Preparation of macroporous lithium iron manganese phosphate/carbon composites via sol-gel process accompanied by phase separation
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OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies
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1. I.M. Nwachukwu, A.C. Nwanya, A.B.C. Ekwealor, F.I. Ezema, Recent progress in Mn and Fe-rich cathode materials used in Li-ion batteries. J. Energy Storage. 54, 105248 (2022). https://doi.org/10.1016/j.est.2022.10524810.1016/j.est.2022.105248 ↗
2. G. Rousse, J. Rodriguez-Carvajal, S. Patoux, C. Masquelier, Magnetic structures of the triphylite LiFePO4 and of its delithiated form FePO4. Chem. Mater. 15, 4082–4090 (2003). https://doi.org/10.1021/cm030046210.1021/cm0300462 ↗
3. Z. Myalo, C.O. Ikpo, A.C. Nwanya, M.M. Ndipingwi, S.F. Duoman, K.V. Mokwebo, E.I. Iwuoha, Graphenised lithium iron phosphate and lithium manganese silicate hybrid cathodes: potentials for application in lithium-ion batteries. Electroanalysis. 32, 2982–2999 (2020). https://doi.org/10.1002/elan.20206043510.1002/elan.202060435 ↗
4. T. Zeng, Z. Hu, Z. Zhou, C. Fan, F. Zhang, J. Liu, D. Liu, Boron-catalyzed graphitization carbon layer enabling LiMn0.8Fe0.2PO4 cathode superior kkinetics and Li‐storage properties. Small Methods. 7, 2201390 (2023). https://doi.org/10.1002/smtd.20220139010.1002/smtd.202201390 ↗
5. Y. Liu, Y.-J. Gu, J.-L. Deng, G.-Y. Luo, F.-Z. Wu, Y. Mai, X.-Y. Dai, J.-Q. Li, Effect of doped mn on improving the electrochemical performance of LiFePO4. J. Mater. Sci. : Mater. Electron. 31, 2887–2894 (2020). https://doi.org/10.1007/s10854-019-02833-510.1007/s10854-019-02833-5 ↗
6. L. Wang, Y. Li, J. Wu, F. Liang, K. Zhang, R. Xu, H. Wan, Y. Dai, Y. Yao, Synthesis mechanism and characterization of LiMn0.5Fe0.5PO4/C composite cathode material for lithium-ion batteries. J. Alloys Compd. 839, 155653 (2020). https://doi.org/10.1016/j.jallcom.2020.15565310.1016/j.jallcom.2020.155653 ↗
7. H. Zhuang, Y. Bao, Y. Nie, Y. Qian, Y. Deng, G. Chen, Synergistic effect of composite carbon source and simple pre-calcining process on significantly enhanced electrochemical performance of porous LiFe0.5Mn0.5PO4/C agglomerations, Electrochim. Acta. 314, 102–114 (2019). https://doi.org/10.1016/j.electacta.2019.05.06610.1016/j.electacta.2019.05.066 ↗
8. G. Du, X. Guo, W. Yang, Y. Bi, R. Du, Y. Liu, D. Wang, Additives to disturb LiMn0.8Fe0.2PO4 growth and their influence on performance. J. Nanopart. Res. 17, 272 (2015). https://doi.org/10.1007/s11051-015-3077-310.1007/s11051-015-3077-3 ↗
9. K. Kisu, E. Iwama, W. Onishi, S. Nakashima, W. Naoi, K. Naoi, Ultrafast nano-spherical single-crystalline LiMn0.792Fe0.198Mg0.010PO4 solid-solution confined among unbundled interstices of SGCNTs. J. Mater. Chem. A 2, 20789–20798 (2014). https://doi.org/10.1039/C4TA04723K10.1039/C4TA04723K ↗
