Highly selective oxidation of alcohols catalyzed by Cu(II)-Schiff base-SBA-15 with hydrogen peroxide in water
Source abstract
Abstract
An efficient catalyst for selective oxidation of alcohols was prepared by grafting the Cu(II) Schiff base complex onto the channels of mesoporous silica material SBA-15. The characterizations illustrated that the functionalized SBA-15 maintained the primary hexagonally ordered mesoporous structure, and the Cu(II) Schiff base complexes were bonded inside the mesoporous channels of SBA-15. The selective oxidation of benzyl alcohol was carried out in water phase with hydrogen peroxide. The C6H5CH2OH conversion could reach 98.5 % with 100 % of the selectivity to C6H5CHO under the optimum conditions. The catalyst could also react well on the selective oxidation of other primary alcohols.
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Research context
OpenAlex topics: Oxidative Organic Chemistry Reactions · Mesoporous Materials and Catalysis · Catalytic Processes in Materials Science
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (36)
Show source-provided references
1. S.M. Ma, J.X. Liu, S.H. Li, B. Chen, J.J. Cheng, J.Q. Kuang, Y. Liu, B.Q. Wan, Y.L. Wang, J.T. Ye, Q. Yu, W.M. Yuan, S.C. Yu, Adv. Synth. Catal. 353, 1005 (2011)10.1002/adsc.201100033 ↗
2. S. Farhadi, M. Zaidi, Appl. Catal. A General 354, 119 (2009)10.1016/j.apcata.2008.11.024 ↗
3. S. Velusamy, M. Ahamed, T. Punniyamurthy, Org. Lett. 6, 4821 (2004)10.1021/ol048195t ↗
4. A. Dewan, T. Sarma, U. Bora, D.K. Kakati, Tetrahedron Lett. 52, 2563 (2011)10.1016/j.tetlet.2011.03.044 ↗
5. F. Adam, I. Sugiarmawan, J. Porous. Mat. 16, 321 (2009)10.1007/s10934-008-9203-1 ↗
6. B.A. Steinhoff, S.R. Fix, S.S. Stahl, J. Am. Chem. Soc. 124, 766 (2002)10.1021/ja016806w ↗
7. G.J. ten Brink, I.W. Arends, R.A. Sheldon, Science 287, 1636 (2000)10.1126/science.287.5458.1636 ↗
8. B.M. Choudary, M.L. Kantam, A. Rahman, C.V. Reddy, K.K. Rao, Angew. Chem. Int. Edit. 40, 763 (2001)10.1002/1521-3773(20010216)40:4<763::AID-ANIE7630>3.0.CO;2-T ↗
9. A. Villa, N. Janjic, P. Spontoni, D. Wang, D.S. Su, L. Prati, Appl. Catal. A General 364, 221 (2009)10.1016/j.apcata.2009.05.059 ↗
10. M.L. Kantam, U. Pal, B. Sreedhar, S. Bhargava, Y. Iwasawa, M. Tada, B.M. Choudary, Adv. Synth. Catal. 350, 1225 (2008)10.1002/adsc.200800013 ↗
11. M.J. Jacinto, O.H.C.F. Santos, R.F. Jardim, R. Landers, L.M. Rossi, Appl. Catal. A General 360, 177 (2009)10.1016/j.apcata.2009.03.018 ↗
12. A. Kockritz, M. Sebek, A. Dittmar, J. Radnik, A. Bruckner, U. Bentrup, M.M. Pohl, H. Hugl, W. Magerlein, J. Mol. Catal. A: Chem. 246, 85 (2006)10.1016/j.molcata.2005.10.020 ↗
