Efficient adsorptive removal of diclofenac sodium by acidified MIL101(Cr): optimizing the content of phosphotungstic acid, flow loop thin film slurry flat plate reactor
Source abstract
Abstract
In this study, the adsorptive removal of diclofenac sodium (DFC), one of the most frequently encountered pharmaceuticals and personal care products (PPCPs), by MIL101(Cr) and five different contents of encapsulated phosphotungstic acid (PTA) using one pot method in PTA@MIL101(Cr) were investigated using a designed batch continuous flow loop thin film slurry flat plate reactor (TFSR). Several influential variables such as adsorbate mass, pH, contact time, temperature, flowrate and initial DFC concentration was analyzed in order to find the best operating range for DFC removal from aqueous solutions. When using 12 wt% PTA synthesized within the metal organic framework (MOF). The most significant DFC removal was observed. Computing by the Langmuir equation, the maximum adsorption capacity of DFC was 413.22 mg g−1. The Langmuir model matched the isotherm adsorption data and the removal process was complemented with a pseudo-second-order kinetics model. According to the thermodynamic analyses, the process was found to be spontaneous and endothermic. In order to regenerate the MOF, 0.1 M HCl/EtOH (20/80 v/v) best performed as elution agent, regenerating the MOF to 88% of its originated maximum capacity after 5 times reusing. PTA (12 wt%) @MIL101(Cr) showed to be a tremendous reusable adsorbent for removing DFC from aqueous media.
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Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Chemical Synthesis and Characterization · Adsorption and biosorption for pollutant removal
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References (53)
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