10. S. Qiao, L. Zhu, E. Han, L. Li, C. Du, Y. He, Synthesis and electrochemical properties of na and mg co doped LiFe0.65Mn0.35PO4/C cathode materials for lithium-ion batteries. Int. J. Electrochem. Sci. 14, 10616–10629 (2019). https://doi.org/10.20964/2019.12.6710.20964/2019.12.67 ↗
11. H. Yang, C. Fu, Y. Sun, L. Wang, T. Liu, Fe-doped LiMnPO4@C nanofibers with high Li-ion diffusion coefficient. Carbon. 158, 102–109 (2020). https://doi.org/10.1016/j.carbon.2019.11.06710.1016/j.carbon.2019.11.067 ↗
12. K. Nakanishi, N. Soga, Phase separation in gelling silica–organic polymer solution: systems containing poly(sodium styrenesulfonate). J. Am. Ceram. Soc. 74, 2518–2530 (1991). https://doi.org/10.1111/j.1151-2916.1991.tb06794.x10.1111/j.1151-2916.1991.tb06794.x ↗
13. A.E. Gash, T.M. Tillotson, J.H. Satcher, J.F. Poco, L.W. Hrubesh, R.L. Simpson, Use of epoxides in the sol – gel synthesis of porous iron (III) oxide monoliths from Fe (III) salts. Chem. Mater. 13, 999–1007 (2001). https://doi.org/10.1021/cm000761110.1021/cm0007611 ↗
14. R.E. Phillips, R.L. Soulen, Propylene oxide addition to hydrochloric acid: a textbook error. J. Chem. Educ. 72, 624 (1995). https://doi.org/10.1021/ed072p62410.1021/ed072p624 ↗
15. J. Konishi, K. Fujita, S. Oiwa, K. Nakanishi, K. Hirao, Crystalline ZrO2 monoliths with well-defined macropores and mesostructured skeletons prepared by combining the alkoxy-derived sol–gel process accompanied by phase separation and the solvothermal process. Chem. Mater. 20, 2165–2173 (2008). https://doi.org/10.1021/cm703351d10.1021/cm703351d ↗
16. Y. Tokudome, K. Fujita, K. Nakanishi, K. Miura, K. Hirao, Synthesis of monolithic Al2O3 with well-defined macropores and mesostructured skeletons via the sol – gel process accompanied by phase separation. Chem. Mater. 19, 3393–3398 (2007). https://doi.org/10.1021/cm063051p10.1021/cm063051p ↗
17. Y. Kido, K. Nakanishi, A. Miyasaka, K. Kanamori, Synthesis of monolithic hierarchically porous iron-based xerogels from iron (III) salts via an epoxide-mediated sol–gel process. Chem. Mater. 24, 2071–2077 (2012). https://doi.org/10.1021/cm300495j10.1021/cm300495j ↗
18. W. Li, Y. Zhu, X. Guo, K. Nakanishi, K. Kanamori, H. Yang, Preparation of a hierarchically porous AlPO4 monolith via an epoxide-mediated sol–gel process accompanied by phase separation. Sci. Technol. Adv. Mater. 14, 045007 (2013). https://doi.org/10.1088/1468-6996/14/4/04500710.1088/1468-6996/14/4/045007 ↗
19. X. Guo, H. Yu, H. Yang, K. Kanamori, Y. Zhu, K. Nakanishi, Pore structure control of macroporous methylsilsesquioxane monoliths prepared by in situ two-step processing. J. Porous Mater. 20, 1477–1483 (2013). https://doi.org/10.1007/s10934-013-9733-z10.1007/s10934-013-9733-z ↗
20. Y. Wang, W. Zhu, Micro/nano-structured Li4Ti5O12 as high rate anode material for lithium ion batteries. Solid State Ionics. 349, 115297 (2020). https://doi.org/10.1016/j.ssi.2020.11529710.1016/j.ssi.2020.115297 ↗
21. D. Feng, H. Yang, Q. Wang, X. Guo, Preparation and characteristic of three-dimensional NiCo alloy/carbon composite monoliths with well-defined macropores and mesostructured skeletons. J. Mater. Sci. 54, 4719–4731 (2019). https://doi.org/10.1007/s10853-018-03224-710.1007/s10853-018-03224-7 ↗
