The relationship between the hydrophobic capacity and extraction efficiency of organic–inorganic hybrid mesoporous silicas for the determination of dibutyl phthalate by SPME–HPLC
Source abstract
Abstract
Three kinds of organofunctionalized mesoporous silicas, including methyl-MCM-41, propyl-MCM-41 and octyl-MCM-41, were synthesized via one-step co-condensation and for the first time employed as the coatings of solid-phase microextraction fibers coupled with HPLC to extract dibutyl phthalate (DBP). The samples were characterized by fourier transform infrared, small-angle X-ray diffractometer, transmission electron microscope, thermogravimetry analysis and N2 adsorption–desorption. The results showed that the organofunctionalized mesoporous silicas still preserve a desirable two-dimensional P6mm hexagonal structure with large pore volume, good thermal stability and strong hydrophobicity after introducing alkyl groups of various carbon chains to the framework of MCM-41. When the concentration of DBP in standard solution is 1.0 × 10−9 mol L−1, the extraction efficiency of octyl-MCM-41, propyl-MCM-41 and methyl-MCM-41 is 5.7, 4.6 and 4.1 times higher than that of the pure MCM-41, respectively.
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Research context
OpenAlex topics: Mesoporous Materials and Catalysis · Analytical chemistry methods development · Analytical Chemistry and Chromatography
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (61)
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