A from aqueous phase

Bilgen Osman, Elif Tümay Özer, Ali Kara, Emel Yeşilova, Necati Beşirli

Journal of Porous Materials· Volume 22· Issue 1

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Abstract

In this study, magnetic poly(ethylene glycol dimethacrylate-N-methacryloyl-l-tryptophan methyl ester) [m-poly(EGDMA-MATrp)] beads (average diameter = 53–103 μm) were synthesized by copolymerizing of N-methacryloyl-l-tryptophan methyl ester with ethylene glycol dimethacrylate in the presence of magnetite (Fe3O4) and used for removal of bisphenol-A (BPA). The m-poly(EGDMA-MATrp) beads were characterized by N2 adsorption/desorption isotherms (BET), X-ray photoelectron spectroscopy, scanning electron microscopy, infrared spectroscopy, thermal gravimetric analysis, electron spin resonance analysis and swelling studies. To evaluate the efficiency of m-poly(EGDMA-MATrp) beads for adsorption of BPA from aqueous medium, the effects of pH, initial concentration, contact time and temperature were analyzed. The maximum BPA adsorption capacity of the m-poly(EGDMA-MATrp) beads was determined as 139.6 mg/g at pH 5.0, 25 °C. All the isotherm data can be fitted with the Langmuir, Freundlich and Dubinin–Radushkevich isotherm models. The adsorption process obeyed pseudo-second-order kinetic model.

Source: openaire · Quality: candidate unverified · Source record ↗

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OpenAlex topics: Adsorption and biosorption for pollutant removal · Microfluidic and Capillary Electrophoresis Applications · Polymer crystallization and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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