22. D. Feng, H. Yang, X. Guo, 3-Dimensional hierarchically porous ZnFe2O4/C composites with stable performance as anode materials for Li-ion batteries. Chem. Eng. J. (Amsterdam Neth). 355, 687–696 (2019). https://doi.org/10.1016/j.cej.2018.08.20210.1016/j.cej.2018.08.202 ↗
23. Z. Chen, W. Zhang, Z. Yang, A review on cathode materials for advanced lithium ion batteries: microstructure designs and performance regulations. Nanotechnology. 31, 012001 (2020). https://doi.org/10.1088/1361-6528/ab444710.1088/1361-6528/ab4447 ↗
24. S. Sun, C. Matei Ghimbeu, R. Janot, J.-M. Le Meins, A. Cassel, C. Davoisne, C. Masquelier, C. Vix-Guterl, One-pot synthesis of LiFePO4 –carbon mesoporous composites for Li-ion batteries. Microporous Mesoporous Mater. 198, 175–184 (2014). https://doi.org/10.1016/j.micromeso.2014.07.03910.1016/j.micromeso.2014.07.039 ↗
25. C.M. Doherty, R.A. Caruso, C.J. Drummond, High performance LiFePO4 electrode materials: influence of colloidal particle morphology and porosity on lithium-ion battery power capability. Energy Environ. Sci. 3(6), 813–823 (2010). https://doi.org/10.1039/B922898E10.1039/B922898E ↗
26. G. Hasegawa, Y. Ishihara, K. Kanamori, K. Miyazaki, Y. Yamada, K. Nakanishi, T. Abe, Facile preparation of monolithic LiFePO4/Carbon composites with well-defined macropores for a lithium-ion battery. Chem. Mater. 23, 5208–5216 (2011). https://doi.org/10.1021/cm202143810.1021/cm2021438 ↗
27. X. Zhang, M. Hou, A.G. Tamirate, H. Zhu, C. Wang, Y. Xia, Carbon coated nano-sized LiMn0.8Fe0.2PO4 porous microsphere cathode material for Li-ion batteries. J. Power Sources. 448, 227438 (2020). https://doi.org/10.1016/j.jpowsour.2019.22743810.1016/j.jpowsour.2019.227438 ↗
28. F. Wen, H. Shu, Y. Zhang, J. Wan, W. Huang, X. Yang, R. Yu, L. Liu, X. Wang, Mesoporous LiMnPO4/C nanoparticles as high performance cathode material for lithium ion batteries. Electrochim. Acta. 214, 85–93 (2016). https://doi.org/10.1016/j.electacta.2016.08.04210.1016/j.electacta.2016.08.042 ↗
29. P. Zuo, L. Wang, W. Zhang, G. Yin, Y. Ma, C. Du, X. Cheng, Y. Gao, A novel nanoporous Fe-doped lithium manganese phosphate material with superior long-term cycling stability for lithium-ion batteries. Nanoscale. 7(27), 11509–11514 (2015). https://doi.org/10.1039/C5NR01881A10.1039/C5NR01881A ↗
30. J.-K. Kim, J.-W. Choi, G.S. Chauhan, J.-H. Ahn, G.-C. Hwang, J.-B. Choi, H.-J. Ahn, Enhancement of electrochemical performance of lithium iron phosphate by controlled sol–gel synthesis. Electrochim. Acta. 53, 8258–8264 (2008). https://doi.org/10.1016/j.electacta.2008.06.04910.1016/j.electacta.2008.06.049 ↗
31. R. Dominko, M. Bele, M. Gaberscek, M. Remskar, D. Hanzel, J.M. Goupil, S. Pejovnik, J. Jamnik, Porous olivine composites synthesized by sol–gel technique. J. Power Sources. 153, 274–280 (2006). https://doi.org/10.1016/j.jpowsour.2005.05.03310.1016/j.jpowsour.2005.05.033 ↗