13. A. Zsigmond, F. Notheisz, G. Csjernyik, J.E. Backvall, Top. Catal. 19, 119 (2002)10.1023/A:1013893502340 ↗
14. H. Yang, X. Han, Z. Ma, R. Wang, J. Liu, X. Ji, Green Chem. 12, 441 (2010)10.1039/b919175e ↗
15. T. Yasu-eda, R. Se-ike, N.O. Ikenaga, T. Miyake, T. Suzuki, J. Mol. Catal. A: Chem. 306, 136 (2009)10.1016/j.molcata.2009.02.039 ↗
16. J. Chen, Q. Zhang, Y. Wang, H. Wan, Adv. Synth. Catal. 350, 453 (2008)10.1002/adsc.200700350 ↗
17. C.Y. Ma, B.J. Dou, J.J. Li, J. Cheng, Q. Hu, Z.P. Hao, S.Z. Qiao, Appl. Catal. B Environ. 92, 202 (2009)10.1016/j.apcatb.2009.07.007 ↗
18. P.G.N. Mertens, P. Vandezande, X. Ye, H. Poelman, D.E. De Vos, I.F.J. Vankelecom, Adv. Synth. Catal. 350, 1241 (2008)10.1002/adsc.200700553 ↗
19. P. Haider, B. Kimmerle, F. Krumeich, W. Kleist, J.D. Grunwaldt, A. Baiker, Catal. Lett. 125, 169 (2008)10.1007/s10562-008-9567-5 ↗
20. M. Ilyas, M. Sadiq, Chem. Eng. Technol. 30, 1391 (2007)10.1002/ceat.200700072 ↗
21. M.J. Beier, T.W. Hansen, J.D. Grunwaldt, J. Catal. 266, 320 (2009)10.1016/j.jcat.2009.06.022 ↗
22. G. Wu, X. Wang, J. Li, N. Zhao, W. Wei, Y. Sun, Catal. Today 131, 402 (2008)10.1016/j.cattod.2007.10.085 ↗
23. X.G. Zhou, X.Q. Yu, J.S. Huang, S.G. Li, L.S. Li, C.M. Che, Chem. Commun. 1789 (1999)10.1039/a905313a ↗
24. N. Sathya, A. Manimaran, G. Raja, P. Muthusamy, K. Deivasigamani, C. Jayabalakrishnan, Transit. Metal. Chem. 34, 7 (2009)10.1007/s11243-008-9144-1 ↗
25. A. Soriente, M. De Rosa, M. Lamberti, C. Tedesco, A. Scettri, C. Pellecchia, J. Mol. Catal. A: Chem. 235, 253 (2005)10.1016/j.molcata.2005.03.012 ↗
26. D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Science 279, 548 (1998)10.1126/science.279.5350.548 ↗
27. M.S. Saraiva, Micropor. Mesopor. Mater. 117, 670 (2009)10.1016/j.micromeso.2008.08.012 ↗
28. L. Saikia, D. Srinivas, P. Ratnasamy, Appl. Catal. A General 309, 144 (2006)10.1016/j.apcata.2006.05.011 ↗
29. J. Hu, K. Li, W. Li, F. Ma, Y. Guo, Appl. Catal. A General 364, 211 (2009)10.1016/j.apcata.2009.05.058 ↗
30. D. Ramakrishna, B.R. Bhat, R. Karvembu, Catal. Commun. 11, 498 (2010)10.1016/j.catcom.2009.12.011 ↗
31. Y. Yang, S. Hao, P. Qiu, F. Shang, W. Ding, Q. Kan, Reac. Kinet. Mech. Cat. 100, 363 (2010)
32. Z. Dong, Z. Dong, J. Ren, J. Jin, P. Wang, J. Jiang, R. Li, J. Ma, Micropor. Mesopor. Mater. 135, 170 (2010)10.1016/j.micromeso.2010.07.006 ↗
33. A.S.M. Chong, X.S. Zhao, J. Phys. Chem. B 107, 12650 (2003)10.1021/jp035877+ ↗
34. S. Jana, B. Dutta, R. Bera, S. Koner, Langmuir 23, 2492 (2007)10.1021/la062409t ↗
35. M.M. Bhadbhade, D. Srinivas, Inorg. Chem. 32, 5458 (1993)10.1021/ic00076a010 ↗
36. S. Velu, K. Suzuki, M. Okazaki, M.P. Kapoor, T. Osaki, F. Ohashi, J. Catal. 194, 373 (2000)10.1006/jcat.2000.2940 ↗