32. L. Wang, Y. Li, Y. Wang, H. Zhang, Y. Dai, Y. Yao, F. Liang, Effect of vacuum assistance on the morphology and electrochemical properties of LiMn0.2Fe0.8PO4/C composites prepared by solid-phase method. Electrochim. Acta. 369, 137675 (2021). https://doi.org/10.1016/j.electacta.2020.13767510.1016/j.electacta.2020.137675 ↗
33. A. Vu, Y. Qian, A. Stein, Porous electrode materials for lithium-ion batteries - how to prepare them and what makes them special. Adv. Energy Mater. 2, 1056–1085 (2012). https://doi.org/10.1002/aenm.20120032010.1002/aenm.201200320 ↗
34. X. Lu, G. Hasegawa, K. Kanamori, K. Nakanishi, Hierarchically porous monoliths prepared via sol–gel process accompanied by spinodal decomposition. J. Sol-Gel Sci. Technol. 95, 530–550 (2020). https://doi.org/10.1007/s10971-020-05370-410.1007/s10971-020-05370-4 ↗
35. D.-M. Gao, B. Zhao, H. Liu, K. Morisato, K. Kanamori, Z. He, M. Zeng, H. Wu, J. Chen, K. Nakanishi, Synthesis of a hierarchically porous niobium phosphate monolith by a sol–gel method for fructose dehydration to 5-hydroxymethylfurfural. Catal. Sci. Technol. 8(14), 3675–3685 (2018). https://doi.org/10.1039/C8CY00803E10.1039/C8CY00803E ↗
36. X. Guo, X. Cai, J. Song, Y. Zhu, K. Nakanishi, K. Kanamori, H. Yang, Facile synthesis of monolithic mayenite with well-defined macropores via an epoxide-mediated sol–gel process accompanied by phase separation. New. J. Chem. 38, 5832–5839 (2014). https://doi.org/10.1039/C4NJ00898G10.1039/C4NJ00898G ↗
37. L.K. Mireles, M.-R. Wu, N. Saadeh, L. Yahia, E. Sacher, Physicochemical characterization of polyvinyl pyrrolidone: a tale of two polyvinyl pyrrolidones. ACS Omega. 5, 30461–30467 (2020). https://doi.org/10.1021/acsomega.0c0401010.1021/acsomega.0c04010 ↗
38. K.M. Koczkur, S. Mourdikoudis, L. Polavarapu, S.E. Skrabalak, Polyvinylpyrrolidone (PVP) in nanoparticle synthesis. Dalton Trans. 44, 17883–17905 (2015). https://doi.org/10.1039/C5DT02964C10.1039/C5DT02964C ↗
39. S. Selvam, M. Sundrarajan, Functionalization of cotton fabric with PVP/ZnO nanoparticles for improved reactive dyeability and antibacterial activity. Carbohydr. Polym. 87, 1419–1424 (2012). https://doi.org/10.1016/j.carbpol.2011.09.02510.1016/j.carbpol.2011.09.025 ↗
40. C. Zou, X. Guo, F. Wang, R. Tian, Y. Hou, F. Liu, H. Yang, Macroporous Ni-Fe hydroxide bifunctional catalyst for efficient alkaline water splitting. J. Sol-Gel Sci. Technol. 103, 505–514 (2022). https://doi.org/10.1007/s10971-022-05793-110.1007/s10971-022-05793-1 ↗
41. X. Lu, K. Kanamori, K. Nakanishi, Hierarchically porous monoliths based on low-valence transition metal (Cu, Co, Mn) oxides: gelation and phase separation. Natl. Sci. Rev. 7, 1656–1666 (2020). https://doi.org/10.1093/nsr/nwaa10310.1093/nsr/nwaa103 ↗
42. Y. Hara, K. Kanamori, K. Morisato, R. Miyamoto, K. Nakanishi, Iron (iii) oxyhydroxide and oxide monoliths with controlled multiscale porosity: synthesis and their adsorption performance. J. Mater. Chem. A 6, 9041–9048 (2018). https://doi.org/10.1039/C8TA01691G10.1039/C8TA01691G ↗
43. F. Liu, D. Feng, H. Yang, X. Guo, Preparation of macroporous transition metal hydroxide monoliths via a sol-gel process accompanied by phase separation. Sci. Rep. 10, 4331 (2020). https://doi.org/10.1038/s41598-020-61195-910.1038/s41598-020-61195-9 ↗
44. Y.-J. Zhong, J.-T. Li, Z.-G. Wu, X.-D. Guo, B.-H. Zhong, S.-G. Sun, LiMn0.5Fe0.5PO4 solid solution materials synthesized by rheological phase reaction and their excellent electrochemical performances as cathode of lithium ion battery. J. Power Sources. 234, 217–222 (2013). https://doi.org/10.1016/j.jpowsour.2013.01.18410.1016/j.jpowsour.2013.01.184 ↗
45. C. Portet, G. Yushin, Y. Gogotsi, Electrochemical performance of carbon onions, nanodiamonds, carbon black and multiwalled nanotubes in electrical double layer capacitors. Carbon. 45, 2511–2518 (2007). https://doi.org/10.1016/j.carbon.2007.08.02410.1016/j.carbon.2007.08.024 ↗
46. C.X. Zhao, Y. Zhang, S.Z. Deng, N.S. Xu, J. Chen, Surface nitrogen functionality for the enhanced field emission of free-standing few-layer graphene nanowalls. J. Alloys Compd. 672, 433–439 (2016). https://doi.org/10.1016/j.jallcom.2016.01.26510.1016/j.jallcom.2016.01.265 ↗
47. B.J. Tan, K.J. Klabunde, P.M.A. Sherwood, XPS studies of solvated metal atom dispersed (SMAD) catalysts. Evidence for layered cobalt-manganese particles on alumina and silica. J. Am. Chem. Soc. 113, 855–861 (1991). https://doi.org/10.1021/ja00003a01910.1021/ja00003a019 ↗
48. X. Tu, Y. Zhou, X. Tian, Y. Song, C. Deng, H. Zhu, Monodisperse LiFePO4 microspheres embedded with well-dispersed nitrogen-doped carbon nanotubes as high-performance positive electrode material for lithium-ion batteries. Electrochim. Acta. 222, 64–73 (2016). https://doi.org/10.1016/j.electacta.2016.10.13710.1016/j.electacta.2016.10.137 ↗
49. C. Gao, J. Zhou, G. Liu, L. Wang, Lithium-ions diffusion kinetic in LiFePO4/carbon nanoparticles synthesized by microwave plasma chemical vapor deposition for lithium-ion batteries. Appl. Surf. Sci. 433, 35–44 (2018). https://doi.org/10.1016/j.apsusc.2017.10.03410.1016/j.apsusc.2017.10.034 ↗
50. X. Yang, S. Liping, L. Qiang, H. Lihua, Z. Hui, Co-prosperity of electrocatalytic activity and stability in high entropy spinel (Cr0.2Mn0.2Fe0.2Ni0.2Zn 0.2)3O4 for the oxygen evolution reaction. J. Mater. Chem. A 10, 17633–17641 (2022). https://doi.org/10.1039/D2TA01376B10.1039/D2TA01376B ↗
51. Z. Wang, S.J. Tang, S.H. Li, Study on the surface modification of LiNi1/3Co1/3Mn1/3O2 ternary cathode material by Al2O3/LiAlO2. J. Liaocheng Univ. (Natural Sci. Edition). 36(3), 56–63 (2023). https://doi.org/10.19728/j.issn1672-6634.202301000710.19728/j.issn1672-6634.2023010007 ↗
52. Y. Gao, L. Zhang, S. Feng, W. Shen, S. Guo, Improving the electrochemical properties of lithium iron (II) phosphate through surface modification with manganese ion (II) and reduced graphene oxide. J. Solid State Electrochem. 22, 285–292 (2018). https://doi.org/10.1007/s10008-017-3757-210.1007/s10008-017-3757-2 ↗